Surface-enhanced resonance Raman spectroscopy as an ancillary high-performance liquid chromatography detector for nitrophenol compounds
In this study, the potential application of surface-enhanced resonance Raman scattering (SERRS) spectroscopy as an off-line secondary detector for HPLC has been evaluated. Four nitrophenol compounds, 2-nitrophenol, 4-nitrophenol, 2,4-dinitrophenol, and 4,6-dinitrocresol were separated by isocratic r...
Gespeichert in:
| Veröffentlicht in: | Analytical chemistry (Washington) 1989-04, Vol.61 (8), p.888-894 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 894 |
|---|---|
| container_issue | 8 |
| container_start_page | 888 |
| container_title | Analytical chemistry (Washington) |
| container_volume | 61 |
| creator | FAN NI THOMAS, L COTTON, T. M |
| description | In this study, the potential application of surface-enhanced resonance Raman scattering (SERRS) spectroscopy as an off-line secondary detector for HPLC has been evaluated. Four nitrophenol compounds, 2-nitrophenol, 4-nitrophenol, 2,4-dinitrophenol, and 4,6-dinitrocresol were separated by isocratic reverse-phase high-performance liquid chromatography (RP-HPLC) and monitored with a conventional UV detector. Resonance Raman (RR) and SERRS spectroscopy were next used to provide the required specificity for distinguishing the nitrophenol compounds. The SERRS detection limit for both 2-nitrophenol and 4-nitrophenol was calculated to be 14 ppb and that for 2,4-dinitrophenol and 4,6-dinitrocresol was estimated to lie near the parts-per-billion level as well. This detection limit is 2-3 orders of magnitude lower than that obtained by RR spectroscopy. |
| doi_str_mv | 10.1021/ac00183a021 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_5175303</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>78980300</sourcerecordid><originalsourceid>FETCH-LOGICAL-g298t-fafd60798b72d9c8512da7cc7e4c64f54097c02e05a57fdd123b3cb7d4b3ffa43</originalsourceid><addsrcrecordid>eNo9kEuP1TAMhSMEGu5cWLFGihCaXcFJ2qZdohEvaSQkHuvKdZLboDbpJO3i_gL-NhnmipUtn89H9mHslYB3AqR4jwQgOoWlf8IOopFQtV0nn7IDAKhKaoDn7Drn3wUTINordiW16KVuD-zPjz05JFvZMGEga3iyOYaHln_HBQPPq6UtxUxxPXPMvIyK6ucZ05lP_jRVq00upuXfzuzvd284TSkuuMVTwnU6c2O3YhITLxwPvtitkw1x5hSXNe7B5BfsmcM525eXemS_Pn38efuluvv2-evth7vqJPtuqxw604Luu1FL01PXCGlQE2lbU1u7poZeE0gLDTbaGSOkGhWN2tSjcg5rdWRvHn1j3vyQyZfDJoohlPuGRuhGgSrQzSO0pni_27wNi89ky8vBxj0Puus7UCXbI3t9AfdxsWZYk19KLMMl3qK_veiYCWeXHpLL_zEtZd3XUv0FH3yMVQ</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>78980300</pqid></control><display><type>article</type><title>Surface-enhanced resonance Raman spectroscopy as an ancillary high-performance liquid chromatography detector for nitrophenol compounds</title><source>MEDLINE</source><source>ACS Publications</source><creator>FAN NI ; THOMAS, L ; COTTON, T. M</creator><creatorcontrib>FAN NI ; THOMAS, L ; COTTON, T. M</creatorcontrib><description>In this study, the potential application of surface-enhanced resonance Raman scattering (SERRS) spectroscopy as an off-line secondary detector for HPLC has been evaluated. Four nitrophenol compounds, 2-nitrophenol, 4-nitrophenol, 2,4-dinitrophenol, and 4,6-dinitrocresol were separated by isocratic reverse-phase high-performance liquid chromatography (RP-HPLC) and monitored with a conventional UV detector. Resonance Raman (RR) and SERRS spectroscopy were next used to provide the required specificity for distinguishing the nitrophenol compounds. The SERRS detection limit for both 2-nitrophenol and 4-nitrophenol was calculated to be 14 ppb and that for 2,4-dinitrophenol and 4,6-dinitrocresol was estimated to lie near the parts-per-billion level as well. This detection limit is 2-3 orders of magnitude lower than that obtained by RR spectroscopy.