Charge Transport at High Pressures in toluene-n-pentane Mixtures
The drift mobility of negative carriers in mixtures of n-pentane and toluene under applied pressures up to 3 kbar is reported. Near 3 kbar, electrons are attached to toluene yet the observed mobility is considerably higher than that expected for ions at this pressure. The mobility decreases graduall...
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| Veröffentlicht in: | Journal of physical chemistry (1952) 1994-02, Vol.98 (7), p.1974-1977 |
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| container_end_page | 1977 |
|---|---|
| container_issue | 7 |
| container_start_page | 1974 |
| container_title | Journal of physical chemistry (1952) |
| container_volume | 98 |
| creator | Itoh, Kengo Ninomiya, Shiro Nishikawa, Masaru Holroyd, Richard A |
| description | The drift mobility of negative carriers in mixtures of n-pentane and toluene under applied pressures up to 3 kbar is reported. Near 3 kbar, electrons are attached to toluene yet the observed mobility is considerably higher than that expected for ions at this pressure. The mobility decreases gradually with increasing dilution by n-pentane and increases with increasing temperature. The results are consistent with a hopping mechanism whereby the electron transfers resonantly (isoenergetically) from a toluene anion to a neighboring toluene site. 11 refs., 4 figs., 2 tabs. |
| doi_str_mv | 10.1021/j100058a042 |
| format | Article |
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Near 3 kbar, electrons are attached to toluene yet the observed mobility is considerably higher than that expected for ions at this pressure. The mobility decreases gradually with increasing dilution by n-pentane and increases with increasing temperature. The results are consistent with a hopping mechanism whereby the electron transfers resonantly (isoenergetically) from a toluene anion to a neighboring toluene site. 11 refs., 4 figs., 2 tabs.</description><identifier>ISSN: 0022-3654</identifier><identifier>EISSN: 1541-5740</identifier><identifier>DOI: 10.1021/j100058a042</identifier><identifier>CODEN: JPCHAX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>400201 - Chemical & Physicochemical Properties ; 990200 - Mathematics & Computers ; ALKANES ; ALKYLATED AROMATICS ; AROMATICS ; CHARGE TRANSPORT ; Chemistry ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Conductivity of specific materials ; DATA ; DISPERSIONS ; ELECTRON TRANSFER ; Electronic transport in condensed matter ; Exact sciences and technology ; EXPERIMENTAL DATA ; GENERAL AND MISCELLANEOUS//MATHEMATICS, COMPUTING, AND INFORMATION SCIENCE ; General and physical chemistry ; HIGH PRESSURE ; HYDROCARBONS ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; Liquid semiconductors ; MATHEMATICAL MODELS ; MIXTURES ; NUMERICAL DATA ; ORGANIC COMPOUNDS ; PENTANE ; Physics ; PRESSURE DEPENDENCE ; Solution properties ; Solutions ; TEMPERATURE DEPENDENCE ; TOLUENE</subject><ispartof>Journal of physical chemistry (1952), 1994-02, Vol.98 (7), p.1974-1977</ispartof><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a423t-3f55420929b614db976385734a46bc3087b8b3adfc3c97b53cfbe1dbdb8f07753</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/j100058a042$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/j100058a042$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,780,784,885,2763,27074,27922,27923,56736,56786</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3995222$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5146171$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Itoh, Kengo</creatorcontrib><creatorcontrib>Ninomiya, Shiro</creatorcontrib><creatorcontrib>Nishikawa, Masaru</creatorcontrib><creatorcontrib>Holroyd, Richard A</creatorcontrib><title>Charge Transport at High Pressures in toluene-n-pentane Mixtures</title><title>Journal of physical chemistry (1952)</title><addtitle>J. Phys. Chem</addtitle><description>The drift mobility of negative carriers in mixtures of n-pentane and toluene under applied pressures up to 3 kbar is reported. Near 3 kbar, electrons are attached to toluene yet the observed mobility is considerably higher than that expected for ions at this pressure. The mobility decreases gradually with increasing dilution by n-pentane and increases with increasing temperature. 