Laser ionization gas chromatography/mass spectrometry of tetraethyltin
A new method for detecting tetraethyltin that combines the high efficiency of laser ionization, the selectivity of capillary column gas chromatography, and the large throughput of a time-of-flight mass spectrometer is demonstrated. Detection limits of 2.5 pg of tetraethyltin/mL or 1.5 fg of tetraeth...
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| Veröffentlicht in: | Analytical chemistry (Washington) 1990-11, Vol.62 (21), p.2400-2403 |
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| container_title | Analytical chemistry (Washington) |
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| creator | Colby, Steven M Stewart, Michael Reilly, James P |
| description | A new method for detecting tetraethyltin that combines the high efficiency of laser ionization, the selectivity of capillary column gas chromatography, and the large throughput of a time-of-flight mass spectrometer is demonstrated. Detection limits of 2.5 pg of tetraethyltin/mL or 1.5 fg of tetraethyltin absolute have been obtained. These values correspond to 1.3 pg of tin/mL or 750 ag of tin absolute. This method should be generalizable to other elements. |
| doi_str_mv | 10.1021/ac00220a027 |
| format | Article |
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Detection limits of 2.5 pg of tetraethyltin/mL or 1.5 fg of tetraethyltin absolute have been obtained. These values correspond to 1.3 pg of tin/mL or 750 ag of tin absolute. This method should be generalizable to other elements.</description><identifier>ISSN: 0003-2700</identifier><identifier>EISSN: 1520-6882</identifier><identifier>DOI: 10.1021/ac00220a027</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>400102 - Chemical & Spectral Procedures ; 540320 - Environment, Aquatic- Chemicals Monitoring & Transport- (1990-) ; CHEMICAL ANALYSIS ; CHROMATOGRAPHY ; DATA ; ELEMENTS ; ENVIRONMENTAL SCIENCES ; EXPERIMENTAL DATA ; GAS CHROMATOGRAPHY ; HAZARDOUS MATERIALS ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; MASS SPECTROSCOPY ; MATERIALS ; MEASURING METHODS ; METALS ; NUMERICAL DATA ; RESONANCE IONIZATION MASS SPECTROSCOPY ; SENSITIVITY ; SEPARATION PROCESSES ; SPECTROSCOPY ; TIN ; TIN COMPOUNDS</subject><ispartof>Analytical chemistry (Washington), 1990-11, Vol.62 (21), p.2400-2403</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a364t-5262e7b7be61ee3f5446215b030516eab878108ed17921d3ecb8def57ad877783</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ac00220a027$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ac00220a027$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,776,780,881,2751,27055,27903,27904,56717,56767</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/6099380$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Colby, Steven M</creatorcontrib><creatorcontrib>Stewart, Michael</creatorcontrib><creatorcontrib>Reilly, James P</creatorcontrib><title>Laser ionization gas chromatography/mass spectrometry of tetraethyltin</title><title>Analytical chemistry (Washington)</title><addtitle>Anal. 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| fulltext | fulltext |
| identifier | ISSN: 0003-2700 |
| ispartof | Analytical chemistry (Washington), 1990-11, Vol.62 (21), p.2400-2403 |
| issn | 0003-2700 1520-6882 |
| language | eng |
| recordid | cdi_osti_scitechconnect_6099380 |
| source | American Chemical Society Journals |
| subjects | 400102 - Chemical & Spectral Procedures 540320 - Environment, Aquatic- Chemicals Monitoring & Transport- (1990-) CHEMICAL ANALYSIS CHROMATOGRAPHY DATA ELEMENTS ENVIRONMENTAL SCIENCES EXPERIMENTAL DATA GAS CHROMATOGRAPHY HAZARDOUS MATERIALS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MASS SPECTROSCOPY MATERIALS MEASURING METHODS METALS NUMERICAL DATA RESONANCE IONIZATION MASS SPECTROSCOPY SENSITIVITY SEPARATION PROCESSES SPECTROSCOPY TIN TIN COMPOUNDS |
| title | Laser ionization gas chromatography/mass spectrometry of tetraethyltin |
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