The Residual Entropy of the Equimolal KCl-KBr Solid Solution in Relation to Wasast Jerna's Theory of Alkali Halide Solid Solutions

Using the DELTA C/sub p/'s for the temperature range 12 to 300 deg K, the residual entropy was computed to be 1.39 plus or minus 0.04 eu or 1.37 plus or minus 0.04 eu. The values, which are very close to the entropy of random mixing, strongly suggest that there is a negligible amount of local o...

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Veröffentlicht in:	Journal of physical chemistry (1952) 1961-08, Vol.65 (8)
Hauptverfasser:	Milnes, M. V., Wallace, W. E.
Format:	Artikel
Sprache:	eng
Schlagworte:	ALKALI METALS ANIONS CHEMISTRY ENTROPY HALIDES LATTICES MIXING POTASSIUM BROMIDES POTASSIUM CHLORIDES SALTS SOLIDS SOLUTIONS TEMPERATURE
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