The Fe-FeO buffer at lower mantle pressures and temperatures

As a constraint on oxygen fugacity of the lower mantle, the iron‐wüstite (IW) oxygen buffer has been calculated for temperatures to 3000 K and pressures to 135 GPa using available thermochemical and thermophysical data for Fe, FeO, and O2. At conditions corresponding to the coremantle boundary and 6...

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Veröffentlicht in:Geophysical research letters 1991-07, Vol.18 (7), p.1309-1312
1. Verfasser: Hirsch, L. M.
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description As a constraint on oxygen fugacity of the lower mantle, the iron‐wüstite (IW) oxygen buffer has been calculated for temperatures to 3000 K and pressures to 135 GPa using available thermochemical and thermophysical data for Fe, FeO, and O2. At conditions corresponding to the coremantle boundary and 670 km depth, respectively, the oxygen fugacity of this buffer is 1020 and 10³ Pa; oxygen activities referenced to these conditions are 10−9 and 10−13.
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identifier ISSN: 0094-8276
ispartof Geophysical research letters, 1991-07, Vol.18 (7), p.1309-1312
issn 0094-8276
1944-8007
language eng
recordid cdi_osti_scitechconnect_5422466
source Wiley Online Library Journals Frontfile Complete
subjects 360606 - Other Materials- Physical Properties- (1992-)
580000 - Geosciences
Boundaries
Buffers
CALCULATION METHODS
CHALCOGENIDES
DEPTH
DIMENSIONS
EARTH CORE
EARTH MANTLE
ELEMENTS
Fugacity
Geophysics
GEOSCIENCES
INTERFACES
Iron
IRON COMPOUNDS
IRON OXIDES
Mantle
MATERIALS SCIENCE
Mathematical analysis
NONMETALS
OXIDES
OXYGEN
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
TEMPERATURE RANGE
TEMPERATURE RANGE 1000-4000 K
THERMODYNAMIC PROPERTIES
Thermophysical
TRANSITION ELEMENT COMPOUNDS
VAPOR PRESSURE
VERY HIGH PRESSURE
title The Fe-FeO buffer at lower mantle pressures and temperatures
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