Acidic Centers on the Surface of a Crystalline α-Sn(IV) Phosphate Characterized by the Solid-State 1 H, 2 H, 31 P, and 119 Sn MAS NMR Techniques
A layered crystalline phosphate α-Sn(HPO ) ·H O ( ), prepared and characterized in the present study by the multinuclear solid-state nuclear magnetic resonance (NMR), powder X-ray diffraction, and thermogravimetric analysis techniques, was treated with D O and HOD imitating the reaction conditions i...
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| Veröffentlicht in: | Inorganic chemistry 2022-11, Vol.61 (44), p.17759-17766 |
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| container_title | Inorganic chemistry |
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| creator | Bakhmutov, Vladimir I Elliott, Douglas W Contreras-Ramirez, Aida Drake, Hannah Zhou, Hong-Cai |
| description | A layered crystalline phosphate α-Sn(HPO
)
·H
O (
), prepared and characterized in the present study by the multinuclear solid-state nuclear magnetic resonance (NMR), powder X-ray diffraction, and thermogravimetric analysis techniques, was treated with D
O and HOD imitating the reaction conditions in a water medium. The
H solid-echo magic angle spinning NMR spectra of the products have revealed on their surface low mobile water molecules and hydronium ions, forming a structure close to the Zundel cation, [D
O···D-OD
]
. All the deuterons in the hydronium ions are tangled by hydrogen bonds with the water and the surface phosphate groups and stabilized by ionic interactions. |
| doi_str_mv | 10.1021/acs.inorgchem.2c03047 |
| format | Article |
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)
·H
O (
), prepared and characterized in the present study by the multinuclear solid-state nuclear magnetic resonance (NMR), powder X-ray diffraction, and thermogravimetric analysis techniques, was treated with D
O and HOD imitating the reaction conditions in a water medium. The
H solid-echo magic angle spinning NMR spectra of the products have revealed on their surface low mobile water molecules and hydronium ions, forming a structure close to the Zundel cation, [D
O···D-OD
]
. All the deuterons in the hydronium ions are tangled by hydrogen bonds with the water and the surface phosphate groups and stabilized by ionic interactions.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/acs.inorgchem.2c03047</identifier><identifier>PMID: 36269387</identifier><language>eng</language><publisher>United States: American Chemical Society (ACS)</publisher><subject>Cations ; Chemistry ; Hydrogen Bonding ; Magnetic Resonance Spectroscopy - methods ; Phosphates ; Water - chemistry</subject><ispartof>Inorganic chemistry, 2022-11, Vol.61 (44), p.17759-17766</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1487-4b77d3d4efb52d3d5e27ba2e7ed4815492e008daf1abfefa2fb40fbe0f57b973</citedby><cites>FETCH-LOGICAL-c1487-4b77d3d4efb52d3d5e27ba2e7ed4815492e008daf1abfefa2fb40fbe0f57b973</cites><orcidid>0000-0002-9029-3788 ; 0000-0002-5011-0385 ; 0000000250110385 ; 0000000290293788</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,2765,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36269387$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/2420657$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Bakhmutov, Vladimir I</creatorcontrib><creatorcontrib>Elliott, Douglas W</creatorcontrib><creatorcontrib>Contreras-Ramirez, Aida</creatorcontrib><creatorcontrib>Drake, Hannah</creatorcontrib><creatorcontrib>Zhou, Hong-Cai</creatorcontrib><creatorcontrib>Texas A & M Univ., College Station, TX (United States)</creatorcontrib><title>Acidic Centers on the Surface of a Crystalline α-Sn(IV) Phosphate Characterized by the Solid-State 1 H, 2 H, 31 P, and 119 Sn MAS NMR Techniques</title><title>Inorganic chemistry</title><addtitle>Inorg Chem</addtitle><description>A layered crystalline phosphate α-Sn(HPO
)
·H
O (
), prepared and characterized in the present study by the multinuclear solid-state nuclear magnetic resonance (NMR), powder X-ray diffraction, and thermogravimetric analysis techniques, was treated with D
O and HOD imitating the reaction conditions in a water medium. The
H solid-echo magic angle spinning NMR spectra of the products have revealed on their surface low mobile water molecules and hydronium ions, forming a structure close to the Zundel cation, [D
O···D-OD
]