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Ninomiya, Shiro ; Nishikawa, Masaru ; Holroyd, Richard A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a423t-3f55420929b614db976385734a46bc3087b8b3adfc3c97b53cfbe1dbdb8f07753</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>400201 - Chemical & Physicochemical Properties</topic><topic>990200 - Mathematics & Computers</topic><topic>ALKANES</topic><topic>ALKYLATED AROMATICS</topic><topic>AROMATICS</topic><topic>CHARGE TRANSPORT</topic><topic>Chemistry</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Conductivity of specific materials</topic><topic>DATA</topic><topic>DISPERSIONS</topic><topic>ELECTRON TRANSFER</topic><topic>Electronic transport in condensed matter</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>GENERAL AND MISCELLANEOUS//MATHEMATICS, COMPUTING, AND INFORMATION SCIENCE</topic><topic>General and physical chemistry</topic><topic>HIGH PRESSURE</topic><topic>HYDROCARBONS</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>Liquid semiconductors</topic><topic>MATHEMATICAL MODELS</topic><topic>MIXTURES</topic><topic>NUMERICAL DATA</topic><topic>ORGANIC COMPOUNDS</topic><topic>PENTANE</topic><topic>Physics</topic><topic>PRESSURE DEPENDENCE</topic><topic>Solution properties</topic><topic>Solutions</topic><topic>TEMPERATURE DEPENDENCE</topic><topic>TOLUENE</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Itoh, Kengo</creatorcontrib><creatorcontrib>Ninomiya, Shiro</creatorcontrib><creatorcontrib>Nishikawa, Masaru</creatorcontrib><creatorcontrib>Holroyd, Richard A</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of physical chemistry (1952)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Itoh, Kengo</au><au>Ninomiya, Shiro</au><au>Nishikawa, Masaru</au><au>Holroyd, Richard A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Charge Transport at High Pressures in toluene-n-pentane Mixtures</atitle><jtitle>Journal of physical chemistry (1952)</jtitle><addtitle>J. Phys. Chem</addtitle><date>1994-02</date><risdate>1994</risdate><volume>98</volume><issue>7</issue><spage>1974</spage><epage>1977</epage><pages>1974-1977</pages><issn>0022-3654</issn><eissn>1541-5740</eissn><coden>JPCHAX</coden><abstract>The drift mobility of negative carriers in mixtures of n-pentane and toluene under applied pressures up to 3 kbar is reported. Near 3 kbar, electrons are attached to toluene yet the observed mobility is considerably higher than that expected for ions at this pressure. The mobility decreases gradually with increasing dilution by n-pentane and increases with increasing temperature. The results are consistent with a hopping mechanism whereby the electron transfers resonantly (isoenergetically) from a toluene anion to a neighboring toluene site. 11 refs., 4 figs., 2 tabs.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/j100058a042</doi><tpages>4</tpages></addata></record> |
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| identifier | ISSN: 0022-3654 |
| ispartof | Journal of physical chemistry (1952), 1994-02, Vol.98 (7), p.1974-1977 |
| issn | 0022-3654 1541-5740 |
| language | eng |
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| source | ACS Publications |
| subjects | 400201 - Chemical & Physicochemical Properties 990200 - Mathematics & Computers ALKANES ALKYLATED AROMATICS AROMATICS CHARGE TRANSPORT Chemistry Condensed matter: electronic structure, electrical, magnetic, and optical properties Conductivity of specific materials DATA DISPERSIONS ELECTRON TRANSFER Electronic transport in condensed matter Exact sciences and technology EXPERIMENTAL DATA GENERAL AND MISCELLANEOUS//MATHEMATICS, COMPUTING, AND INFORMATION SCIENCE General and physical chemistry HIGH PRESSURE HYDROCARBONS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Liquid semiconductors MATHEMATICAL MODELS MIXTURES NUMERICAL DATA ORGANIC COMPOUNDS PENTANE Physics PRESSURE DEPENDENCE Solution properties Solutions TEMPERATURE DEPENDENCE TOLUENE |
| title | Charge Transport at High Pressures in toluene-n-pentane Mixtures |
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