Syntheses and structures of two trifluoroacetate-trapped derivatives of a ruthenium butatrienylidene complex

The alkynyl ketone [Ru(C[equivalent to]CCOCHMe[sub 2])-(PPh[sub 3])[sub 2](Cp)] (1) reacts with trifluoroacetic anhydride at ambient temperature to give [Ru(C[equivalent to]CC(OCOCF[sub 3])CMe[sub 2])(PPh[sub 3])[sub 2](Cp)][center dot]0.5Et[sub 2]O (2), an enynyl trifluoracetate ester which structu...

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Veröffentlicht in:	Organometallics 1993-03, Vol.12 (3), p.616-617
Hauptverfasser:	Lomprey, Jeffrey R, Selegue, John P
Format:	Artikel
Sprache:	eng
Schlagworte:	360606 - Other Materials- Physical Properties- (1992-) 400201 - Chemical & Physicochemical Properties CHEMICAL REACTIONS Chemistry COHERENT SCATTERING COMPLEXES Condensed matter: structure, mechanical and thermal properties CRYSTALLOGRAPHY DIFFRACTION Exact sciences and technology INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MATERIALS SCIENCE MOLECULAR STRUCTURE Organic chemistry Organic compounds Organometalloidal and organometallic compounds Physics Preparations and properties RUTHENIUM COMPLEXES SCATTERING Structure of solids and liquids crystallography Structure of specific crystalline solids SYNTHESIS TRANSITION ELEMENT COMPLEXES Transition metals derivatives X-RAY DIFFRACTION
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