Selective acetylation of porphyrins possessing a free pyrrolic position as a tool for petroporphyrin analysis. A reinvestigation

Friedel-Crafts acetylation of petroporphyrins is a useful method for discriminating between fully and partially alkylated macrocycles (pyrrolic positions). A reinvestigation of this reaction led to a better understanding of its course and to a optimization of the conditions, as a function of the com...

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Veröffentlicht in:Energy & fuels 1990-11, Vol.4 (6), p.665-667
Hauptverfasser: Jeandon, C, Bauder, C, Callot, H. J
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container_issue 6
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container_title Energy & fuels
container_volume 4
creator Jeandon, C
Bauder, C
Callot, H. J
description Friedel-Crafts acetylation of petroporphyrins is a useful method for discriminating between fully and partially alkylated macrocycles (pyrrolic positions). A reinvestigation of this reaction led to a better understanding of its course and to a optimization of the conditions, as a function of the complexed metal (nickel or vanadium).
doi_str_mv 10.1021/ef00024a009
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identifier ISSN: 0887-0624
ispartof Energy & fuels, 1990-11, Vol.4 (6), p.665-667
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language eng
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source American Chemical Society Web Editions
subjects 02 PETROLEUM
023000 - Petroleum- Properties & Composition
04 OIL SHALES AND TAR SANDS
040500 - Oil Shales & Tar Sands- Properties & Composition
400201 - Chemical & Physicochemical Properties
ACETYLATION
ACYLATION
Applied sciences
CARBOXYLIC ACIDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
Crude oil, natural gas and petroleum products
Earth sciences
Earth, ocean, space
Energy
Exact sciences and technology
FRIEDEL-CRAFTS REACTION
Fuels
Geology and geochemistry. Geological and geochemical prospecting. Petroliferous series
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
Hydrocarbons
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
KINETICS
MAGNETIC RESONANCE
NICKEL COMPOUNDS
NUCLEAR MAGNETIC RESONANCE
OPTIMIZATION
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PORPHYRINS
Prospecting and exploration
Prospecting and production of crude oil, natural gas, oil shales and tar sands
REACTION KINETICS
RESONANCE
Sedimentary rocks
SPECTROPHOTOMETRY
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPOUNDS
title Selective acetylation of porphyrins possessing a free pyrrolic position as a tool for petroporphyrin analysis. A reinvestigation
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