</description><identifier>ISSN: 0003-2700</identifier><identifier>EISSN: 1520-6882</identifier><identifier>DOI: 10.1021/ac00183a021</identifier><identifier>PMID: 2719276</identifier><identifier>CODEN: ANCHAM</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>400102 - Chemical & Spectral Procedures ; 400105 - Separation Procedures ; 540320 - Environment, Aquatic- Chemicals Monitoring & Transport- (1990-) ; Analytical chemistry ; AROMATICS ; CHEMICAL ANALYSIS ; Chemistry ; Chromatographic methods and physical methods associated with chromatography ; CHROMATOGRAPHY ; Chromatography, High Pressure Liquid ; DATA ; ENVIRONMENTAL SCIENCES ; Exact sciences and technology ; EXPERIMENTAL DATA ; HYDROGEN COMPOUNDS ; HYDROXY COMPOUNDS ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; LASER SPECTROSCOPY ; LIQUID COLUMN CHROMATOGRAPHY ; MEASURING INSTRUMENTS ; MONITORS ; NITRO COMPOUNDS ; NITROPHENOL ; Nitrophenols - analysis ; NUMERICAL DATA ; ORGANIC COMPOUNDS ; ORGANIC NITROGEN COMPOUNDS ; Other chromatographic methods ; OXYGEN COMPOUNDS ; PHENOLS ; POLLUTANTS ; POLLUTION ; QUANTITATIVE CHEMICAL ANALYSIS ; RAMAN SPECTRA ; RAMAN SPECTROSCOPY ; SEPARATION PROCESSES ; SPECTRA ; SPECTROSCOPY ; Spectrum Analysis, Raman - methods ; TRACE AMOUNTS ; WATER ; WATER POLLUTION ; WATER POLLUTION MONITORS</subject><ispartof>Analytical chemistry (Washington), 1989-04, Vol.61 (8), p.888-894</ispartof><rights>1989 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7224942$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/2719276$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5175303$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>FAN NI</creatorcontrib><creatorcontrib>THOMAS, L</creatorcontrib><creatorcontrib>COTTON, T. M</creatorcontrib><title>Surface-enhanced resonance Raman spectroscopy as an ancillary high-performance liquid chromatography detector for nitrophenol compounds</title><title>Analytical chemistry (Washington)</title><addtitle>Anal Chem</addtitle><description>In this study, the potential application of surface-enhanced resonance Raman scattering (SERRS) spectroscopy as an off-line secondary detector for HPLC has been evaluated. Four nitrophenol compounds, 2-nitrophenol, 4-nitrophenol, 2,4-dinitrophenol, and 4,6-dinitrocresol were separated by isocratic reverse-phase high-performance liquid chromatography (RP-HPLC) and monitored with a conventional UV detector. Resonance Raman (RR) and SERRS spectroscopy were next used to provide the required specificity for distinguishing the nitrophenol compounds. The SERRS detection limit for both 2-nitrophenol and 4-nitrophenol was calculated to be 14 ppb and that for 2,4-dinitrophenol and 4,6-dinitrocresol was estimated to lie near the parts-per-billion level as well. This detection limit is 2-3 orders of magnitude lower than that obtained by RR spectroscopy.</description><subject>400102 - Chemical & Spectral Procedures</subject><subject>400105 - Separation Procedures</subject><subject>540320 - Environment, Aquatic- Chemicals Monitoring & Transport- (1990-)</subject><subject>Analytical chemistry</subject><subject>AROMATICS</subject><subject>CHEMICAL ANALYSIS</subject><subject>Chemistry</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>CHROMATOGRAPHY</subject><subject>Chromatography, High Pressure Liquid</subject><subject>DATA</subject><subject>ENVIRONMENTAL SCIENCES</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>HYDROGEN COMPOUNDS</subject><subject>HYDROXY COMPOUNDS</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>LASER SPECTROSCOPY</subject><subject>LIQUID COLUMN CHROMATOGRAPHY</subject><subject>MEASURING