Characterization of a water-in-oil microemulsion containing a concentrated ammonium ferric sulfate aqueous phase
A water-in-oil (w/o) microemulsion containing high concentrations of ammonium ferric sulfate in solution was characterized by SAXS, EXAFS, electrical conductivity, and viscosity measurements and by its phase behavior. The nanometer-sized aqueous droplets are microemulsified by sodium bis(2-ethylhexy...
Gespeichert in:
| Veröffentlicht in: | Langmuir 1994-01, Vol.10 (1), p.135-141 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 141 |
|---|---|
| container_issue | 1 |
| container_start_page | 135 |
| container_title | Langmuir |
| container_volume | 10 |
| creator | Darab, John G Pfund, David M Fulton, John L Linehan, John C Capel, Malcolm Ma, Yanjun |
| description | A water-in-oil (w/o) microemulsion containing high concentrations of ammonium ferric sulfate in solution was characterized by SAXS, EXAFS, electrical conductivity, and viscosity measurements and by its phase behavior. The nanometer-sized aqueous droplets are microemulsified by sodium bis(2-ethylhexyl) sulfosuccinate (AOT) in an isooctane continuous phase. Addition of small amounts of sodium dodecyl sulfate (SDS) as a cosurfactant greatly aids in the solubilization of the inorganic electrolyte-laden aqueous phase. For this five-component system there is a large region of the composition phase space that exists as a clear, stable w/o microemulsion. A portion of this w/o microemulsion phase space can be characterized as spherically shaped aqueous nanometer-sized droplets. A simple relationship between the total surfactant concentration and the amount of water on the droplet size was established. This relationship has the same form as the well-known relationship for the ternary system, AOT/water/isooctane. True thermodynamic equilibrium was not established in this microemulsion study because the reaction times for the various ferric oxyhydroxide species are prohibitively long. As a result, pseudoequilibria for this ammonium ferric sulfate microemulsion are reported. 31 refs., 7 figs., 1 tab. |
| doi_str_mv | 10.1021/la00013a020 |
| format | Article |
| fullrecord | <record><control><sourceid>istex_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_5147297</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_TPS_CF8KB2MS_Z</sourcerecordid><originalsourceid>FETCH-LOGICAL-a423t-f052a8c745df7c68912b31a1a75592ba6c0f8f48dfbe86564b76814d873dbc203</originalsourceid><addsrcrecordid>eNpt0MuOFCEUBmBiNLEdXfkCxJi4MKVcC2qpHUeNYzSZceOGnKLAZqyCHqDi5emlU2biwhWB80F-foQeU_KCEkZfzkAIoRwII3fQjkpGOqmZuot2RAneKdHz--hBKdeNDVwMO3TcHyCDrS6H31BDijh5DPgHtJMuxC6FGS_B5uSWdS6nuU2xQoghfmuubayLNTc-YViWFMO6YO9yDhaXdfZtgOFmdWkt-HiA4h6iex7m4h79Xc_Ql_M3V_t33cWnt-_3ry46EIzXzhPJQFsl5OSV7fVA2cgpUFBSDmyE3hKvvdCTH53uZS9G1WsqJq34NFpG-Bl6sr2bSg2m2FCdPbS40dlqJBWKDaqh5xtqHywlO2-OOSyQfxlKzKlR80-jTT_d9BGKhdlniDaU2yuCtrT8xLqNhVLdz9sx5O-mV1xJc_X50uzP9YfX7OOl-dr8s82DLeY6rTm2Xv4b4A8ieJKi</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Characterization of a water-in-oil microemulsion containing a concentrated ammonium ferric sulfate aqueous phase</title><source>ACS Publications</source><creator>Darab, John G ; Pfund, David M ; Fulton, John L ; Linehan, John C ; Capel, Malcolm ; Ma, Yanjun</creator><creatorcontrib>Darab, John G ; Pfund, David M ; Fulton, John L ; Linehan, John C ; Capel, Malcolm ; Ma, Yanjun</creatorcontrib><description>A water-in-oil (w/o) microemulsion containing high concentrations of ammonium ferric sulfate in solution was characterized by SAXS, EXAFS, electrical conductivity, and viscosity measurements and by its phase behavior. The nanometer-sized aqueous droplets are microemulsified by sodium bis(2-ethylhexyl) sulfosuccinate (AOT) in an isooctane continuous phase. Addition of small amounts of sodium