Synthesis and characterizations of cyclometalated iridium(III) solvento complexes

Complexes of the type [Ir(L)[sub 2](S)[sub 2]][OTf] have been prepared by reactions of [Ir(L)[sub 2]Cl][sub 2] with AgOTf in an appropriate solvent medium (L = 2-phenylpyridine (ppy) or 2-(p-tolyl)pyridine (ptpy); S = H[sub 2]O or CH[sub 3]CN; OTf = CF[sub 3]SO[sub 3][sup [minus]]). These solvento c...

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