Small-angle x-ray scattering from zirconium(IV) hydrous tetramers
Small-angle X-ray scatterings (SAXS) data were collected for 0.035 - 1.0 M Zr(IV) in aqueous solution where the species present where hydroxyl-bridged tetramers. The scattering data were fitted to a cylindrical model with a radius of 4.8 {angstrom} and an aspect ratio of 2.3. Similar fits of the dat...
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| Veröffentlicht in: | Journal of physical chemistry (1952) 1991-04, Vol.95 (8), p.3106-3108 |
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| container_end_page | 3108 |
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| container_issue | 8 |
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| container_title | Journal of physical chemistry (1952) |
| container_volume | 95 |
| creator | Toth, L. M Lin, J. S Felker, L. K |
| description | Small-angle X-ray scatterings (SAXS) data were collected for 0.035 - 1.0 M Zr(IV) in aqueous solution where the species present where hydroxyl-bridged tetramers. The scattering data were fitted to a cylindrical model with a radius of 4.8 {angstrom} and an aspect ratio of 2.3. Similar fits of the data to spherical and elliptical models were also tested. These SAXS data have provided corroborative evidence for the existence of tetrameric species in aqueous solution. |
| doi_str_mv | 10.1021/j100161a028 |
| format | Article |
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M ; Lin, J. S ; Felker, L. K</creator><creatorcontrib>Toth, L. M ; Lin, J. S ; Felker, L. K</creatorcontrib><description>Small-angle X-ray scatterings (SAXS) data were collected for 0.035 - 1.0 M Zr(IV) in aqueous solution where the species present where hydroxyl-bridged tetramers. The scattering data were fitted to a cylindrical model with a radius of 4.8 {angstrom} and an aspect ratio of 2.3. Similar fits of the data to spherical and elliptical models were also tested. These SAXS data have provided corroborative evidence for the existence of tetrameric species in aqueous solution.</description><identifier>ISSN: 0022-3654</identifier><identifier>EISSN: 1541-5740</identifier><identifier>DOI: 10.1021/j100161a028</identifier><identifier>CODEN: JPCHAX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>400201 - Chemical & Physicochemical Properties ; Applied sciences ; AQUEOUS SOLUTIONS ; CHARGED PARTICLES ; DATA ; DATA ANALYSIS ; DISPERSIONS ; ELEMENTS ; Exact sciences and technology ; EXPERIMENTAL DATA ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; IONS ; LIGHT SCATTERING ; METALS ; MIXTURES ; NUMERICAL DATA ; Organic polymers ; Physicochemistry of polymers ; SCATTERING ; SMALL ANGLE SCATTERING ; SOLUTIONS ; THEORETICAL DATA ; TRANSITION ELEMENTS ; ZIRCONIUM ; ZIRCONIUM IONS</subject><ispartof>Journal of physical chemistry (1952), 1991-04, Vol.95 (8), p.3106-3108</ispartof><rights>1992 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a357t-13ab64026353c601ed76b0e08f63f04d28c5173c8d88e28d19fef4d0f78cdba03</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/j100161a028$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/j100161a028$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,780,784,885,2763,27075,27923,27924,56737,56787</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5403793$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5637097$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Toth, L. M</creatorcontrib><creatorcontrib>Lin, J. S</creatorcontrib><creatorcontrib>Felker, L. K</creatorcontrib><title>Small-angle x-ray scattering from zirconium(IV) hydrous tetramers</title><title>Journal of physical chemistry (1952)</title><addtitle>J. Phys. Chem</addtitle><description>Small-angle X-ray scatterings (SAXS) data were collected for 0.035 - 1.0 M Zr(IV) in aqueous solution where the species present where hydroxyl-bridged tetramers. The scattering data were fitted to a cylindrical model with a radius of 4.8 {angstrom} and an aspect ratio of 2.3. Similar fits of the data to spherical and elliptical models were also tested. These SAXS data have provided corroborative evidence for the existence of tetrameric species in aqueous solution.