Impedance spectroscopy as a nondestructive health interrogation tool for lithium-BCX cells
The objective of this investigation was to study the growth of thick passivating layers on the Li anode in Li/BCX (Li/SOCL[sub 2] + BrCl) cells which were stored for a period of 3 years. Impedance spectroscopy and equivalent circuit models were used to determine characterizing parameters for these c...
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| Veröffentlicht in: | Journal of the Electrochemical Society 1993-11, Vol.140 (11), p.3097-3103 |
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| container_end_page | 3103 |
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| container_issue | 11 |
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| container_title | Journal of the Electrochemical Society |
| container_volume | 140 |
| creator | POPOV, B. N ZHANG, W DARCY, E. C WHITE, R. E |
| description | The objective of this investigation was to study the growth of thick passivating layers on the Li anode in Li/BCX (Li/SOCL[sub 2] + BrCl) cells which were stored for a period of 3 years. Impedance spectroscopy and equivalent circuit models were used to determine characterizing parameters for these cells. The equivalent circuit used for virgin cells includes a faradic contribution and diffusion of the electroactive species. The equivalent circuit for batteries stored 1 or 2 years includes the impedance of a metal/passive film interface, the resistance of the film, and the impedance of the passivating film/electrolyte interface. The equivalent circuit used for batteries stored for 3 years accounts for cathodic contributions in the overall impedance spectrum. |
| doi_str_mv | 10.1149/1.2220992 |
| format | Article |
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N</creatorcontrib><creatorcontrib>ZHANG, W</creatorcontrib><creatorcontrib>DARCY, E. C</creatorcontrib><creatorcontrib>WHITE, R. E</creatorcontrib><title>Impedance spectroscopy as a nondestructive health interrogation tool for lithium-BCX cells</title><title>Journal of the Electrochemical Society</title><description>The objective of this investigation was to study the growth of thick passivating layers on the Li anode in Li/BCX (Li/SOCL[sub 2] + BrCl) cells which were stored for a period of 3 years. Impedance spectroscopy and equivalent circuit models were used to determine characterizing parameters for these cells. The equivalent circuit used for virgin cells includes a faradic contribution and diffusion of the electroactive species. The equivalent circuit for batteries stored 1 or 2 years includes the impedance of a metal/passive film interface, the resistance of the film, and the impedance of the passivating film/electrolyte interface. 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E</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Impedance spectroscopy as a nondestructive health interrogation tool for lithium-BCX cells</atitle><jtitle>Journal of the Electrochemical Society</jtitle><date>1993-11-01</date><risdate>1993</risdate><volume>140</volume><issue>11</issue><spage>3097</spage><epage>3103</epage><pages>3097-3103</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><coden>JESOAN</coden><abstract>The objective of this investigation was to study the growth of thick passivating layers on the Li anode in Li/BCX (Li/SOCL[sub 2] + BrCl) cells which were stored for a period of 3 years. Impedance spectroscopy and equivalent circuit models were used to determine characterizing parameters for these cells. The equivalent circuit used for virgin cells includes a faradic contribution and diffusion of the electroactive species. The equivalent circuit for batteries stored 1 or 2 years includes the impedance of a metal/passive film interface, the resistance of the film, and the impedance of the passivating film/electrolyte interface. The equivalent circuit used for batteries stored for 3 years accounts for cathodic contributions in the overall impedance spectrum.</abstract><cop>Pennington, NJ</cop><pub>Electrochemical Society</pub><doi>10.1149/1.2220992</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 0013-4651 |
| ispartof | Journal of the Electrochemical Society, 1993-11, Vol.140 (11), p.3097-3103 |
| issn | 0013-4651 1945-7111 |
| language | eng |
| recordid | cdi_osti_scitechconnect_5567989 |
| source | IOP Publishing Journals |
| subjects | 250902 - Energy Storage- Batteries- Performance & Testing 360105 - Metals & Alloys- Corrosion & Erosion ALKALI METAL COMPOUNDS ALKALI METALS ANODES BROMINE CHLORIDES BROMINE COMPOUNDS Chemistry CHLORIDES CHLORINE COMPOUNDS Electrochemistry ELECTRODES ELEMENTS ENERGY STORAGE Exact sciences and technology General and physical chemistry HALIDES HALOGEN COMPOUNDS Kinetics and mechanism of reactions LIFETIME LITHIUM LITHIUM CHLORIDES LITHIUM COMPOUNDS LITHIUM HALIDES MATERIALS SCIENCE METALS PASSIVATION PRIMARY BATTERIES SERVICE LIFE SULFUR CHLORIDES SULFUR COMPOUNDS |
| title | Impedance spectroscopy as a nondestructive health interrogation tool for lithium-BCX cells |
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