Primary reduction and oxidation of thymine derivatives: ESR/ENDOR of thymidine and 1-methylthymine x-irradiated at 10 K

Single crystals of thymidine and 1-methylthymine were x-irradiated at 10 K and studied by using K-band ESR, ENDOR, and FSE spectroscopy. In thymidine, six primary radicals were identified. The major species were the O4-protonated anion (TI), the radical formed by net H addition to the C6 position of...

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Veröffentlicht in:	Journal of physical chemistry (1952) 1991-02, Vol.95 (3), p.1494-1503
Hauptverfasser:	Hole, Eli O, Sagstuen, Einar, Nelson, William H, Close, David M
Format:	Artikel
Sprache:	eng
Schlagworte:	400600 - Radiation Chemistry 560120 - Radiation Effects on Biochemicals, Cells, & Tissue Culture Atomic and molecular physics AZINES CHEMICAL RADIATION EFFECTS CRYSTALS DATA ELECTROMAGNETIC RADIATION ELECTRON SPIN RESONANCE Exact sciences and technology EXPERIMENTAL DATA HETEROCYCLIC COMPOUNDS INFORMATION IONIZING RADIATIONS MAGNETIC RESONANCE MEASURING METHODS Molecular properties and interactions with photons MONOCRYSTALS NUCLEIC ACIDS NUCLEOSIDES NUCLEOTIDES NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS Physics PYRIMIDINES RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY RADIATION EFFECTS RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTANT EFFECTS ON LIVING ORGS. AND BIOL. MAT RADIATIONS RESONANCE RIBOSIDES THYMIDINE ULTRALOW TEMPERATURE X RADIATION
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