In situ Raman spectroscopy of reactions in supercritical water

The decomposition of hydrazine (N[sub 2]H[sub 4]) in near-critical and supercritical water is studied by in situ Raman spectroscopy. A high-pressure, high-temperature optical cell equipped with diamond windows allows us to perform Raman measurements at up to 430[degree]C and 350 atm of water. Using...

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Veröffentlicht in:	Journal of physical chemistry (1952) 1993-08, Vol.97 (33), p.8557-8559
Hauptverfasser:	Masten, David A, Foy, Bernard R, Harradine, David M, Dyer, R. Brian
Format:	Artikel
Sprache:	eng
Schlagworte:	400102 > Chemical & Spectral Procedures AMMONIA Atomic and molecular physics CARBON CHEMICAL REACTIONS Chemistry DECOMPOSITION DIAMONDS ELEMENTAL MINERALS ELEMENTS Exact sciences and technology HYDRAZINE HYDRIDES HYDROGEN COMPOUNDS Inorganic chemistry and origins of life INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KINETICS Kinetics and mechanism of reactions LASER SPECTROSCOPY MANAGEMENT MINERALS Molecular properties and interactions with photons Molecular spectra NITROGEN COMPOUNDS NITROGEN HYDRIDES NONMETALS OPENINGS OXYGEN COMPOUNDS Physics PROCESSING Raman and rayleigh spectra (including optical scattering) RAMAN SPECTROSCOPY REACTION KINETICS SPECTROSCOPY SUPERCRITICAL STATE WASTE MANAGEMENT 400201 > Chemical & Physicochemical Properties WASTE PROCESSING WATER WINDOWS
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