A novel fluorescence detection method for organosilanes

Quinones such as phenanthraquinone and anthraquinone react with organosilanes giving persistent, strongly fluorescent radicals. The reactions are photochemically initiated, rapid, and facile; detection of concentrations of silanes in the 10{sup {minus}7} M range are readily achieved. The staring mat...

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Veröffentlicht in:Analytical letters 1989-02, Vol.22 (2), p.419-426
Hauptverfasser: YANG, H.-X, CRAW, M. T, DEPEW, M. C, WAN, J. K. S
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container_title Analytical letters
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creator YANG, H.-X
CRAW, M. T
DEPEW, M. C
WAN, J. K. S
description Quinones such as phenanthraquinone and anthraquinone react with organosilanes giving persistent, strongly fluorescent radicals. The reactions are photochemically initiated, rapid, and facile; detection of concentrations of silanes in the 10{sup {minus}7} M range are readily achieved. The staring materials do not fluorescence making the procedure simple, selective and specific.
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ispartof Analytical letters, 1989-02, Vol.22 (2), p.419-426
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language eng
recordid cdi_osti_scitechconnect_5175221
source Taylor & Francis Journals Complete
subjects 400102 - Chemical & Spectral Procedures
400500 - Photochemistry
Analytical chemistry
AROMATICS
CHEMICAL ANALYSIS
CHEMICAL REACTIONS
CHEMISTRY
DATA
EMISSION SPECTROSCOPY
Exact sciences and technology
EXPERIMENTAL DATA
FLUORESCENCE
FLUORESCENCE SPECTROSCOPY
HYDRIDES
HYDROGEN COMPOUNDS
INFORMATION
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
LUMINESCENCE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SILICON COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOCHEMISTRY
QUANTITATIVE CHEMICAL ANALYSIS
QUINONES
RADICALS
REACTION INTERMEDIATES
SILANES
SILICON COMPOUNDS
Spectrometric and optical methods
SPECTROSCOPY
TRACE AMOUNTS
title A novel fluorescence detection method for organosilanes
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