Reduction of (pddi)Cr reveals redox noninnocence via C-C bond formation amidst competing electrophilicity: [(cpta)CrMe n ] - ( n = 0, 1) and [(pta)Cr]

Reduction of (pddi)Cr reveals redox noninnocence via C-C bond formation amidst competing electrophilicity: [(cpta)CrMe n ] - ( n = 0, 1) and [(pta)Cr]

Reversible cyclopropane formation is probed as a means of redox noninnocence in diimine/diamide chelates reduction and complex anion formation. Competition from imine attack renders complications in the latter approach, and electrochemical measurements with calculational support provide the rational...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-06, Vol.60 (53), p.6785-6788
Hauptverfasser: D'Arpino, Alexander A, Wolczanski, Peter T, MacMillan, Samantha N, Cundari, Thomas R, Krumov, Mihail R
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Covalent bonds
Cyclopropane
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container_issue 53
container_start_page 6785
container_title Chemical communications (Cambridge, England)
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creator D'Arpino, Alexander A
Wolczanski, Peter T
MacMillan, Samantha N
Cundari, Thomas R
Krumov, Mihail R
description Reversible cyclopropane formation is probed as a means of redox noninnocence in diimine/diamide chelates reduction and complex anion formation. Competition from imine attack renders complications in the latter approach, and electrochemical measurements with calculational support provide the rationale.
doi_str_mv 10.1039/d4cc01690d
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Covalent bonds
Cyclopropane
title Reduction of (pddi)Cr reveals redox noninnocence via C-C bond formation amidst competing electrophilicity: [(cpta)CrMe n ] - ( n = 0, 1) and [(pta)Cr]
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