Liquid formation at hte peritectic temperature in superconducting YBa sub 2 Cu sub 3 O sub 7 minus x; Observation of a new phase YBa sub 4 CuAlO sub 8

This paper reports, in the system Y-Ba- Cu-O partial melting of peritectically decomposing YBa{sub 2}Cu{sub 3}O{sub 7{minus}x} (123) used to produce a bulk material of high critical current density when the material was aligned. The liquid formation mechanism and its relation to reaction with alumin...

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Veröffentlicht in:Journal of the American Ceramic Society 1990-07, Vol.73:7
Hauptverfasser: Zhou, J.P., Sorrell, C.C., Bourdillon, A.J., Dou, S.X.
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Sorrell, C.C.
Bourdillon, A.J.
Dou, S.X.
description This paper reports, in the system Y-Ba- Cu-O partial melting of peritectically decomposing YBa{sub 2}Cu{sub 3}O{sub 7{minus}x} (123) used to produce a bulk material of high critical current density when the material was aligned. The liquid formation mechanism and its relation to reaction with alumina refractory was studied. A previously unreported phase of the approximate stoichiometric ration Y:Ba:Cu:Al = 1:4:1:1 (YBa{sub 4}CuAlO{sub 8}) was detected. The crystal structure was determined to be tetragonal with lattice parameters {alpha}{sub 0} = b{sub 0} = 1.651 nm, c{sub 0} = 1.793 nm. The 1411 phase bears a close structural relationship to BaCuO{sub 2}.
doi_str_mv 10.1111/j.1151-2916.1990.tb05291.x
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The liquid formation mechanism and its relation to reaction with alumina refractory was studied. A previously unreported phase of the approximate stoichiometric ration Y:Ba:Cu:Al = 1:4:1:1 (YBa{sub 4}CuAlO{sub 8}) was detected. The crystal structure was determined to be tetragonal with lattice parameters {alpha}{sub 0} = b{sub 0} = 1.651 nm, c{sub 0} = 1.793 nm. 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The liquid formation mechanism and its relation to reaction with alumina refractory was studied. A previously unreported phase of the approximate stoichiometric ration Y:Ba:Cu:Al = 1:4:1:1 (YBa{sub 4}CuAlO{sub 8}) was detected. The crystal structure was determined to be tetragonal with lattice parameters {alpha}{sub 0} = b{sub 0} = 1.651 nm, c{sub 0} = 1.793 nm. 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Observation of a new phase YBa sub 4 CuAlO sub 8</atitle><jtitle>Journal of the American Ceramic Society</jtitle><date>1990-07-01</date><risdate>1990</risdate><volume>73:7</volume><issn>0002-7820</issn><eissn>1551-2916</eissn><abstract>This paper reports, in the system Y-Ba- Cu-O partial melting of peritectically decomposing YBa{sub 2}Cu{sub 3}O{sub 7{minus}x} (123) used to produce a bulk material of high critical current density when the material was aligned. The liquid formation mechanism and its relation to reaction with alumina refractory was studied. A previously unreported phase of the approximate stoichiometric ration Y:Ba:Cu:Al = 1:4:1:1 (YBa{sub 4}CuAlO{sub 8}) was detected. The crystal structure was determined to be tetragonal with lattice parameters {alpha}{sub 0} = b{sub 0} = 1.651 nm, c{sub 0} = 1.793 nm. The 1411 phase bears a close structural relationship to BaCuO{sub 2}.</abstract><cop>United States</cop><doi>10.1111/j.1151-2916.1990.tb05291.x</doi></addata></record>
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ispartof Journal of the American Ceramic Society, 1990-07, Vol.73:7
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language eng
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subjects 360202 - Ceramics, Cermets, & Refractories- Structure & Phase Studies
360204 - Ceramics, Cermets, & Refractories- Physical Properties
426001 - Engineering- Superconducting Devices & Circuits- (1990-)
656100 - Condensed Matter Physics- Superconductivity
ALKALINE EARTH METAL COMPOUNDS
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
BARIUM COMPOUNDS
BARIUM OXIDES
CHALCOGENIDES
CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
COPPER COMPOUNDS
COPPER OXIDES
CRITICAL CURRENT
CRYSTAL STRUCTURE
CURRENT DENSITY
CURRENTS
ELECTRIC CONDUCTIVITY
ELECTRIC CURRENTS
ELECTRICAL PROPERTIES
EPITAXY
LATTICE PARAMETERS
LIQUID PHASE EPITAXY
MATERIALS SCIENCE
OXIDES
OXYGEN COMPOUNDS
PHASE STUDIES
PHYSICAL PROPERTIES
REFRACTORIES
STOICHIOMETRY
SUPERCONDUCTIVITY
SUPERCONDUCTORS
TRANSITION ELEMENT COMPOUNDS
YTTRIUM COMPOUNDS
title Liquid formation at hte peritectic temperature in superconducting YBa sub 2 Cu sub 3 O sub 7 minus x; Observation of a new phase YBa sub 4 CuAlO sub 8
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