Stability of beta alumina electrolyte in sodium/FeCl/sub 2/ (Zebra) cells
The authors describe how the stability of beta alumina in fully developed Zebra Na/FeCl/sub 2/ cells under long-term cycling has been proven. In the early stages of development of the Na/FeCl/sub 2/ cell, some problems in the form of increased resistances were encountered under certain extreme condi...
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| Veröffentlicht in: | Journal of the Electrochemical Society 1989-05, Vol.136:5 |
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| container_title | Journal of the Electrochemical Society |
| container_volume | 136:5 |
| creator | Moseley, P.T. Bones, R.J. Teagle, D.A. Bellamy, B.A. Hawes, R.W.M. |
| description | The authors describe how the stability of beta alumina in fully developed Zebra Na/FeCl/sub 2/ cells under long-term cycling has been proven. In the early stages of development of the Na/FeCl/sub 2/ cell, some problems in the form of increased resistances were encountered under certain extreme conditions of temperature and voltage. While these difficulties have now been overcome in practical cells, the scientific investigation into the causes of the anomalous resistance behavior showed it to be related to the interaction of the beta alumina with constituents of the positive electrode compartment. In particular, iron has been shown to enter beta alumina in the presence of an electric field when current is passing, if the cell is deliberately overheated. |
| doi_str_mv | 10.1149/1.2096922 |
| format | Article |
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In the early stages of development of the Na/FeCl/sub 2/ cell, some problems in the form of increased resistances were encountered under certain extreme conditions of temperature and voltage. While these difficulties have now been overcome in practical cells, the scientific investigation into the causes of the anomalous resistance behavior showed it to be related to the interaction of the beta alumina with constituents of the positive electrode compartment. In particular, iron has been shown to enter beta alumina in the presence of an electric field when current is passing, if the cell is deliberately overheated.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1.2096922</identifier><language>eng</language><publisher>United States</publisher><subject>30 DIRECT ENERGY CONVERSION ; 300503 - Fuel Cells- Materials, Components, & Auxiliaries ; 300505 - Fuel Cells- Electrochemistry, Mass Transfer & Thermodynamics ; 400400 - Electrochemistry ; ALUMINIUM COMPOUNDS ; ALUMINIUM OXIDES ; CHALCOGENIDES ; CHARGED PARTICLES ; CHEMICAL REACTION KINETICS ; CHEMISTRY ; CHLORIDES ; CHLORINE COMPOUNDS ; DIRECT ENERGY CONVERTERS ; ELECTRIC FIELDS ; ELECTRIC IMPEDANCE ; ELECTROCHEMICAL CELLS ; ELECTROCHEMISTRY ; ELECTRODES ; ELECTROLYTES ; FUEL CELLS ; HALIDES ; HALOGEN COMPOUNDS ; IMPEDANCE ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; IONS ; IRON CHLORIDES ; IRON COMPOUNDS ; KINETICS ; OXIDES ; OXYGEN COMPOUNDS ; REACTION KINETICS ; SODIUM IONS ; STABILITY ; TRANSITION ELEMENT COMPOUNDS</subject><ispartof>Journal of the Electrochemical Society, 1989-05, Vol.136:5</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27901,27902</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/5257830$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Moseley, P.T.</creatorcontrib><creatorcontrib>Bones, R.J.</creatorcontrib><creatorcontrib>Teagle, D.A.</creatorcontrib><creatorcontrib>Bellamy, B.A.</creatorcontrib><creatorcontrib>Hawes, R.W.M.</creatorcontrib><title>Stability of beta alumina electrolyte in sodium/FeCl/sub 2/ (Zebra) cells</title><title>Journal of the Electrochemical Society</title><description>The authors describe how the stability of beta alumina in fully developed Zebra Na/FeCl/sub 2/ cells under long-term cycling has been proven. In the early stages of development of the Na/FeCl/sub 2/ cell, some problems in the form of increased resistances were encountered under certain extreme conditions of temperature and voltage. While these difficulties have now been overcome in practical cells, the scientific investigation into the causes of the anomalous resistance behavior showed it to be related to the interaction of the beta alumina with constituents of the positive electrode compartment. 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In the early stages of development of the Na/FeCl/sub 2/ cell, some problems in the form of increased resistances were encountered under certain extreme conditions of temperature and voltage. While these difficulties have now been overcome in practical cells, the scientific investigation into the causes of the anomalous resistance behavior showed it to be related to the interaction of the beta alumina with constituents of the positive electrode compartment. In particular, iron has been shown to enter beta alumina in the presence of an electric field when current is passing, if the cell is deliberately overheated.</abstract><cop>United States</cop><doi>10.1149/1.2096922</doi></addata></record> |
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| ispartof | Journal of the Electrochemical Society, 1989-05, Vol.136:5 |
| issn | 0013-4651 1945-7111 |
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| subjects | 30 DIRECT ENERGY CONVERSION 300503 - Fuel Cells- Materials, Components, & Auxiliaries 300505 - Fuel Cells- Electrochemistry, Mass Transfer & Thermodynamics 400400 - Electrochemistry ALUMINIUM COMPOUNDS ALUMINIUM OXIDES CHALCOGENIDES CHARGED PARTICLES CHEMICAL REACTION KINETICS CHEMISTRY CHLORIDES CHLORINE COMPOUNDS DIRECT ENERGY CONVERTERS ELECTRIC FIELDS ELECTRIC IMPEDANCE ELECTROCHEMICAL CELLS ELECTROCHEMISTRY ELECTRODES ELECTROLYTES FUEL CELLS HALIDES HALOGEN COMPOUNDS IMPEDANCE INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONS IRON CHLORIDES IRON COMPOUNDS KINETICS OXIDES OXYGEN COMPOUNDS REACTION KINETICS SODIUM IONS STABILITY TRANSITION ELEMENT COMPOUNDS |
| title | Stability of beta alumina electrolyte in sodium/FeCl/sub 2/ (Zebra) cells |
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