A novel fluorescence detection method for organosilanes
Quinones such as phenanthraquinone and anthraquinone react with organosilanes giving persistent, strongly fluorescent radicals. The reactions are photochemically initiated, rapid, and facile; detection of concentrations of silanes in the 10{sup {minus}7} M range are readily achieved. The staring mat...
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Veröffentlicht in: | Analytical letters 1989-02, Vol.22 (2), p.419-426 |
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creator | YANG, H.-X CRAW, M. T DEPEW, M. C WAN, J. K. S |
description | Quinones such as phenanthraquinone and anthraquinone react with organosilanes giving persistent, strongly fluorescent radicals. The reactions are photochemically initiated, rapid, and facile; detection of concentrations of silanes in the 10{sup {minus}7} M range are readily achieved. The staring materials do not fluorescence making the procedure simple, selective and specific. |
doi_str_mv | 10.1080/00032718908052350 |
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The staring materials do not fluorescence making the procedure simple, selective and specific.</description><subject>400102 - Chemical & Spectral Procedures</subject><subject>400500 - Photochemistry</subject><subject>Analytical chemistry</subject><subject>AROMATICS</subject><subject>CHEMICAL ANALYSIS</subject><subject>CHEMICAL REACTIONS</subject><subject>CHEMISTRY</subject><subject>DATA</subject><subject>EMISSION SPECTROSCOPY</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>FLUORESCENCE</subject><subject>FLUORESCENCE SPECTROSCOPY</subject><subject>HYDRIDES</subject><subject>HYDROGEN COMPOUNDS</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>LUMINESCENCE</subject><subject>NUMERICAL DATA</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC OXYGEN COMPOUNDS</subject><subject>ORGANIC SILICON COMPOUNDS</subject><subject>PHOTOCHEMICAL REACTIONS</subject><subject>PHOTOCHEMISTRY</subject><subject>QUANTITATIVE CHEMICAL ANALYSIS</subject><subject>QUINONES</subject><subject>RADICALS</subject><subject>REACTION INTERMEDIATES</subject><subject>SILANES</subject><subject>SILICON COMPOUNDS</subject><subject>Spectrometric and optical methods</subject><subject>SPECTROSCOPY</subject><subject>TRACE AMOUNTS</subject><issn>0003-2719</issn><issn>1532-236X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNotjkFLxDAQRoMoWFd_gLciXqszSZu0x2XRVVjwouCtxGTiRrrJklTBf2-W9TR8zOPxGLtGuEPo4R4ABFfYD2V0XHRwwirsBG-4kO-nrDr8mwIM5-wi5y8A5D3HiqllHeIPTbWbvmOibCgYqi3NZGYfQ72jeRtt7WKqY_rUIWY_6UD5kp05PWW6-r8L9vb48Lp6ajYv6-fVctNEjjg3emjBkIFeGiFbUtSTENoeUjvOlUOUQB8SCYe2BTLOWuWEGngL1ukCL9jN0Rvz7MdsfAnbmhhC6Rs7VMWCBbo9QnudjZ5c0sH4PO6T3-n0OyqOxSjFH9toVM0</recordid><startdate>19890201</startdate><enddate>19890201</enddate><creator>YANG, H.-X</creator><creator>CRAW, M. 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S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-o211t-a940cec086c364e7e8e33ad32715227f1160eb61e19440ecfdd7f379240dfa8e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>400102 - Chemical & Spectral Procedures</topic><topic>400500 - Photochemistry</topic><topic>Analytical chemistry</topic><topic>AROMATICS</topic><topic>CHEMICAL ANALYSIS</topic><topic>CHEMICAL REACTIONS</topic><topic>CHEMISTRY</topic><topic>DATA</topic><topic>EMISSION SPECTROSCOPY</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>FLUORESCENCE</topic><topic>FLUORESCENCE SPECTROSCOPY</topic><topic>HYDRIDES</topic><topic>HYDROGEN COMPOUNDS</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>LUMINESCENCE</topic><topic>NUMERICAL DATA</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC OXYGEN COMPOUNDS</topic><topic>ORGANIC SILICON COMPOUNDS</topic><topic>PHOTOCHEMICAL REACTIONS</topic><topic>PHOTOCHEMISTRY</topic><topic>QUANTITATIVE CHEMICAL ANALYSIS</topic><topic>QUINONES</topic><topic>RADICALS</topic><topic>REACTION INTERMEDIATES</topic><topic>SILANES</topic><topic>SILICON COMPOUNDS</topic><topic>Spectrometric and optical methods</topic><topic>SPECTROSCOPY</topic><topic>TRACE AMOUNTS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>YANG, H.-X</creatorcontrib><creatorcontrib>CRAW, M. T</creatorcontrib><creatorcontrib>DEPEW, M. C</creatorcontrib><creatorcontrib>WAN, J. K. S</creatorcontrib><collection>Pascal-Francis</collection><collection>OSTI.GOV</collection><jtitle>Analytical letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>YANG, H.-X</au><au>CRAW, M. T</au><au>DEPEW, M. C</au><au>WAN, J. K. S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A novel fluorescence detection method for organosilanes</atitle><jtitle>Analytical letters</jtitle><date>1989-02-01</date><risdate>1989</risdate><volume>22</volume><issue>2</issue><spage>419</spage><epage>426</epage><pages>419-426</pages><issn>0003-2719</issn><eissn>1532-236X</eissn><coden>ANALBP</coden><abstract>Quinones such as phenanthraquinone and anthraquinone react with organosilanes giving persistent, strongly fluorescent radicals. The reactions are photochemically initiated, rapid, and facile; detection of concentrations of silanes in the 10{sup {minus}7} M range are readily achieved. The staring materials do not fluorescence making the procedure simple, selective and specific.</abstract><cop>Philadelphia, PA</cop><pub>Taylor & Francis</pub><doi>10.1080/00032718908052350</doi><tpages>8</tpages></addata></record> |
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source | Taylor & Francis Journals Complete |
subjects | 400102 - Chemical & Spectral Procedures 400500 - Photochemistry Analytical chemistry AROMATICS CHEMICAL ANALYSIS CHEMICAL REACTIONS CHEMISTRY DATA EMISSION SPECTROSCOPY Exact sciences and technology EXPERIMENTAL DATA FLUORESCENCE FLUORESCENCE SPECTROSCOPY HYDRIDES HYDROGEN COMPOUNDS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LUMINESCENCE NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC OXYGEN COMPOUNDS ORGANIC SILICON COMPOUNDS PHOTOCHEMICAL REACTIONS PHOTOCHEMISTRY QUANTITATIVE CHEMICAL ANALYSIS QUINONES RADICALS REACTION INTERMEDIATES SILANES SILICON COMPOUNDS Spectrometric and optical methods SPECTROSCOPY TRACE AMOUNTS |
title | A novel fluorescence detection method for organosilanes |
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