dodecyl sulfate (SDS) as a cosurfactant greatly aids in the solubilization of the inorganic electrolyte-laden aqueous phase. For this five-component system there is a large region of the composition phase space that exists as a clear, stable w/o microemulsion. A portion of this w/o microemulsion phase space can be characterized as spherically shaped aqueous nanometer-sized droplets. A simple relationship between the total surfactant concentration and the amount of water on the droplet size was established. This relationship has the same form as the well-known relationship for the ternary system, AOT/water/isooctane. True thermodynamic equilibrium was not established in this microemulsion study because the reaction times for the various ferric oxyhydroxide species are prohibitively long. As a result, pseudoequilibria for this ammonium ferric sulfate microemulsion are reported. 31 refs., 7 figs., 1 tab.</description><identifier>ISSN: 0743-7463</identifier><identifier>EISSN: 1520-5827</identifier><identifier>DOI: 10.1021/la00013a020</identifier><identifier>CODEN: LANGD5</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>360602 - Other Materials- Structure & Phase Studies ; 400201 - Chemical & Physicochemical Properties ; AMMONIUM COMPOUNDS ; Chemistry ; Colloidal state and disperse state ; COLLOIDS ; DIAGRAMS ; DISPERSIONS ; ELECTRIC CONDUCTIVITY ; ELECTRICAL PROPERTIES ; ELECTROMAGNETIC RADIATION ; EMULSIONS ; Emulsions. Microemulsions. Foams ; Exact sciences and technology ; General and physical chemistry ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; IONIZING RADIATIONS ; IRON COMPOUNDS ; MATERIALS SCIENCE ; MICROEMULSIONS ; OXYGEN COMPOUNDS ; PHASE DIAGRAMS ; PHYSICAL PROPERTIES ; RADIATIONS ; SCATTERING ; SULFATES ; SULFUR COMPOUNDS ; SURFACTANTS ; TRANSITION ELEMENT COMPOUNDS ; VISCOSITY ; X RADIATION</subject><ispartof>Langmuir, 1994-01, Vol.10 (1), p.135-141</ispartof><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a423t-f052a8c745df7c68912b31a1a75592ba6c0f8f48dfbe86564b76814d873dbc203</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/la00013a020$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/la00013a020$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,780,784,885,2765,4024,27076,27923,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4174530$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5147297$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Darab, John G</creatorcontrib><creatorcontrib>Pfund, David M</creatorcontrib><creatorcontrib>Fulton, John L</creatorcontrib><creatorcontrib>Linehan, John C</creatorcontrib><creatorcontrib>Capel, Malcolm</creatorcontrib><creatorcontrib>Ma, Yanjun</creatorcontrib><title>Characterization of a water-in-oil microemulsion containing a concentrated ammonium ferric sulfate aqueous phase</title><title>Langmuir</title><addtitle>Langmuir</addtitle><description>A water-in-oil (w/o) microemulsion containing high concentrations of ammonium ferric sulfate in solution was characterized by SAXS, EXAFS, electrical conductivity, and viscosity measurements and by its phase behavior. The nanometer-sized aqueous droplets are microemulsified by sodium bis(2-ethylhexyl) sulfosuccinate (AOT) in an isooctane continuous phase. Addition of small amounts of sodium dodecyl sulfate (SDS) as a cosurfactant greatly aids in the solubilization of the inorganic electrolyte-laden aqueous phase. For this five-component system there is a large region of the composition phase space that exists as a clear, stable w/o microemulsion. A portion of this w/o microemulsion phase space can be characterized as spherically shaped aqueous nanometer-sized droplets. A simple relationship between the total surfactant concentration and the amount of water on the droplet size was established. This relationship has the same form as the well-known relationship for the ternary system, AOT/water/isooctane. True thermodynamic equilibrium was not established in this microemulsion study because the reaction times for the various ferric oxyhydroxide species are prohibitively long. As a result, pseudoequilibria for this ammonium ferric sulfate microemulsion are reported. 