Simultaneous oscillations of the surface mass and potential in the course of the galvanostatic oxidation of 2-propanol

The results presented on simultaneous oscillations of the potential and surface mass during the galvanostatic oxidation of 2-propanol in acid media are the first experimental evidence that the oscillation arising in the course of galvanostatic oxidation of simple organic compounds is associated with...

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Veröffentlicht in:	Journal of physical chemistry (1952) 1993-06, Vol.97 (23), p.6104-6106
Hauptverfasser:	Inzelt, Gyorgy, Kertesz, Vilmos, Lang, Gyozo
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 > Chemical & Physicochemical Properties ALCOHOLS BALANCES CHEMICAL REACTIONS CHEMISORPTION CHEMISTRY ELECTROCHEMISTRY Exact sciences and technology General and physical chemistry HYDROXY COMPOUNDS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Kinetics and mechanism of reactions MEASURING INSTRUMENTS MICROBALANCES ORGANIC COMPOUNDS OSCILLATION MODES OXIDATION PROPANOLS SEPARATION PROCESSES SORPTION VOLTAMETRY WEIGHT INDICATORS 400400 > Electrochemistry
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Zusammenfassung:	The results presented on simultaneous oscillations of the potential and surface mass during the galvanostatic oxidation of 2-propanol in acid media are the first experimental evidence that the oscillation arising in the course of galvanostatic oxidation of simple organic compounds is associated with the accumulation and consumption of the chemisorbed species. The results of the electrochemical quartz crystal microbalance experiment may open up new vistas in the quantitative description of the heterogeneous oscillation phenomena. 12 refs., 4 figs.
ISSN:	0022-3654 1541-5740
DOI:	10.1021/j100125a002