Metal iodides: novel solution precursors to cuprate superconductors
YBa[sub 2]Cu[sub 3]O[sub 7[minus][delta]] of (YBCO) was produced through oxidation of a 1:2:3 mixture of YI[sub 3], BaI[sub 2]2H[sub 2]O, and CuI solids. TGA of the iodides revealed low-temperature oxidation below 600[degrees]C of the iodide precursors to the oxides. Thin oriented films of orthorhom...
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| Veröffentlicht in: | Chemistry of materials 1992-09, Vol.4 (5), p.984-987 |
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| creator | Baney, Ronald H Bergstrom, Debora F Justice, Bruce H |
| description | YBa[sub 2]Cu[sub 3]O[sub 7[minus][delta]] of (YBCO) was produced through oxidation of a 1:2:3 mixture of YI[sub 3], BaI[sub 2]2H[sub 2]O, and CuI solids. TGA of the iodides revealed low-temperature oxidation below 600[degrees]C of the iodide precursors to the oxides. Thin oriented films of orthorhombic YBCO were prepared by multiple spin coating, drying, and oxidizing solutions of the same solids mixture in acetonitrile/ethanol on a SrTiO[sub 3] single crystal. Confirmation of bulk and film structures were made with the aid of X-ray diffractograms, scanning electron and optical microscopy, and resistivity measurements. Typical zero resistance' behavior at 90 K was observed for the iodide precursor derived YBCO. |
| doi_str_mv | 10.1021/cm00023a011 |
| format | Article |
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TGA of the iodides revealed low-temperature oxidation below 600[degrees]C of the iodide precursors to the oxides. Thin oriented films of orthorhombic YBCO were prepared by multiple spin coating, drying, and oxidizing solutions of the same solids mixture in acetonitrile/ethanol on a SrTiO[sub 3] single crystal. Confirmation of bulk and film structures were made with the aid of X-ray diffractograms, scanning electron and optical microscopy, and resistivity measurements. Typical zero resistance' behavior at 90 K was observed for the iodide precursor derived YBCO.</description><identifier>ISSN: 0897-4756</identifier><identifier>EISSN: 1520-5002</identifier><identifier>DOI: 10.1021/cm00023a011</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>360201 - Ceramics, Cermets, & Refractories- Preparation & Fabrication ; 360207 - Ceramics, Cermets, & Refractories- Superconducting Properties- (1992-) ; ALKALINE EARTH METAL COMPOUNDS ; BARIUM COMPOUNDS ; BARIUM IODIDES ; BARIUM OXIDES ; CHALCOGENIDES ; CHEMICAL ANALYSIS ; CHEMICAL PREPARATION ; CHEMICAL REACTIONS ; COHERENT SCATTERING ; Condensed matter: structure, mechanical and thermal properties ; COPPER COMPOUNDS ; COPPER HALIDES ; COPPER IODIDES ; COPPER OXIDES ; CRYSTAL LATTICES ; CRYSTAL STRUCTURE ; DIFFRACTION ; ELECTRIC CONDUCTIVITY ; ELECTRICAL PROPERTIES ; ELECTRON MICROSCOPY ; Exact sciences and technology ; GRAVIMETRIC ANALYSIS ; HALIDES ; HALOGEN COMPOUNDS ; HIGH-TC SUPERCONDUCTORS ; IODIDES ; IODINE COMPOUNDS ; MATERIALS SCIENCE ; MICROSCOPY ; ORTHORHOMBIC LATTICES ; OXIDATION ; OXIDES ; OXYGEN COMPOUNDS ; PHYSICAL PROPERTIES ; Physics ; QUANTITATIVE CHEMICAL ANALYSIS ; SCANNING ELECTRON MICROSCOPY ; SCATTERING ; Solid surfaces and solid-solid interfaces ; STRUCTURAL CHEMICAL ANALYSIS ; SUPERCONDUCTORS ; Surface and interface dynamics and vibrations ; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties) ; SYNTHESIS ; THERMAL ANALYSIS ; THERMAL GRAVIMETRIC ANALYSIS ; Thin film structure and morphology ; TRANSITION ELEMENT COMPOUNDS ; X-RAY DIFFRACTION ; YTTRIUM COMPOUNDS ; YTTRIUM IODIDES ; YTTRIUM OXIDES</subject><ispartof>Chemistry of materials, 1992-09, Vol.4 (5), p.984-987</ispartof><rights>1993 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a359t-a41d6e8408ffc8af7170a488946ba74599650d1b5817e84102bd04d44fa546123</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cm00023a011$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cm00023a011$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,780,784,885,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4515638$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5155898$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Baney, Ronald H</creatorcontrib><creatorcontrib>Bergstrom, Debora F</creatorcontrib><creatorcontrib>Justice, Bruce H</creatorcontrib><title>Metal iodides: novel solution precursors to cuprate superconductors</title><title>Chemistry of materials</title><addtitle>Chem. Mater</addtitle><description>YBa[sub 2]Cu[sub 3]O[sub 7[minus][delta]] of (YBCO) was produced through oxidation of a 1:2:3 mixture of YI[sub 3], BaI[sub 2]2H[sub 2]O, and CuI solids. TGA of the iodides revealed low-temperature oxidation below 600[degrees]C of the iodide precursors to the oxides. Thin oriented films of orthorhombic YBCO were prepared by multiple spin coating, drying, and oxidizing solutions of the same solids mixture in acetonitrile/ethanol on a SrTiO[sub 3] single crystal. Confirmation of bulk and film structures were made with the aid of X-ray diffractograms, scanning electron and optical microscopy, and resistivity measurements. Typical zero resistance' behavior at 90 K was observed for the iodide precursor derived YBCO.</description><subject>360201 - Ceramics, Cermets, & Refractories- Preparation & Fabrication</subject><subject>360207 - Ceramics, Cermets, & Refractories- Superconducting Properties- (1992-)</subject><subject>ALKALINE EARTH METAL COMPOUNDS</subject><subject>BARIUM COMPOUNDS</subject><subject>BARIUM IODIDES</subject><subject>BARIUM OXIDES</subject><subject>CHALCOGENIDES</subject><subject>CHEMICAL ANALYSIS</subject><subject>CHEMICAL PREPARATION</subject><subject>CHEMICAL REACTIONS</subject><subject>COHERENT SCATTERING</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>COPPER COMPOUNDS</subject><subject>COPPER HALIDES</subject><subject>COPPER IODIDES</subject><subject>COPPER OXIDES</subject><subject>CRYSTAL LATTICES</subject><subject>CRYSTAL STRUCTURE</subject><subject>DIFFRACTION</subject><subject>ELECTRIC CONDUCTIVITY</subject><subject>ELECTRICAL PROPERTIES</subject><subject>ELECTRON MICROSCOPY</subject><subject>Exact sciences and technology</subject><subject>GRAVIMETRIC ANALYSIS</subject><subject>HALIDES</subject><subject>HALOGEN COMPOUNDS</subject><subject>HIGH-TC SUPERCONDUCTORS</subject><subject>IODIDES</subject><subject>IODINE COMPOUNDS</subject><subject>MATERIALS SCIENCE</subject><subject>MICROSCOPY</subject><subject>ORTHORHOMBIC LATTICES</subject><subject>OXIDATION</subject><subject>OXIDES</subject><subject>OXYGEN COMPOUNDS</subject><subject>PHYSICAL PROPERTIES</subject><subject>Physics</subject><subject>QUANTITATIVE CHEMICAL ANALYSIS</subject><subject>SCANNING ELECTRON MICROSCOPY</subject><subject>SCATTERING</subject><subject>Solid surfaces