Plasma remediation of trichloroethylene in silent discharge plasmas

Plasma destruction of toxins, and volatile organic compounds in particular, from gas streams is receiving increased attention as an energy efficient means to remediate those compounds. In this regard, remediation of trichloroethylene (TCE) in silent discharge plasmas has been experimentally and theo...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of applied physics 1993-11, Vol.74 (9), p.5378-5386
Hauptverfasser: EVANS, D, ROSOCHA, L. A, ANDERSON, G. K, COOGAN, J. J, KUSHNER, M. J
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 5386
container_issue 9
container_start_page 5378
container_title Journal of applied physics
container_volume 74
creator EVANS, D
ROSOCHA, L. A
ANDERSON, G. K
COOGAN, J. J
KUSHNER, M. J
description Plasma destruction of toxins, and volatile organic compounds in particular, from gas streams is receiving increased attention as an energy efficient means to remediate those compounds. In this regard, remediation of trichloroethylene (TCE) in silent discharge plasmas has been experimentally and theoretically investigated. We found that TCE can be removed from Ar/O2 gas streams at atmospheric pressure with an energy efficiency of 15–20 ppm/(mJ/cm3), or 2–3 kW h kg−1. The majority of the Cl from TCE is converted to HCl, Cl2, and COCl2, which can be removed from the gas stream by a water bubbler. The destruction efficiency of TCE is smaller in humid mixtures compared to dry mixtures due to interception of reactive intermediates by OH radicals.
doi_str_mv 10.1063/1.354241
format Article
fullrecord <record><control><sourceid>pascalfrancis_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_5975252</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>4085989</sourcerecordid><originalsourceid>FETCH-LOGICAL-c347t-5f230f4db7998eae3d9390e98b53fe98e8c3b4615decf08257dd9cedfd3b3f4c3</originalsourceid><addsrcrecordid>eNo90DFPwzAQBWALgUQpSPwECzGwpNix3dgjqiggVYIB5sg5n4lRGle2l_57AkFM74bv3fAIueZsxdla3POVULKW_IQsONOmapRip2TBWM0rbRpzTi5y_mKMcy3MgmzeBpv3libcowu2hDjS6GlJAfohpoilPw44Ig0jzWG6CnUhQ2_TJ9LDbzdfkjNvh4xXf7kkH9vH981ztXt9etk87CoQsimV8rVgXrquMUajReGMMAyN7pTwU6AG0ck1Vw7BM12rxjkD6LwTnfASxJLczH9jLqHNEApCD3EcEUqrTKNqVU_obkaQYs4JfXtIYW_TseWs_Vmo5e280ERvZ3qwGezgkx0h5H8vmVZGG_ENBaFlsQ</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Plasma remediation of trichloroethylene in silent discharge plasmas</title><source>AIP Digital Archive</source><creator>EVANS, D ; ROSOCHA, L. A ; ANDERSON, G. K ; COOGAN, J. J ; KUSHNER, M. J</creator><creatorcontrib>EVANS, D ; ROSOCHA, L. A ; ANDERSON, G. K ; COOGAN, J. J ; KUSHNER, M. J</creatorcontrib><description>Plasma destruction of toxins, and volatile organic compounds in particular, from gas streams is receiving increased attention as an energy efficient means to remediate those compounds. In this regard, remediation of trichloroethylene (TCE) in silent discharge plasmas has been experimentally and theoretically investigated. We found that TCE can be removed from Ar/O2 gas streams at atmospheric pressure with an energy efficiency of 15–20 ppm/(mJ/cm3), or 2–3 kW h kg−1. The majority of the Cl from TCE is converted to HCl, Cl2, and COCl2, which can be removed from the gas stream by a water bubbler. The destruction efficiency of TCE is smaller in humid mixtures compared to dry mixtures due to interception of reactive intermediates by OH radicals.</description><identifier>ISSN: 0021-8979</identifier><identifier>EISSN: 1089-7550</identifier><identifier>DOI: 10.1063/1.354241</identifier><identifier>CODEN: JAPIAU</identifier><language>eng</language><publisher>Woodbury, NY: American Institute of Physics</publisher><subject>540220 -- Environment, Terrestrial-- Chemicals Monitoring &amp; Transport-- (1990-) ; 661300 -- Other Aspects of Physical Science-- (1992-) ; ANTIGENS ; Chemistry ; CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS ; DETOXIFICATION ; EFFICIENCY ; ELECTRIC DISCHARGES ; ENVIRONMENTAL SCIENCES ; Exact sciences and technology ; FLUID FLOW ; GAS FLOW ; HAZARDOUS MATERIALS ; Inorganic chemistry and origins of life ; Kinetics and mechanism of reactions ; MATERIALS ; ORGANIC CHLORINE COMPOUNDS ; ORGANIC COMPOUNDS ; ORGANIC HALOGEN COMPOUNDS ; PLASMA DIAGNOSTICS ; TOXIC MATERIALS 540120 -- Environment, Atmospheric-- Chemicals Monitoring &amp; Transport-- (1990-) ; TOXINS ; VOLATILITY</subject><ispartof>Journal of applied physics, 1993-11, Vol.74 (9), p.5378-5386</ispartof><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c347t-5f230f4db7998eae3d9390e98b53fe98e8c3b4615decf08257dd9cedfd3b3f4c3</citedby><cites>FETCH-LOGICAL-c347t-5f230f4db7998eae3d9390e98b53fe98e8c3b4615decf08257dd9cedfd3b3f4c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27903,27904</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=4085989$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5975252$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>EVANS, D</creatorcontrib><creatorcontrib>ROSOCHA, L. A</creatorcontrib><creatorcontrib>ANDERSON, G. K</creatorcontrib><creatorcontrib>COOGAN, J. J</creatorcontrib><creatorcontrib>KUSHNER, M. J</creatorcontrib><title>Plasma remediation of trichloroethylene in silent discharge plasmas</title><title>Journal of applied physics</title><description>Plasma destruction of toxins, and volatile organic compounds in particular, from gas streams is receiving increased attention as an energy efficient means to remediate those compounds. In this regard, remediation of trichloroethylene (TCE) in silent discharge plasmas has been experimentally and theoretically investigated. We found that TCE can be removed from Ar/O2 gas streams at atmospheric pressure with an energy efficiency of 15–20 ppm/(mJ/cm3), or 2–3 kW h kg−1. The majority of the Cl from TCE is converted to HCl, Cl2, and COCl2, which can be removed from the gas stream by a water bubbler. The destruction efficiency of TCE is smaller in humid mixtures compared to dry mixtures due to interception of reactive intermediates by OH radicals.</description><subject>540220 -- Environment, Terrestrial-- Chemicals Monitoring &amp; Transport-- (1990-)</subject><subject>661300 -- Other Aspects of Physical Science-- (1992-)</subject><subject>ANTIGENS</subject><subject>Chemistry</subject><subject>CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS</subject><subject>DETOXIFICATION</subject><subject>EFFICIENCY</subject><subject>ELECTRIC DISCHARGES</subject><subject>ENVIRONMENTAL SCIENCES</subject><subject>Exact sciences and technology</subject><subject>FLUID FLOW</subject><subject>GAS FLOW</subject><subject>HAZARDOUS MATERIALS</subject><subject>Inorganic chemistry and origins of life</subject><subject>Kinetics and mechanism of reactions</subject><subject>MATERIALS</subject><subject>ORGANIC CHLORINE COMPOUNDS</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC HALOGEN COMPOUNDS</subject><subject>PLASMA DIAGNOSTICS</subject><subject>TOXIC MATERIALS 540120 -- Environment, Atmospheric-- Chemicals Monitoring &amp; Transport-- (1990-)</subject><subject>TOXINS</subject><subject>VOLATILITY</subject><issn>0021-8979</issn><issn>1089-7550</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNo90DFPwzAQBWALgUQpSPwECzGwpNix3dgjqiggVYIB5sg5n4lRGle2l_57AkFM74bv3fAIueZsxdla3POVULKW_IQsONOmapRip2TBWM0rbRpzTi5y_mKMcy3MgmzeBpv3libcowu2hDjS6GlJAfohpoilPw44Ig0jzWG6CnUhQ2_TJ9LDbzdfkjNvh4xXf7kkH9vH981ztXt9etk87CoQsimV8rVgXrquMUajReGMMAyN7pTwU6AG0ck1Vw7BM12rxjkD6LwTnfASxJLczH9jLqHNEApCD3EcEUqrTKNqVU_obkaQYs4JfXtIYW_TseWs_Vmo5e280ERvZ3qwGezgkx0h5H8vmVZGG_ENBaFlsQ</recordid><startdate>19931101</startdate><enddate>19931101</enddate><creator>EVANS, D</creator><creator>ROSOCHA, L. A</creator><creator>ANDERSON, G. K</creator><creator>COOGAN, J. J</creator><creator>KUSHNER, M. J</creator><general>American Institute of Physics</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19931101</creationdate><title>Plasma remediation of trichloroethylene in silent discharge plasmas</title><author>EVANS, D ; ROSOCHA, L. A ; ANDERSON, G. K ; COOGAN, J. J ; KUSHNER, M. J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c347t-5f230f4db7998eae3d9390e98b53fe98e8c3b4615decf08257dd9cedfd3b3f4c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>540220 -- Environment, Terrestrial-- Chemicals Monitoring &amp; Transport-- (1990-)</topic><topic>661300 -- Other Aspects of Physical Science-- (1992-)</topic><topic>ANTIGENS</topic><topic>Chemistry</topic><topic>CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS</topic><topic>DETOXIFICATION</topic><topic>EFFICIENCY</topic><topic>ELECTRIC DISCHARGES</topic><topic>ENVIRONMENTAL SCIENCES</topic><topic>Exact sciences and technology</topic><topic>FLUID FLOW</topic><topic>GAS FLOW</topic><topic>HAZARDOUS MATERIALS</topic><topic>Inorganic chemistry and origins of life</topic><topic>Kinetics and mechanism of reactions</topic><topic>MATERIALS</topic><topic>ORGANIC CHLORINE COMPOUNDS</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC HALOGEN COMPOUNDS</topic><topic>PLASMA DIAGNOSTICS</topic><topic>TOXIC MATERIALS 540120 -- Environment, Atmospheric-- Chemicals Monitoring &amp; Transport-- (1990-)</topic><topic>TOXINS</topic><topic>VOLATILITY</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>EVANS, D</creatorcontrib><creatorcontrib>ROSOCHA, L. A</creatorcontrib><creatorcontrib>ANDERSON, G. K</creatorcontrib><creatorcontrib>COOGAN, J. J</creatorcontrib><creatorcontrib>KUSHNER, M. J</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of applied physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>EVANS, D</au><au>ROSOCHA, L. A</au><au>ANDERSON, G. K</au><au>COOGAN, J. J</au><au>KUSHNER, M. J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Plasma remediation of trichloroethylene in silent discharge plasmas</atitle><jtitle>Journal of applied physics</jtitle><date>1993-11-01</date><risdate>1993</risdate><volume>74</volume><issue>9</issue><spage>5378</spage><epage>5386</epage><pages>5378-5386</pages><issn>0021-8979</issn><eissn>1089-7550</eissn><coden>JAPIAU</coden><abstract>Plasma destruction of toxins, and volatile organic compounds in particular, from gas streams is receiving increased attention as an energy efficient means to remediate those compounds. In this regard, remediation of trichloroethylene (TCE) in silent discharge plasmas has been experimentally and theoretically investigated. We found that TCE can be removed from Ar/O2 gas streams at atmospheric pressure with an energy efficiency of 15–20 ppm/(mJ/cm3), or 2–3 kW h kg−1. The majority of the Cl from TCE is converted to HCl, Cl2, and COCl2, which can be removed from the gas stream by a water bubbler. The destruction efficiency of TCE is smaller in humid mixtures compared to dry mixtures due to interception of reactive intermediates by OH radicals.</abstract><cop>Woodbury, NY</cop><pub>American Institute of Physics</pub><doi>10.1063/1.354241</doi><tpages>9</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0021-8979
ispartof Journal of applied physics, 1993-11, Vol.74 (9), p.5378-5386
issn 0021-8979
1089-7550
language eng
recordid cdi_osti_scitechconnect_5975252
source AIP Digital Archive
subjects 540220 -- Environment, Terrestrial-- Chemicals Monitoring & Transport-- (1990-)
661300 -- Other Aspects of Physical Science-- (1992-)
ANTIGENS
Chemistry
CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS
DETOXIFICATION
EFFICIENCY
ELECTRIC DISCHARGES
ENVIRONMENTAL SCIENCES
Exact sciences and technology
FLUID FLOW
GAS FLOW
HAZARDOUS MATERIALS
Inorganic chemistry and origins of life
Kinetics and mechanism of reactions
MATERIALS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PLASMA DIAGNOSTICS
TOXIC MATERIALS 540120 -- Environment, Atmospheric-- Chemicals Monitoring & Transport-- (1990-)
TOXINS
VOLATILITY
title Plasma remediation of trichloroethylene in silent discharge plasmas
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-28T07%3A22%3A23IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pascalfrancis_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Plasma%20remediation%20of%20trichloroethylene%20in%20silent%20discharge%20plasmas&rft.jtitle=Journal%20of%20applied%20physics&rft.au=EVANS,%20D&rft.date=1993-11-01&rft.volume=74&rft.issue=9&rft.spage=5378&rft.epage=5386&rft.pages=5378-5386&rft.issn=0021-8979&rft.eissn=1089-7550&rft.coden=JAPIAU&rft_id=info:doi/10.1063/1.354241&rft_dat=%3Cpascalfrancis_osti_%3E4085989%3C/pascalfrancis_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true