Oxidation of the ruthenium hydride complex (.eta.5-C5H5)Ru(CO)(PPh3)H: generation of a dihydrogen complex by oxidatively induced intermolecular proton transfer

Ruthenium hydride ({eta}{sup 5}-C{sub 5}H{sub 5})Ru(CO)(PPh{sub 3})H (1) undergoes a chemically irreversible oxidation at +0.39 V vs the ferrocene/ferrocenium couple. Oxidation of 1 with ({eta}{sup 5}-C{sub 5}H{sub 5}){sub 2}Fe{sup +}PF{sub 6}{sup {minus}} (3) in dichloromethane-d{sub 2} yields the...

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Veröffentlicht in:	Organometallics 1991-01, Vol.10 (1), p.298-304
Hauptverfasser:	Ryan, Olav B, Tilset, Mats, Parker, Vernon D
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties ACETONITRILE ALKENES BORON COMPOUNDS BORON FLUORIDES CATALYTIC EFFECTS CHEMICAL REACTION KINETICS CHEMICAL REACTIONS Chemistry COMPLEXES CYCLOALKENES CYCLOPENTADIENE DIENES ELECTRIC POTENTIAL ELECTROCHEMICAL CELLS ELECTROLYSIS Exact sciences and technology FLUORIDES FLUORINE COMPOUNDS HALIDES HALOGEN COMPOUNDS HYDROCARBONS INFRARED SPECTRA INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IRON COMPLEXES KINETICS LIGANDS LYSIS METHYLENE CHLORIDE NITRILES NMR SPECTRA Organic chemistry ORGANIC CHLORINE COMPOUNDS ORGANIC COMPOUNDS ORGANIC HALOGEN COMPOUNDS ORGANIC NITROGEN COMPOUNDS Organometalloidal and organometallic compounds OXIDATION PHOSPHINES PHOSPHORUS COMPOUNDS POLYENES Preparations and properties REACTION INTERMEDIATES REACTION KINETICS RUTHENIUM COMPLEXES SPECTRA TRANSITION ELEMENT COMPLEXES Transition metals derivatives VOLTAMETRY
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