INSTRUMENTS</subject><subject>MONITORS</subject><subject>NITRO COMPOUNDS</subject><subject>NITROPHENOL</subject><subject>Nitrophenols - analysis</subject><subject>NUMERICAL DATA</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC NITROGEN COMPOUNDS</subject><subject>Other chromatographic methods</subject><subject>OXYGEN COMPOUNDS</subject><subject>PHENOLS</subject><subject>POLLUTANTS</subject><subject>POLLUTION</subject><subject>QUANTITATIVE CHEMICAL ANALYSIS</subject><subject>RAMAN SPECTRA</subject><subject>RAMAN SPECTROSCOPY</subject><subject>SEPARATION PROCESSES</subject><subject>SPECTRA</subject><subject>SPECTROSCOPY</subject><subject>Spectrum Analysis, Raman - methods</subject><subject>TRACE AMOUNTS</subject><subject>WATER</subject><subject>WATER POLLUTION</subject><subject>WATER POLLUTION MONITORS</subject><issn>0003-2700</issn><issn>1520-6882</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNo9kEuP1TAMhSMEGu5cWLFGihCaXcFJ2qZdohEvaSQkHuvKdZLboDbpJO3i_gL-NhnmipUtn89H9mHslYB3AqR4jwQgOoWlf8IOopFQtV0nn7IDAKhKaoDn7Drn3wUTINordiW16KVuD-zPjz05JFvZMGEga3iyOYaHln_HBQPPq6UtxUxxPXPMvIyK6ucZ05lP_jRVq00upuXfzuzvd284TSkuuMVTwnU6c2O3YhITLxwPvtitkw1x5hSXNe7B5BfsmcM525eXemS_Pn38efuluvv2-evth7vqJPtuqxw604Luu1FL01PXCGlQE2lbU1u7poZeE0gLDTbaGSOkGhWN2tSjcg5rdWRvHn1j3vyQyZfDJoohlPuGRuhGgSrQzSO0pni_27wNi89ky8vBxj0Puus7UCXbI3t9AfdxsWZYk19KLMMl3qK_veiYCWeXHpLL_zEtZd3XUv0FH3yMVQ</recordid><startdate>19890415</startdate><enddate>19890415</enddate><creator>FAN NI</creator><creator>THOMAS, L</creator><creator>COTTON, T. M</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>7X8</scope><scope>OTOTI</scope></search><sort><creationdate>19890415</creationdate><title>Surface-enhanced resonance Raman spectroscopy as an ancillary high-performance liquid chromatography detector for nitrophenol compounds</title><author>FAN NI ; THOMAS, L ; COTTON, T. M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g298t-fafd60798b72d9c8512da7cc7e4c64f54097c02e05a57fdd123b3cb7d4b3ffa43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>400102 - Chemical & Spectral Procedures</topic><topic>400105 - Separation Procedures</topic><topic>540320 - Environment, Aquatic- Chemicals Monitoring & Transport- (1990-)</topic><topic>Analytical chemistry</topic><topic>AROMATICS</topic><topic>CHEMICAL ANALYSIS</topic><topic>Chemistry</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>CHROMATOGRAPHY</topic><topic>Chromatography, High Pressure Liquid</topic><topic>DATA</topic><topic>ENVIRONMENTAL SCIENCES</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>HYDROGEN COMPOUNDS</topic><topic>HYDROXY COMPOUNDS</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>LASER SPECTROSCOPY</topic><topic>LIQUID COLUMN CHROMATOGRAPHY</topic><topic>MEASURING INSTRUMENTS</topic><topic>MONITORS</topic><topic>NITRO COMPOUNDS</topic><topic>NITROPHENOL</topic><topic>Nitrophenols - analysis</topic><topic>NUMERICAL DATA</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC NITROGEN COMPOUNDS</topic><topic>Other chromatographic methods</topic><topic>OXYGEN COMPOUNDS</topic><topic>PHENOLS</topic><topic>POLLUTANTS</topic><topic>POLLUTION</topic><topic>QUANTITATIVE CHEMICAL ANALYSIS</topic><topic>RAMAN SPECTRA</topic><topic>RAMAN SPECTROSCOPY</topic><topic>SEPARATION PROCESSES</topic><topic>SPECTRA</topic><topic>SPECTROSCOPY</topic><topic>Spectrum Analysis, Raman - methods</topic><topic>TRACE AMOUNTS</topic><topic>WATER</topic><topic>WATER POLLUTION</topic><topic>WATER POLLUTION MONITORS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>FAN NI</creatorcontrib><creatorcontrib>THOMAS, L</creatorcontrib><creatorcontrib>COTTON, T. M</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><jtitle>Analytical