Radiation-induced Hydrolysis of Acetal: Evidence for the Reaction of H3O+ Ions in Spurs in the Radiolysis of Water
IT has recently been experimentally demonstrated that in water close to p H. 7 (ref. 1) and at p H. 4 (ref. 2), the reducing radical formed during radiolysis bears a unit negative charge. This suggests that an ejected electron escapes from its parent H 2 O + ion. It follows that H 2 O + ions should...
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| Veröffentlicht in: | Nature (London) 1963-10, Vol.200 (4901), p.66-67 |
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| container_end_page | 67 |
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| container_issue | 4901 |
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| container_title | Nature (London) |
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| creator | SMITH, D. R. STEVENS, W. H. |
| description | IT has recently been experimentally demonstrated that in water close to
p
H. 7 (ref. 1) and at
p
H. 4 (ref. 2), the reducing radical formed during radiolysis bears a unit negative charge. This suggests that an ejected electron escapes from its parent H
2
O
+
ion. It follows that H
2
O
+
ions should temporarily exist in a spur. The H
2
O
+
ions, or their hydrolysis products, H
3
O
+
(H
2
O
+
+ H
2
O→H
3
O
+
+· OH), might cause a suitable solute to ‘see’ a spur as a volume which temporarily has a lower
p
H than the body of the solution. The purpose of this communication is to present some experimental results which we interpret as evidence for this effect. |
| doi_str_mv | 10.1038/200066a0 |
| format | Article |
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p
H. 7 (ref. 1) and at
p
H. 4 (ref. 2), the reducing radical formed during radiolysis bears a unit negative charge. This suggests that an ejected electron escapes from its parent H
2
O
+
ion. It follows that H
2
O
+
ions should temporarily exist in a spur. The H
2
O
+
ions, or their hydrolysis products, H
3
O
+
(H
2
O
+
+ H
2
O→H
3
O
+
+· OH), might cause a suitable solute to ‘see’ a spur as a volume which temporarily has a lower
p
H than the body of the solution. The purpose of this communication is to present some experimental results which we interpret as evidence for this effect.</description><identifier>ISSN: 0028-0836</identifier><identifier>EISSN: 1476-4687</identifier><identifier>DOI: 10.1038/200066a0</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>ACETALDEHYDE ; ACETIC ACID ; ACIDITY ; AIR ; ALDEHYDES ; CATALYSIS ; CATIONS ; CHEMISTRY ; DECOMPOSITION ; ELECTRIC CHARGES ; ENERGY RANGE ; ETHANOL ; ETHYL RADICALS ; FREE RADICALS ; Humanities and Social Sciences ; HYDROGEN COMPOUNDS ; HYDROLYSIS ; IRRADIATION ; letter ; multidisciplinary ; RADIATION CHEMISTRY ; RADIOLYSIS ; REDUCTION ; Science ; Science (multidisciplinary) ; SOLUTIONS ; SPUR ; WATER ; X RADIATION</subject><ispartof>Nature (London), 1963-10, Vol.200 (4901), p.66-67</ispartof><rights>Springer Nature Limited 1963</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c286t-5db009ae39075d58526253f17ad64bc80b3c970162cee5082b12048bd1421daa3</citedby><cites>FETCH-LOGICAL-c286t-5db009ae39075d58526253f17ad64bc80b3c970162cee5082b12048bd1421daa3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1038/200066a0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1038/200066a0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,780,784,885,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/4701947$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>SMITH, D. R.</creatorcontrib><creatorcontrib>STEVENS, W. H.</creatorcontrib><creatorcontrib>Atomic Energy of Canada Ltd., Chalk River, Ont</creatorcontrib><title>Radiation-induced Hydrolysis of Acetal: Evidence for the Reaction of H3O+ Ions in Spurs in the Radiolysis of Water</title><title>Nature (London)</title><addtitle>Nature</addtitle><description>IT has recently been experimentally demonstrated that in water close to
p
H. 7 (ref. 1) and at
p
H. 4 (ref. 2), the reducing radical formed during radiolysis bears a unit negative charge. This suggests that an ejected electron escapes from its parent H
2
O
+
ion. It follows that H
2
O
+
ions should temporarily exist in a spur. The H
2
O
+
ions, or their hydrolysis products, H
3
O
+
(H
2
O
+
+ H
2
O→H
3
O
+
+· OH), might cause a suitable solute to ‘see’ a spur as a volume which temporarily has a lower
p