and solid-solid interfaces</subject><subject>STRUCTURAL CHEMICAL ANALYSIS</subject><subject>SUPERCONDUCTORS</subject><subject>Surface and interface dynamics and vibrations</subject><subject>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><subject>SYNTHESIS</subject><subject>THERMAL ANALYSIS</subject><subject>THERMAL GRAVIMETRIC ANALYSIS</subject><subject>Thin film structure and morphology</subject><subject>TRANSITION ELEMENT COMPOUNDS</subject><subject>X-RAY DIFFRACTION</subject><subject>YTTRIUM COMPOUNDS</subject><subject>YTTRIUM IODIDES</subject><subject>YTTRIUM OXIDES</subject><issn>0897-4756</issn><issn>1520-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1992</creationdate><recordtype>article</recordtype><recordid>eNpt0MtKxDAUBuAgCo6jK1-giOBCqkmbNKk7GXS8zOBt3LgJmTTFaG1KTir69maoDC5cBXK-c_j5Edon-ITgjJzqD4xxlitMyAYaEZbhlMWPTTTCouQp5azYRjsAbzgKnIkRmsxNUE1iXWUrA2dJ6z5Nk4Br-mBdm3Te6N6D85AEl-i-8yqYBPrOeO3aqtchjnbRVq0aMHu_7xg9X14sJlfp7G56PTmfpSpnZUgVJVVhBMWirrVQNSccKypESYul4pSVZcFwRZZMEB5ZzLesMK0orRWjBcnyMToY7joIVoK2wejXGKM1OkhGGBOliOh4QNo7AG9q2Xn7ofy3JFiuSpJ_Sor6cNCdAq2a2qtWW1iv0Hi1yFdH04FZCOZrPVb-XRY850wu7p_kdJ7dvhQ3j_Ih-qPBKw3yzfW-jb38G-AHuIOBPA</recordid><startdate>19920901</startdate><enddate>19920901</enddate><creator>Baney, Ronald H</creator><creator>Bergstrom, Debora F</creator><creator>Justice, Bruce H</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19920901</creationdate><title>Metal iodides: novel solution precursors to cuprate superconductors</title><author>Baney, Ronald H ; Bergstrom, Debora F ; Justice, Bruce H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a359t-a41d6e8408ffc8af7170a488946ba74599650d1b5817e84102bd04d44fa546123</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1992</creationdate><topic>360201 - Ceramics, Cermets, & Refractories- Preparation & Fabrication</topic><topic>360207 - Ceramics, Cermets, & Refractories- Superconducting Properties- (1992-)</topic><topic>ALKALINE EARTH METAL COMPOUNDS</topic><topic>BARIUM COMPOUNDS</topic><topic>BARIUM IODIDES</topic><topic>BARIUM OXIDES</topic><topic>CHALCOGENIDES</topic><topic>CHEMICAL ANALYSIS</topic><topic>CHEMICAL PREPARATION</topic><topic>CHEMICAL REACTIONS</topic><topic>COHERENT SCATTERING</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>COPPER COMPOUNDS</topic><topic>COPPER HALIDES</topic><topic>COPPER IODIDES</topic><topic>COPPER OXIDES</topic><topic>CRYSTAL LATTICES</topic><topic>CRYSTAL STRUCTURE</topic><topic>DIFFRACTION</topic><topic>ELECTRIC CONDUCTIVITY</topic><topic>ELECTRICAL PROPERTIES</topic><topic>ELECTRON MICROSCOPY</topic><topic>Exact sciences and technology</topic><topic>GRAVIMETRIC ANALYSIS</topic><topic>HALIDES</topic><topic>HALOGEN COMPOUNDS</topic><topic>HIGH-TC SUPERCONDUCTORS</topic><topic>IODIDES</topic><topic>IODINE COMPOUNDS</topic><topic>MATERIALS SCIENCE</topic><topic>MICROSCOPY</topic><topic>ORTHORHOMBIC LATTICES</topic><topic>OXIDATION</topic><topic>OXIDES</topic><topic>OXYGEN COMPOUNDS</topic><topic>PHYSICAL PROPERTIES</topic><topic>Physics</topic><topic>QUANTITATIVE CHEMICAL ANALYSIS</topic><topic>SCANNING ELECTRON MICROSCOPY</topic><topic>SCATTERING</topic><topic>Solid surfaces and solid-solid interfaces</topic><topic>STRUCTURAL CHEMICAL ANALYSIS</topic><topic>SUPERCONDUCTORS</topic><topic>Surface and interface dynamics and