chemistry (Washington)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>FAN NI</au><au>THOMAS, L</au><au>COTTON, T. M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Surface-enhanced resonance Raman spectroscopy as an ancillary high-performance liquid chromatography detector for nitrophenol compounds</atitle><jtitle>Analytical chemistry (Washington)</jtitle><addtitle>Anal Chem</addtitle><date>1989-04-15</date><risdate>1989</risdate><volume>61</volume><issue>8</issue><spage>888</spage><epage>894</epage><pages>888-894</pages><issn>0003-2700</issn><eissn>1520-6882</eissn><coden>ANCHAM</coden><abstract>In this study, the potential application of surface-enhanced resonance Raman scattering (SERRS) spectroscopy as an off-line secondary detector for HPLC has been evaluated. Four nitrophenol compounds, 2-nitrophenol, 4-nitrophenol, 2,4-dinitrophenol, and 4,6-dinitrocresol were separated by isocratic reverse-phase high-performance liquid chromatography (RP-HPLC) and monitored with a conventional UV detector. Resonance Raman (RR) and SERRS spectroscopy were next used to provide the required specificity for distinguishing the nitrophenol compounds. The SERRS detection limit for both 2-nitrophenol and 4-nitrophenol was calculated to be 14 ppb and that for 2,4-dinitrophenol and 4,6-dinitrocresol was estimated to lie near the parts-per-billion level as well. This detection limit is 2-3 orders of magnitude lower than that obtained by RR spectroscopy.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>2719276</pmid><doi>10.1021/ac00183a021</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0003-2700 |
| ispartof | Analytical chemistry (Washington), 1989-04, Vol.61 (8), p.888-894 |
| issn | 0003-2700 1520-6882 |
| language | eng |
| recordid | cdi_osti_scitechconnect_5175303 |
| source | MEDLINE; ACS Publications |
| subjects | 400102 - Chemical & Spectral Procedures 400105 - Separation Procedures 540320 - Environment, Aquatic- Chemicals Monitoring & Transport- (1990-) Analytical chemistry AROMATICS CHEMICAL ANALYSIS Chemistry Chromatographic methods and physical methods associated with chromatography CHROMATOGRAPHY Chromatography, High Pressure Liquid DATA ENVIRONMENTAL SCIENCES Exact sciences and technology EXPERIMENTAL DATA HYDROGEN COMPOUNDS HYDROXY COMPOUNDS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LASER SPECTROSCOPY LIQUID COLUMN CHROMATOGRAPHY MEASURING INSTRUMENTS MONITORS NITRO COMPOUNDS NITROPHENOL Nitrophenols - analysis NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS Other chromatographic methods OXYGEN COMPOUNDS PHENOLS POLLUTANTS POLLUTION QUANTITATIVE CHEMICAL ANALYSIS RAMAN SPECTRA RAMAN SPECTROSCOPY SEPARATION PROCESSES SPECTRA SPECTROSCOPY Spectrum Analysis, Raman - methods TRACE AMOUNTS WATER WATER POLLUTION WATER POLLUTION MONITORS |
| title | Surface-enhanced resonance Raman spectroscopy as an ancillary high-performance liquid chromatography detector for nitrophenol compounds |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T09%3A12%3A13IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Surface-enhanced%20resonance%20Raman%20spectroscopy%20as%20an%20ancillary%20high-performance%20liquid%20chromatography%20detector%20for%20nitrophenol%20compounds&rft.jtitle=Analytical%20chemistry%20(Washington)&rft.au=FAN%20NI&rft.date=1989-04-15&rft.volume=61&rft.issue=8&rft.spage=888&rft.epage=894&rft.pages=888-894&rft.issn=0003-2700&rft.eissn=1520-6882&rft.coden=ANCHAM&rft_id=info:doi/10.1021/ac00183a021&rft_dat=%3Cproquest_osti_%3E78980300%3C/proquest_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=78980300&rft_id=info:pmid/2719276&rfr_iscdi=true |