Abiotic loss of chemicals in soil

A laboratory study was conducted to evaluate the abiotic losses of organics in soil. 2,3- and 2,5-dichlorophenol were added to microcosms containing soil treated either by autoclaving or gamma irradiation or incubated under anoxic conditions. Biologically active aerobic microcosms were used as contr...

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Veröffentlicht in:Hazardous waste & hazardous materials 1988, Vol.5 (2), p.121-128
Hauptverfasser: ERICKSON, D. C, SPANIEL, K, LOEHR, R. C
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container_title Hazardous waste & hazardous materials
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creator ERICKSON, D. C
SPANIEL, K
LOEHR, R. C
description A laboratory study was conducted to evaluate the abiotic losses of organics in soil. 2,3- and 2,5-dichlorophenol were added to microcosms containing soil treated either by autoclaving or gamma irradiation or incubated under anoxic conditions. Biologically active aerobic microcosms were used as controls. Losses of the compounds were monitored using gas chromatography. Significant losses were observed in both the autoclaved and irradiated soils. Loss rates in the autoclaved soils were lowest; losses were greatest in the biologically active soils. Anoxic conditions slowed but did not stop the losses. Autoclaving and radiation appeared to increase the sorptive capacity of the soil. The study stresses the difficulty of achieving sterile conditions in soils, even when sound sterilization methods are used by competent analysts. Studies that report information about sterile conditions and abiotic losses of chemicals in soils should check for, and not presume, sterility in any tests that are conducted.
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Biologically active aerobic microcosms were used as controls. Losses of the compounds were monitored using gas chromatography. Significant losses were observed in both the autoclaved and irradiated soils. Loss rates in the autoclaved soils were lowest; losses were greatest in the biologically active soils. Anoxic conditions slowed but did not stop the losses. Autoclaving and radiation appeared to increase the sorptive capacity of the soil. The study stresses the difficulty of achieving sterile conditions in soils, even when sound sterilization methods are used by competent analysts. Studies that report information about sterile conditions and abiotic losses of chemicals in soils should check for, and not presume, sterility in any tests that are conducted.</abstract><cop>New York, NY</cop><pub>Liebert</pub><doi>10.1089/hwm.1988.5.121</doi><tpages>8</tpages></addata></record>
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identifier ISSN: 0882-5696
ispartof Hazardous waste & hazardous materials, 1988, Vol.5 (2), p.121-128
issn 0882-5696
2331-4591
language eng
recordid cdi_osti_scitechconnect_5765033
source Mary Ann Liebert Online
subjects 540220 - Environment, Terrestrial- Chemicals Monitoring & Transport- (1990-)
Agronomy. Soil science and plant productions
ANOXIA
AROMATICS
AUTOCLAVES
BENCH-SCALE EXPERIMENTS
Biological and medical sciences
CHLORINATED AROMATIC HYDROCARBONS
CHROMATOGRAPHY
CONTAMINATION
ELECTROMAGNETIC RADIATION
ENVIRONMENTAL SCIENCES
Fundamental and applied biological sciences. Psychology
GAMMA RADIATION
GAS CHROMATOGRAPHY
HALOGENATED AROMATIC HYDROCARBONS
IONIZING RADIATIONS
LOSSES
MICROCOSMS
MONITORING
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
RADIATIONS
SEPARATION PROCESSES
Soil and water pollution
Soil science
SOILS
SORPTIVE PROPERTIES
STERILIZATION
SURFACE PROPERTIES
title Abiotic loss of chemicals in soil
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