Mechanistic studies of olefin epoxidation by a manganese porphyrin and hypochlorite: an alternative explanation of saturation kinetics

The catalytic epoxidation of olefins with Mn(TMP)Cl with phase-transfer catalysis and hypochlorite has been reexamined from the point of view of material balance and stability of this system in the presence of three axial ligands. The efficiency (yield of epoxide formation based on OCl{sup {minus}}...

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Veröffentlicht in:	Journal of the American Chemical Society 1990-10, Vol.112 (22), p.7980-7984
Hauptverfasser:	Collman, James P, Brauman, John I, Hampton, Philip D, Tanaka, Hiroo, Bohle, D. Scott, Hembre, Robert T
Format:	Artikel
Sprache:	eng
Schlagworte:	02 PETROLEUM 020400 - Petroleum- Processing ALKENES CARBOXYLIC ACIDS CATALYSTS CHEMICAL PREPARATION CHEMICAL REACTIONS Chemistry COMPLEXES DATA EPOXIDES Exact sciences and technology EXPERIMENTAL DATA HETEROCYCLIC ACIDS HETEROCYCLIC COMPOUNDS HYDROCARBONS INFORMATION Kinetics and mechanisms LIGANDS MANGANESE COMPLEXES NUMERICAL DATA ORGANIC ACIDS Organic chemistry ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS ORGANIC OXYGEN COMPOUNDS PORPHYRINS Reactivity and mechanisms SYNTHESIS TRANSITION ELEMENT COMPLEXES
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