Osmium(II)/ruthenium(II) trimetallics incorporating polyazine bridging ligands: isovalent near-IR absorbers with unique electrochemical behavior

A series of mixed-metal Os(II)/Ru(II) trimetallic complexes bridged by polypyridyl ligands have been prepared of general form ([(bpy)[sub 2]Ru(BL)][sub 2]OSCl[sub 2])[sup 4+] (where BL = 2,3-bis(2-pyridyl)pyrazine (dpp), 2,3-bis(2-pyridyl)-quinoxaline (dpq) and 2,3-bis(2-pyridyl) benzoquinoxaline (d...

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Veröffentlicht in:	Inorganic chemistry 1993-12, Vol.32 (25), p.5762-5768
Hauptverfasser:	Richter, Mark M, Brewer, Karen J
Format:	Artikel
Sprache:	eng
Schlagworte:	400400 - Electrochemistry ABSORPTION SPECTROSCOPY AZINES BIPYRIDINES CALCULATION METHODS CHEMICAL PREPARATION CHEMISTRY COMPLEXES Coordination compounds ELECTROCHEMISTRY Exact sciences and technology HETEROCYCLIC COMPOUNDS Inorganic chemistry and origins of life INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MOLECULAR ORBITAL METHOD ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS OSMIUM COMPLEXES Preparations and properties PYRIDINES RUTHENIUM COMPLEXES SPECTROSCOPY SYNTHESIS TRANSITION ELEMENT COMPLEXES VOLTAMETRY
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