31 refs., 7 figs., 1 tab.</description><subject>360602 - Other Materials- Structure & Phase Studies</subject><subject>400201 - Chemical & Physicochemical Properties</subject><subject>AMMONIUM COMPOUNDS</subject><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>COLLOIDS</subject><subject>DIAGRAMS</subject><subject>DISPERSIONS</subject><subject>ELECTRIC CONDUCTIVITY</subject><subject>ELECTRICAL PROPERTIES</subject><subject>ELECTROMAGNETIC RADIATION</subject><subject>EMULSIONS</subject><subject>Emulsions. Microemulsions. Foams</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>IONIZING RADIATIONS</subject><subject>IRON COMPOUNDS</subject><subject>MATERIALS SCIENCE</subject><subject>MICROEMULSIONS</subject><subject>OXYGEN COMPOUNDS</subject><subject>PHASE DIAGRAMS</subject><subject>PHYSICAL PROPERTIES</subject><subject>RADIATIONS</subject><subject>SCATTERING</subject><subject>SULFATES</subject><subject>SULFUR COMPOUNDS</subject><subject>SURFACTANTS</subject><subject>TRANSITION ELEMENT COMPOUNDS</subject><subject>VISCOSITY</subject><subject>X RADIATION</subject><issn>0743-7463</issn><issn>1520-5827</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNpt0MuOFCEUBmBiNLEdXfkCxJi4MKVcC2qpHUeNYzSZceOGnKLAZqyCHqDi5emlU2biwhWB80F-foQeU_KCEkZfzkAIoRwII3fQjkpGOqmZuot2RAneKdHz--hBKdeNDVwMO3TcHyCDrS6H31BDijh5DPgHtJMuxC6FGS_B5uSWdS6nuU2xQoghfmuubayLNTc-YViWFMO6YO9yDhaXdfZtgOFmdWkt-HiA4h6iex7m4h79Xc_Ql_M3V_t33cWnt-_3ry46EIzXzhPJQFsl5OSV7fVA2cgpUFBSDmyE3hKvvdCTH53uZS9G1WsqJq34NFpG-Bl6sr2bSg2m2FCdPbS40dlqJBWKDaqh5xtqHywlO2-OOSyQfxlKzKlR80-jTT_d9BGKhdlniDaU2yuCtrT8xLqNhVLdz9sx5O-mV1xJc_X50uzP9YfX7OOl-dr8s82DLeY6rTm2Xv4b4A8ieJKi</recordid><startdate>19940101</startdate><enddate>19940101</enddate><creator>Darab, John G</creator><creator>Pfund, David M</creator><creator>Fulton, John L</creator><creator>Linehan, John C</creator><creator>Capel, Malcolm</creator><creator>Ma, Yanjun</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19940101</creationdate><title>Characterization of a water-in-oil microemulsion containing a concentrated ammonium ferric sulfate aqueous phase</title><author>Darab, John G ; Pfund, David M ; Fulton, John L ; Linehan, John C ; Capel, Malcolm ; Ma, Yanjun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a423t-f052a8c745df7c68912b31a1a75592ba6c0f8f48dfbe86564b76814d873dbc203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>360602 - Other Materials- Structure & Phase Studies</topic><topic>400201 - Chemical & Physicochemical Properties</topic><topic>AMMONIUM COMPOUNDS</topic><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>COLLOIDS</topic><topic>DIAGRAMS</topic><topic>DISPERSIONS</topic><topic>ELECTRIC CONDUCTIVITY</topic><topic>ELECTRICAL PROPERTIES</topic><topic>ELECTROMAGNETIC RADIATION</topic><topic>EMULSIONS</topic><topic>Emulsions. Microemulsions. Foams</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>IONIZING RADIATIONS</topic><topic>IRON COMPOUNDS</topic><topic>MATERIALS SCIENCE</topic><topic>MICROEMULSIONS</topic><topic>OXYGEN COMPOUNDS</topic><topic>PHASE DIAGRAMS</topic><topic>PHYSICAL PROPERTIES</topic><topic>RADIATIONS</topic><topic>SCATTERING</topic><topic>SULFATES</topic><topic>SULFUR COMPOUNDS</topic><topic>SURFACTANTS</topic><topic>TRANSITION ELEMENT COMPOUNDS</topic><topic>VISCOSITY</topic><topic>X RADIATION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Darab, John G</creatorcontrib><creatorcontrib>Pfund, David M</creatorcontrib><creatorcontrib>Fulton, John