Photodissociation dynamics of the singlet and triplet states of the NCN radical

The spectroscopy and photodissociation dynamics of the NCN radical have been investigated by fast beam photofragment translational spectroscopy. The B̃ 3Σu−←X̃ 3Σg−, c̃ 1Πu←ã 1Δg, and d̃ 1Δu←ã 1Δg transitions were examined. The major dissociation products for the B̃ 3Σu− and c̃ 1Πu states are N2(X̃ ...

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Veröffentlicht in:	The Journal of chemical physics 1999-09, Vol.111 (11), p.4923-4932
Hauptverfasser:	Bise, Ryan T., Choi, Hyeon, Neumark, Daniel M.
Format:	Artikel
Sprache:	eng
Schlagworte:	CHEMICAL REACTIONS COMBUSTION PRODUCTS CYANOGEN DECOMPOSITION DISSOCIATION ENERGY ELECTRONIC STRUCTURE ENERGY INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY NITROGEN COMPOUNDS PHOTOCHEMICAL REACTIONS 400500 > Photochemistry PHOTOLYSIS RADICALS REACTION INTERMEDIATES
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