H than the body of the solution. The purpose of this communication is to present some experimental results which we interpret as evidence for this effect.</description><subject>ACETALDEHYDE</subject><subject>ACETIC ACID</subject><subject>ACIDITY</subject><subject>AIR</subject><subject>ALDEHYDES</subject><subject>CATALYSIS</subject><subject>CATIONS</subject><subject>CHEMISTRY</subject><subject>DECOMPOSITION</subject><subject>ELECTRIC CHARGES</subject><subject>ENERGY RANGE</subject><subject>ETHANOL</subject><subject>ETHYL RADICALS</subject><subject>FREE RADICALS</subject><subject>Humanities and Social Sciences</subject><subject>HYDROGEN COMPOUNDS</subject><subject>HYDROLYSIS</subject><subject>IRRADIATION</subject><subject>letter</subject><subject>multidisciplinary</subject><subject>RADIATION CHEMISTRY</subject><subject>RADIOLYSIS</subject><subject>REDUCTION</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><subject>SOLUTIONS</subject><subject>SPUR</subject><subject>WATER</subject><subject>X RADIATION</subject><issn>0028-0836</issn><issn>1476-4687</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1963</creationdate><recordtype>article</recordtype><recordid>eNpl0MFKAzEQBuAgCtYq-AjBkyKrk2w2m_VWSrWFQqEqHpdskrUpNSlJWujbu20VD55mDt__wwxC1wQeCOTikQIA5xJOUI-wkmeMi_IU9QCoyEDk_BxdxLjsUEFK1kNhLrWVyXqXWac3ymg83ungV7toI_YtHiiT5OoJj7ZWG6cMbn3AaWHw3Ei1z-3ROJ_d44l3EVuHX9ebcFgOqqv_K_uQyYRLdNbKVTRXP7OP3p9Hb8NxNp29TIaDaaao4CkrdANQSZNXUBa6EAXltMhbUkrNWaMENLmqSiCcKmMKELQhFJhoNGGUaCnzPro59vqYbB2VTUYtlHfOqFSzLlmxskO3R6SCjzGYtl4H-yXDriZQ7x9a_z60o3dHGjviPk2ol34TXHfCf_sNQl9ztQ</recordid><startdate>19631005</startdate><enddate>19631005</enddate><creator>SMITH, D. R.</creator><creator>STEVENS, W. H.</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19631005</creationdate><title>Radiation-induced Hydrolysis of Acetal: Evidence for the Reaction of H3O+ Ions in Spurs in the Radiolysis of Water</title><author>SMITH, D. R. ; STEVENS, W. H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c286t-5db009ae39075d58526253f17ad64bc80b3c970162cee5082b12048bd1421daa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1963</creationdate><topic>ACETALDEHYDE</topic><topic>ACETIC ACID</topic><topic>ACIDITY</topic><topic>AIR</topic><topic>ALDEHYDES</topic><topic>CATALYSIS</topic><topic>CATIONS</topic><topic>CHEMISTRY</topic><topic>DECOMPOSITION</topic><topic>ELECTRIC CHARGES</topic><topic>ENERGY RANGE</topic><topic>ETHANOL</topic><topic>ETHYL RADICALS</topic><topic>FREE RADICALS</topic><topic>Humanities and Social Sciences</topic><topic>HYDROGEN COMPOUNDS</topic><topic>HYDROLYSIS</topic><topic>IRRADIATION</topic><topic>letter</topic><topic>multidisciplinary</topic><topic>RADIATION CHEMISTRY</topic><topic>RADIOLYSIS</topic><topic>REDUCTION</topic><topic>Science</topic><topic>Science (multidisciplinary)</topic><topic>SOLUTIONS</topic><topic>SPUR</topic><topic>WATER</topic><topic>X RADIATION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>SMITH, D. R.</creatorcontrib><creatorcontrib>STEVENS, W. H.</creatorcontrib><creatorcontrib>Atomic Energy of Canada Ltd., Chalk River, Ont</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Nature (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>SMITH, D. R.</au><au>STEVENS, W. H.</au><aucorp>Atomic Energy of Canada Ltd., Chalk River, Ont</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Radiation-induced Hydrolysis of Acetal: Evidence for the Reaction of H3O+ Ions in Spurs in the Radiolysis of Water</atitle><jtitle>Nature (London)</jtitle><stitle>Nature</stitle><date>1963-10-05</date><risdate>1963</risdate><volume>200</volume><issue>4901</issue><spage>66</spage><epage>67</epage><pages>66-67</pages><issn>0028-0836</issn><eissn>1476-4687</eissn><abstract>IT has recently been experimentally demonstrated that in water close to
p
H. 7 (ref. 1) and at
p
H. 4 (ref. 2), the reducing radical formed during radiolysis bears a unit negative charge. This suggests that an ejected electron escapes from its parent H
2
O
+
ion. It follows that H
2
O
+
ions should temporarily exist in a spur. The H
2
O
+
ions, or their hydrolysis products, H
3
O
+
(H
2
O
+
+ H
2
O→H
3
O
+
+· OH), might cause a suitable solute to ‘see’ a spur as a volume which temporarily has a lower
p
H than the body of the solution. The purpose of this communication is to present some experimental results which we interpret as evidence for this effect.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><doi>10.1038/200066a0</doi><tpages>2</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0028-0836 |
| ispartof | Nature (London), 1963-10, Vol.200 (4901), p.66-67 |
| issn | 0028-0836 1476-4687 |
| language | eng |
| recordid | cdi_osti_scitechconnect_4701947 |
| source | Nature; SpringerLink Journals - AutoHoldings |
| subjects | ACETALDEHYDE ACETIC ACID ACIDITY AIR ALDEHYDES CATALYSIS CATIONS CHEMISTRY DECOMPOSITION ELECTRIC CHARGES ENERGY RANGE ETHANOL ETHYL RADICALS FREE RADICALS Humanities and Social Sciences HYDROGEN COMPOUNDS HYDROLYSIS IRRADIATION letter multidisciplinary RADIATION CHEMISTRY RADIOLYSIS REDUCTION Science Science (multidisciplinary) SOLUTIONS SPUR WATER X RADIATION |
| title | Radiation-induced Hydrolysis of Acetal: Evidence for the Reaction of H3O+ Ions in Spurs in the Radiolysis of Water |
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