Pressure broadening of deuterium hydride lines in the 5-0 vibrational band between 77 and 295 K

Self-braodening measurements have been made for the R(0) and R(1) lines of the 5-0 the vibration-rotation band of deuterium hydride. Pressure broadening coefficients and temperature-dependence indices have been determined from measurements over the temperature range of 77 to 295 K. A temperature-dep...

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Veröffentlicht in:Icarus (New York, N.Y. 1962) N.Y. 1962), 1991-06, Vol.91 (2), p.234-237
Hauptverfasser: Smith, Wm.Hayden, Keffer, Charles E., Connor, Charles P.
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Sprache:eng
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Zusammenfassung:Self-braodening measurements have been made for the R(0) and R(1) lines of the 5-0 the vibration-rotation band of deuterium hydride. Pressure broadening coefficients and temperature-dependence indices have been determined from measurements over the temperature range of 77 to 295 K. A temperature-dependent index, n, of 0.31 was derived for the HD lines studied. A provisional temperature-dependence index for H 2 vibrational-rotational line broadening as small or smaller that the HD index is suggested. A small temperature-dependence index significantly reduces the derived H 2 abundances in the outer planets and correspondingly increases the D/H ratios.
ISSN:0019-1035
1090-2643
DOI:10.1016/0019-1035(91)90021-K