. All the deuterons in the hydronium ions are tangled by hydrogen bonds with the water and the surface phosphate groups and stabilized by ionic interactions.</description><subject>Cations</subject><subject>Chemistry</subject><subject>Hydrogen Bonding</subject><subject>Magnetic Resonance Spectroscopy - methods</subject><subject>Phosphates</subject><subject>Water - chemistry</subject><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNo9kU1u2zAQhYmiReOkPUKLQVcJELkkRYnW0hDyByRtUBlFdwJ_hhEDm3JIeeHcIkfJRXKmyHCazcxbvO9hMI-Qb4xOGeXspzJp6kMf70yHqyk3NKdCfiATVnCaFYz--0gmlI6alWV1QA5TuqeUVrkoP5ODvORllc_khDzNjbfeQI1hwJigDzB0CM0mOmUQegcK6rhNg1oufUB4ec6acHz19wRuuz6tOzUg1J2Kyoy4f0QLertP6JfeZs2wMzC4PAW-GzmD21NQwQJjFTQBbuYN_Lr5Aws0XfAPG0xfyCenlgm_vu0jsjg_W9SX2fXvi6t6fp0ZJmYyE1pKm1uBThd8FAVyqRVHiVbMWCEqjpTOrHJMaYdOcacFdRqpK6SuZH5Efuxj-zT4Nhk_jBeYPgQ0Q8sFp2WxMxV7k4l9ShFdu45-peK2ZbTd1dCONbTvNbRvNYzc9z233ugV2nfq_9_zV0B_hc0</recordid><startdate>20221107</startdate><enddate>20221107</enddate><creator>Bakhmutov, Vladimir I</creator><creator>Elliott, Douglas W</creator><creator>Contreras-Ramirez, Aida</creator><creator>Drake, Hannah</creator><creator>Zhou, Hong-Cai</creator><general>American Chemical Society (ACS)</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0002-9029-3788</orcidid><orcidid>https://orcid.org/0000-0002-5011-0385</orcidid><orcidid>https://orcid.org/0000000250110385</orcidid><orcidid>https://orcid.org/0000000290293788</orcidid></search><sort><creationdate>20221107</creationdate><title>Acidic Centers on the Surface of a Crystalline α-Sn(IV) Phosphate Characterized by the Solid-State 1 H, 2 H, 31 P, and 119 Sn MAS NMR Techniques</title><author>Bakhmutov, Vladimir I ; Elliott, Douglas W ; Contreras-Ramirez, Aida ; Drake, Hannah ; Zhou, Hong-Cai</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1487-4b77d3d4efb52d3d5e27ba2e7ed4815492e008daf1abfefa2fb40fbe0f57b973</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Cations</topic><topic>Chemistry</topic><topic>Hydrogen Bonding</topic><topic>Magnetic Resonance Spectroscopy - methods</topic><topic>Phosphates</topic><topic>Water - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bakhmutov, Vladimir I</creatorcontrib><creatorcontrib>Elliott, Douglas W</creatorcontrib><creatorcontrib>Contreras-Ramirez, Aida</creatorcontrib><creatorcontrib>Drake, Hannah</creatorcontrib><creatorcontrib>Zhou, Hong-Cai</creatorcontrib><creatorcontrib>Texas A & M Univ., College Station, TX (United States)</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bakhmutov, Vladimir I</au><au>Elliott, Douglas W</au><au>Contreras-Ramirez, Aida</au><au>Drake, Hannah</au><au>Zhou, Hong-Cai</au><aucorp>Texas A & M Univ., College Station, TX (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Acidic Centers on the Surface of a Crystalline α-Sn(IV) Phosphate Characterized by the Solid-State 1 H, 2 H, 31 P, and 119 Sn MAS NMR Techniques</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg Chem</addtitle><date>2022-11-07</date><risdate>2022</risdate><volume>61</volume><issue>44</issue><spage>17759</spage><epage>17766</epage><pages>17759-17766</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>A layered crystalline phosphate α-Sn(HPO
)
·H
O (
), prepared and characterized in the present study by the multinuclear solid-state nuclear magnetic resonance (NMR), powder X-ray diffraction, and thermogravimetric analysis techniques, was treated with D
O and HOD imitating the reaction conditions in a water medium. The
H solid-echo magic angle spinning NMR spectra of the products have revealed on their surface low mobile water molecules and hydronium ions, forming a structure close to the Zundel cation, [D
O···D-OD
]
. All the deuterons in the hydronium ions are tangled by hydrogen bonds with the water and the surface phosphate groups and stabilized by ionic interactions.</abstract><cop>United States</cop><pub>American Chemical Society (ACS)</pub><pmid>36269387</pmid><doi>10.1021/acs.inorgchem.2c03047</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-9029-3788</orcidid><orcidid>https://orcid.org/0000-0002-5011-0385</orcidid><orcidid>https://orcid.org/0000000250110385</orcidid><orcidid>https://orcid.org/0000000290293788</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | Inorganic chemistry, 2022-11, Vol.61 (44), p.17759-17766 |
| issn | 0020-1669 1520-510X |
| language | eng |
| recordid | cdi_osti_scitechconnect_2420657 |
| source | MEDLINE; ACS Publications |
| subjects | Cations Chemistry Hydrogen Bonding Magnetic Resonance Spectroscopy - methods Phosphates Water - chemistry |
| title | Acidic Centers on the Surface of a Crystalline α-Sn(IV) Phosphate Characterized by the Solid-State 1 H, 2 H, 31 P, and 119 Sn MAS NMR Techniques |
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