Relaxation and the reentrant appearance of phases in molecular monolayer
The structure of monolayers of CH{sub 3}(CH{sub 2}){sub 22}COOH on water, along {similar to}21 {degree}C isotherms between 18 and 35 A {sup 2}/molecule, has been studied with glancing-angle x-ray diffraction and specular reflection. Following an incremental area change, in some regions of the isothe...
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| Veröffentlicht in: | Physical review letters 1991-03, Vol.66 (12), p.1599-1602 |
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| container_title | Physical review letters |
| container_volume | 66 |
| creator | SCHLOSSMAN, M. L SCHWARTZ, D. K PERSHAN, P. S KAWAMOTO, E. H KELLOGG, G. J LEE, S |
| description | The structure of monolayers of CH{sub 3}(CH{sub 2}){sub 22}COOH on water, along {similar to}21 {degree}C isotherms between 18 and 35 A {sup 2}/molecule, has been studied with glancing-angle x-ray diffraction and specular reflection. Following an incremental area change, in some regions of the isotherm, the diffraction pattern evolves until the surface pressure {pi} is relaxing {approx lt}0.01 dyn/cm h. Reentrant behavior between tilted and nontilted phases is observed. Phase coexistence is indicated by differences between the deposited area/molecule and the area of the x-ray-determined unit cell. |
| doi_str_mv | 10.1103/PhysRevLett.66.1599 |
| format | Article |
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L</creatorcontrib><creatorcontrib>SCHWARTZ, D. K</creatorcontrib><creatorcontrib>PERSHAN, P. S</creatorcontrib><creatorcontrib>KAWAMOTO, E. H</creatorcontrib><creatorcontrib>KELLOGG, G. J</creatorcontrib><creatorcontrib>LEE, S</creatorcontrib><title>Relaxation and the reentrant appearance of phases in molecular monolayer</title><title>Physical review letters</title><addtitle>Phys Rev Lett</addtitle><description>The structure of monolayers of CH{sub 3}(CH{sub 2}){sub 22}COOH on water, along {similar to}21 {degree}C isotherms between 18 and 35 A {sup 2}/molecule, has been studied with glancing-angle x-ray diffraction and specular reflection. Following an incremental area change, in some regions of the isotherm, the diffraction pattern evolves until the surface pressure {pi} is relaxing {approx lt}0.01 dyn/cm h. Reentrant behavior between tilted and nontilted phases is observed. Phase coexistence is indicated by differences between the deposited area/molecule and the area of the x-ray-determined unit cell.</description><subject>360602 - Other Materials- Structure & Phase Studies</subject><subject>COHERENT SCATTERING</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>CRYSTALS</subject><subject>DATA</subject><subject>DIFFRACTION</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>Fluid surfaces and fluid-fluid interfaces</subject><subject>HYDROGEN COMPOUNDS</subject><subject>INCIDENCE ANGLE</subject><subject>INFORMATION</subject><subject>ISOTHERMS</subject><subject>MATERIALS SCIENCE</subject><subject>MEDIUM TEMPERATURE</subject><subject>MOLECULAR CRYSTALS</subject><subject>NUMERICAL DATA</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC OXYGEN COMPOUNDS</subject><subject>OXYGEN COMPOUNDS</subject><subject>PHASE STUDIES</subject><subject>Physics</subject><subject>REFLECTION</subject><subject>RELAXATION</subject><subject>SCATTERING</subject><subject>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><subject>THIN FILMS</subject><subject>WATER</subject><subject>X-RAY DIFFRACTION</subject><issn>0031-9007</issn><issn>1079-7114</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><recordid>eNpNkMFq20AQhpeSUjtpn6AQRMghFzkz2tVKOpbQxAVDg2nPy3g1wgryrrq7LvXbV8Ym-DT_4ftnhk-IrwgLRJCPr9tDXPPfFae00HqBZdN8EHOEqskrRHUl5gAS8wagmonrGN8AAAtdfxIzBFCyKHEulmse6B-l3ruMXJulLWeB2aVALmU0jkxTspz5Lhu3FDlmvct2fmC7HyhMyfmBDhw-i48dDZG_nOeN-P38_dfTMl_9fPnx9G2VWwUq5SWQxa7QutNqIzeoWi6lBNUSdLXWuNG2bFFpVhZr2dZSEbXABdoJ77CVN-LutNfH1Jto-8R2a71zbJMpa6V0XU_Qwwkag_-z55jMro-Wh4Ec-300WJdNURUFVhMqT6gNPsbAnRlDv6NwMAjm6NlceDZam6PnqXV7PrDf7Li96JzETsD9GaBoaeiOEvv4zpXTn5VE-R_sg4hQ</recordid><startdate>19910325</startdate><enddate>19910325</enddate><creator>SCHLOSSMAN, M. 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L</creatorcontrib><creatorcontrib>SCHWARTZ, D. K</creatorcontrib><creatorcontrib>PERSHAN, P. S</creatorcontrib><creatorcontrib>KAWAMOTO, E. H</creatorcontrib><creatorcontrib>KELLOGG, G. J</creatorcontrib><creatorcontrib>LEE, S</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><jtitle>Physical review letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>SCHLOSSMAN, M. L</au><au>SCHWARTZ, D. K</au><au>PERSHAN, P. S</au><au>KAWAMOTO, E. H</au><au>KELLOGG, G. J</au><au>LEE, S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Relaxation and the reentrant appearance of phases in molecular monolayer</atitle><jtitle>Physical review letters</jtitle><addtitle>Phys Rev Lett</addtitle><date>1991-03-25</date><risdate>1991</risdate><volume>66</volume><issue>12</issue><spage>1599</spage><epage>1602</epage><pages>1599-1602</pages><issn>0031-9007</issn><eissn>1079-7114</eissn><coden>PRLTAO</coden><abstract>The structure of monolayers of CH{sub 3}(CH{sub 2}){sub 22}COOH on water, along {similar to}21 {degree}C isotherms between 18 and 35 A {sup 2}/molecule, has been studied with glancing-angle x-ray diffraction and specular reflection. Following an incremental area change, in some regions of the isotherm, the diffraction pattern evolves until the surface pressure {pi} is relaxing {approx lt}0.01 dyn/cm h. Reentrant behavior between tilted and nontilted phases is observed. Phase coexistence is indicated by differences between the deposited area/molecule and the area of the x-ray-determined unit cell.</abstract><cop>Ridge, NY</cop><pub>American Physical Society</pub><pmid>10043251</pmid><doi>10.1103/PhysRevLett.66.1599</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Physical review letters, 1991-03, Vol.66 (12), p.1599-1602 |
| issn | 0031-9007 1079-7114 |
| language | eng |
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| source | American Physical Society Journals |
| subjects | 360602 - Other Materials- Structure & Phase Studies COHERENT SCATTERING Condensed matter: structure, mechanical and thermal properties CRYSTALS DATA DIFFRACTION Exact sciences and technology EXPERIMENTAL DATA Fluid surfaces and fluid-fluid interfaces HYDROGEN COMPOUNDS INCIDENCE ANGLE INFORMATION ISOTHERMS MATERIALS SCIENCE MEDIUM TEMPERATURE MOLECULAR CRYSTALS NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC OXYGEN COMPOUNDS OXYGEN COMPOUNDS PHASE STUDIES Physics REFLECTION RELAXATION SCATTERING Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) THIN FILMS WATER X-RAY DIFFRACTION |
| title | Relaxation and the reentrant appearance of phases in molecular monolayer |
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