L</creatorcontrib><creatorcontrib>Linehan, John C</creatorcontrib><creatorcontrib>Capel, Malcolm</creatorcontrib><creatorcontrib>Ma, Yanjun</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Langmuir</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Darab, John G</au><au>Pfund, David M</au><au>Fulton, John L</au><au>Linehan, John C</au><au>Capel, Malcolm</au><au>Ma, Yanjun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization of a water-in-oil microemulsion containing a concentrated ammonium ferric sulfate aqueous phase</atitle><jtitle>Langmuir</jtitle><addtitle>Langmuir</addtitle><date>1994-01-01</date><risdate>1994</risdate><volume>10</volume><issue>1</issue><spage>135</spage><epage>141</epage><pages>135-141</pages><issn>0743-7463</issn><eissn>1520-5827</eissn><coden>LANGD5</coden><abstract>A water-in-oil (w/o) microemulsion containing high concentrations of ammonium ferric sulfate in solution was characterized by SAXS, EXAFS, electrical conductivity, and viscosity measurements and by its phase behavior. The nanometer-sized aqueous droplets are microemulsified by sodium bis(2-ethylhexyl) sulfosuccinate (AOT) in an isooctane continuous phase. Addition of small amounts of sodium dodecyl sulfate (SDS) as a cosurfactant greatly aids in the solubilization of the inorganic electrolyte-laden aqueous phase. For this five-component system there is a large region of the composition phase space that exists as a clear, stable w/o microemulsion. A portion of this w/o microemulsion phase space can be characterized as spherically shaped aqueous nanometer-sized droplets. A simple relationship between the total surfactant concentration and the amount of water on the droplet size was established. This relationship has the same form as the well-known relationship for the ternary system, AOT/water/isooctane. True thermodynamic equilibrium was not established in this microemulsion study because the reaction times for the various ferric oxyhydroxide species are prohibitively long. As a result, pseudoequilibria for this ammonium ferric sulfate microemulsion are reported. 31 refs., 7 figs., 1 tab.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/la00013a020</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0743-7463 |
| ispartof | Langmuir, 1994-01, Vol.10 (1), p.135-141 |
| issn | 0743-7463 1520-5827 |
| language | eng |
| recordid | cdi_osti_scitechconnect_5147297 |
| source | ACS Publications |
| subjects | 360602 - Other Materials- Structure & Phase Studies 400201 - Chemical & Physicochemical Properties AMMONIUM COMPOUNDS Chemistry Colloidal state and disperse state COLLOIDS DIAGRAMS DISPERSIONS ELECTRIC CONDUCTIVITY ELECTRICAL PROPERTIES ELECTROMAGNETIC RADIATION EMULSIONS Emulsions. Microemulsions. Foams Exact sciences and technology General and physical chemistry INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONIZING RADIATIONS IRON COMPOUNDS MATERIALS SCIENCE MICROEMULSIONS OXYGEN COMPOUNDS PHASE DIAGRAMS PHYSICAL PROPERTIES RADIATIONS SCATTERING SULFATES SULFUR COMPOUNDS SURFACTANTS TRANSITION ELEMENT COMPOUNDS VISCOSITY X RADIATION |
| title | Characterization of a water-in-oil microemulsion containing a concentrated ammonium ferric sulfate aqueous phase |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-22T20%3A27%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Characterization%20of%20a%20water-in-oil%20microemulsion%20containing%20a%20concentrated%20ammonium%20ferric%20sulfate%20aqueous%20phase&rft.jtitle=Langmuir&rft.au=Darab,%20John%20G&rft.date=1994-01-01&rft.volume=10&rft.issue=1&rft.spage=135&rft.epage=141&rft.pages=135-141&rft.issn=0743-7463&rft.eissn=1520-5827&rft.coden=LANGD5&rft_id=info:doi/10.1021/la00013a020&rft_dat=%3Cistex_osti_%3Eark_67375_TPS_CF8KB2MS_Z%3C/istex_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |