Toward the Observation of the Tin and Lead Analogs of Formaldehyde

Heavy aldehyde and ketone analogues, R2XO (X = Si, Ge, Sn, or Pb), differ from their R2CO counterparts due to their greater tendency to oligeramize as the XO bond polarity increases as one goes down the periodic table. To date, H2SnO and H2PbO have eluded experimental detection. Herein we prese...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2022-11, Vol.126 (43), p.7930-7937
Hauptverfasser: Kitzmiller, Nathaniel L., Wolf, Mark E., Turney, Justin M., Schaefer, Henry F.
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Sprache:eng
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