Investigation of the redox states of (Ru(bpy) sub 2 CN) sub 2 CN sup + : Evidence for valence delocalization of the singly oxidized complex

A spectroelectrochemical study of both the oxidized and reduced forms of (Ru(bpy){sub 2}CN){sub 2}CN{sup +} is reported. The uv-vis spectra of the parent and reduced species indicate the complex consists of two identical chromophores, which are nearly identical with the Ru(bpy){sub 2}(CN){sub 2} chr...

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Veröffentlicht in:Inorganic chemistry 1991-05, Vol.30:10
Hauptverfasser: Cooper, J.B., Vess, T.M., Kalsbeck, W.A., Wertz, D.W.
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Sprache:eng
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