vibrations</topic><topic>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</topic><topic>SYNTHESIS</topic><topic>THERMAL ANALYSIS</topic><topic>THERMAL GRAVIMETRIC ANALYSIS</topic><topic>Thin film structure and morphology</topic><topic>TRANSITION ELEMENT COMPOUNDS</topic><topic>X-RAY DIFFRACTION</topic><topic>YTTRIUM COMPOUNDS</topic><topic>YTTRIUM IODIDES</topic><topic>YTTRIUM OXIDES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Baney, Ronald H</creatorcontrib><creatorcontrib>Bergstrom, Debora F</creatorcontrib><creatorcontrib>Justice, Bruce H</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Chemistry of materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Baney, Ronald H</au><au>Bergstrom, Debora F</au><au>Justice, Bruce H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal iodides: novel solution precursors to cuprate superconductors</atitle><jtitle>Chemistry of materials</jtitle><addtitle>Chem. Mater</addtitle><date>1992-09-01</date><risdate>1992</risdate><volume>4</volume><issue>5</issue><spage>984</spage><epage>987</epage><pages>984-987</pages><issn>0897-4756</issn><eissn>1520-5002</eissn><abstract>YBa[sub 2]Cu[sub 3]O[sub 7[minus][delta]] of (YBCO) was produced through oxidation of a 1:2:3 mixture of YI[sub 3], BaI[sub 2]2H[sub 2]O, and CuI solids. TGA of the iodides revealed low-temperature oxidation below 600[degrees]C of the iodide precursors to the oxides. Thin oriented films of orthorhombic YBCO were prepared by multiple spin coating, drying, and oxidizing solutions of the same solids mixture in acetonitrile/ethanol on a SrTiO[sub 3] single crystal. Confirmation of bulk and film structures were made with the aid of X-ray diffractograms, scanning electron and optical microscopy, and resistivity measurements. Typical zero resistance' behavior at 90 K was observed for the iodide precursor derived YBCO.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/cm00023a011</doi><tpages>4</tpages></addata></record> |
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| source | ACS Publications |
| subjects | 360201 - Ceramics, Cermets, & Refractories- Preparation & Fabrication 360207 - Ceramics, Cermets, & Refractories- Superconducting Properties- (1992-) ALKALINE EARTH METAL COMPOUNDS BARIUM COMPOUNDS BARIUM IODIDES BARIUM OXIDES CHALCOGENIDES CHEMICAL ANALYSIS CHEMICAL PREPARATION CHEMICAL REACTIONS COHERENT SCATTERING Condensed matter: structure, mechanical and thermal properties COPPER COMPOUNDS COPPER HALIDES COPPER IODIDES COPPER OXIDES CRYSTAL LATTICES CRYSTAL STRUCTURE DIFFRACTION ELECTRIC CONDUCTIVITY ELECTRICAL PROPERTIES ELECTRON MICROSCOPY Exact sciences and technology GRAVIMETRIC ANALYSIS HALIDES HALOGEN COMPOUNDS HIGH-TC SUPERCONDUCTORS IODIDES IODINE COMPOUNDS MATERIALS SCIENCE MICROSCOPY ORTHORHOMBIC LATTICES OXIDATION OXIDES OXYGEN COMPOUNDS PHYSICAL PROPERTIES Physics QUANTITATIVE CHEMICAL ANALYSIS SCANNING ELECTRON MICROSCOPY SCATTERING Solid surfaces and solid-solid interfaces STRUCTURAL CHEMICAL ANALYSIS SUPERCONDUCTORS Surface and interface dynamics and vibrations Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) SYNTHESIS THERMAL ANALYSIS THERMAL GRAVIMETRIC ANALYSIS Thin film structure and morphology TRANSITION ELEMENT COMPOUNDS X-RAY DIFFRACTION YTTRIUM COMPOUNDS YTTRIUM IODIDES YTTRIUM OXIDES |
| title | Metal iodides: novel solution precursors to cuprate superconductors |
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