Engineering Metal–Organic Frameworks for Selective Separation of Hexane Isomers Using 3‑Dimensional Linkers
Metal–organic frameworks (MOFs) are highly tunable materials with potential for use as porous media in non-thermal adsorption or membrane-based separations. However, many separations target molecules with sub-angstrom differences in size, requiring precise control over the pore size. Herein, we demo...
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| Veröffentlicht in: | Journal of the American Chemical Society 2023-03, Vol.145 (11), p.6434-6441 |
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| creator | Smoljan, Courtney S. Li, Zhao Xie, Haomiao Setter, Caitlin J. Idrees, Karam B. Son, Florencia A. Formalik, Filip Shafaie, Saman Islamoglu, Timur Macreadie, Lauren K. Snurr, Randall Q. Farha, Omar K. |
| description | Metal–organic frameworks (MOFs) are highly tunable materials with potential for use as porous media in non-thermal adsorption or membrane-based separations. However, many separations target molecules with sub-angstrom differences in size, requiring precise control over the pore size. Herein, we demonstrate that this precise control can be achieved by installing a three-dimensional linker in an MOF with one-dimensional channels. Specifically, we synthesized single crystals and bulk powder of NU-2002, an isostructural framework to MIL-53 with bicyclo[1.1.1]pentane-1,3-dicarboxylic acid as the organic linker component. Using variable-temperature X-ray diffraction studies, we show that increasing linker dimensionality limits structural breathing relative to MIL-53. Furthermore, single-component adsorption isotherms demonstrate the efficacy of this material for separating hexane isomers based on the different sizes and shapes of these isomers. |
| doi_str_mv | 10.1021/jacs.2c13715 |
| format | Article |
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| source | ACS Publications |
| subjects | Chemistry |
| title | Engineering Metal–Organic Frameworks for Selective Separation of Hexane Isomers Using 3‑Dimensional Linkers |
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