Electrosynthesis of KBiO[sub 3]: A potassium ion conductor with the KSbO[sub 3] tunnel structure

Cubic, anhydrous KBiO[sub 3] was synthesized by electrocrystallization from a KOH flux at 175[degrees]C. KBiO[sub 3] crystallizes in space group Im[bar 3] (No. 204) with Z = 12. The room-temperature data were refined to a = 10.0194 [angstrom], V = 1005.8 [angstrom][sup 3] and R = 2.3% for 576 unique...

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