</description><subject>400201 - Chemical & Physicochemical Properties</subject><subject>Applied sciences</subject><subject>AQUEOUS SOLUTIONS</subject><subject>CHARGED PARTICLES</subject><subject>DATA</subject><subject>DATA ANALYSIS</subject><subject>DISPERSIONS</subject><subject>ELEMENTS</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>IONS</subject><subject>LIGHT SCATTERING</subject><subject>METALS</subject><subject>MIXTURES</subject><subject>NUMERICAL DATA</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>SCATTERING</subject><subject>SMALL ANGLE SCATTERING</subject><subject>SOLUTIONS</subject><subject>THEORETICAL DATA</subject><subject>TRANSITION ELEMENTS</subject><subject>ZIRCONIUM</subject><subject>ZIRCONIUM IONS</subject><issn>0022-3654</issn><issn>1541-5740</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><recordid>eNpt0EtLAzEQB_AgCtbqyS-wiKAi0clm8-ixFB-FgoVWD15Cmk3arfsoSQqtn96VFfHgaQ7zm2Hmj9A5gTsCKblfEwDCiYZUHqAeYRnBTGRwiHoAaYopZ9kxOglhDa2jlPTQcFbpssS6XpY22WGv90kwOkbri3qZON9UyWfhTVMX2-p6_HaTrPa5b7YhiTZ6XVkfTtGR02WwZz-1j14fH-ajZzx5eRqPhhOsKRMRE6oXPIOUU0YNB2JzwRdgQTpOHWR5Kg0jghqZS2lTmZOBsy7LwQlp8oUG2kcX3d4mxEIFU0RrVu1htTVRMU4FDESLbjtkfBOCt05tfFFpv1cE1HdE6k9Erb7s9Ea3T5fO69oU4XeEZUDFgLYMd6wI0e5-29p_KC6oYGo-nSmYyWz2LqaKt_6q89oEtW62vm5z-feAL2V5f54</recordid><startdate>19910401</startdate><enddate>19910401</enddate><creator>Toth, L. M</creator><creator>Lin, J. S</creator><creator>Felker, L. K</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19910401</creationdate><title>Small-angle x-ray scattering from zirconium(IV) hydrous tetramers</title><author>Toth, L. M ; Lin, J. S ; Felker, L. K</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a357t-13ab64026353c601ed76b0e08f63f04d28c5173c8d88e28d19fef4d0f78cdba03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1991</creationdate><topic>400201 - Chemical & Physicochemical Properties</topic><topic>Applied sciences</topic><topic>AQUEOUS SOLUTIONS</topic><topic>CHARGED PARTICLES</topic><topic>DATA</topic><topic>DATA ANALYSIS</topic><topic>DISPERSIONS</topic><topic>ELEMENTS</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>IONS</topic><topic>LIGHT SCATTERING</topic><topic>METALS</topic><topic>MIXTURES</topic><topic>NUMERICAL DATA</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>SCATTERING</topic><topic>SMALL ANGLE SCATTERING</topic><topic>SOLUTIONS</topic><topic>THEORETICAL DATA</topic><topic>TRANSITION ELEMENTS</topic><topic>ZIRCONIUM</topic><topic>ZIRCONIUM IONS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Toth, L. M</creatorcontrib><creatorcontrib>Lin, J. S</creatorcontrib><creatorcontrib>Felker, L. K</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of physical chemistry (1952)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Toth, L. M</au><au>Lin, J. S</au><au>Felker, L. K</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Small-angle x-ray scattering from zirconium(IV) hydrous tetramers</atitle><jtitle>Journal of physical chemistry (1952)</jtitle><addtitle>J. Phys. Chem</addtitle><date>1991-04-01</date><risdate>1991</risdate><volume>95</volume><issue>8</issue><spage>3106</spage><epage>3108</epage><pages>3106-3108</pages><issn>0022-3654</issn><eissn>1541-5740</eissn><coden>JPCHAX</coden><abstract>Small-angle X-ray scatterings (SAXS) data were collected for 0.035 - 1.0 M Zr(IV) in aqueous solution where the species present where hydroxyl-bridged tetramers. The scattering data were fitted to a cylindrical model with a radius of 4.8 {angstrom} and an aspect ratio of 2.3. Similar fits of the data to spherical and elliptical models were also tested. These SAXS data have provided corroborative evidence for the existence of tetrameric species in aqueous solution.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/j100161a028</doi><tpages>3</tpages></addata></record> |
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| ispartof | Journal of physical chemistry (1952), 1991-04, Vol.95 (8), p.3106-3108 |
| issn | 0022-3654 1541-5740 |
| language | eng |
| recordid | cdi_osti_scitechconnect_5637097 |
| source | ACS Publications |
| subjects | 400201 - Chemical & Physicochemical Properties Applied sciences AQUEOUS SOLUTIONS CHARGED PARTICLES DATA DATA ANALYSIS DISPERSIONS ELEMENTS Exact sciences and technology EXPERIMENTAL DATA INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONS LIGHT SCATTERING METALS MIXTURES NUMERICAL DATA Organic polymers Physicochemistry of polymers SCATTERING SMALL ANGLE SCATTERING SOLUTIONS THEORETICAL DATA TRANSITION ELEMENTS ZIRCONIUM ZIRCONIUM IONS |
| title | Small-angle x-ray scattering from zirconium(IV) hydrous tetramers |
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