Spontaneous Liquid/Liquid Displacement in a Capillary
When a two-phase column consisting of paraffin oil and silicon oil is placed in an otherwise air-filled, horizontal glass capillary, the column starts moving spontaneously. Silicon oil displaces paraffin oil, which in its turn displaces air at atmospheric conditions; a stable film of silicon oil is...
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| Veröffentlicht in: | Journal of colloid and interface science 1993-10, Vol.160 (2), p.397-404 |
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| container_title | Journal of colloid and interface science |
| container_volume | 160 |
| creator | Van Remoortere, Pieter Joos, Paul |
| description | When a two-phase column consisting of paraffin oil and silicon oil is placed in an otherwise air-filled, horizontal glass capillary, the column starts moving spontaneously. Silicon oil displaces paraffin oil, which in its turn displaces air at atmospheric conditions; a stable film of silicon oil is left at the receding silicon oil/air meniscus. The driving force for the motion is the difference in capillary pressure at the free interfaces. However, the column moves considerably more slowly than predicted by the driving forces; it appears that the forces resisting the motion at the moving liquid/liquid/solid line are much larger than one would expect on the basis of the interfacial tension and the viscosities of the two phase system. Some considerations are made on the relationship of the theory of Fowkes to our system. Also, a method for measuring low interfacial tensions between immiscible liquids is proposed. |
| doi_str_mv | 10.1006/jcis.1993.1411 |
| format | Article |
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| identifier | ISSN: 0021-9797 |
| ispartof | Journal of colloid and interface science, 1993-10, Vol.160 (2), p.397-404 |
| issn | 0021-9797 1095-7103 |
| language | eng |
| recordid | cdi_osti_scitechconnect_5865463 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | 02 PETROLEUM 020300 - Petroleum- Drilling & Production CAPILLARY FLOW Chemistry ENERGY SOURCES ENHANCED RECOVERY Exact sciences and technology FLOW MODELS FLUID FLOW FOSSIL FUELS FUELS Gas-liquid interface and liquid-liquid interface General and physical chemistry INTERFACES MATHEMATICAL MODELS PETROLEUM PRESSURE GRADIENTS Surface physical chemistry SURFACE PROPERTIES SURFACE TENSION TWO-PHASE FLOW VISCOSITY |
| title | Spontaneous Liquid/Liquid Displacement in a Capillary |
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