Kinetic Study of Polyvinyl Chloride Pyrolysis with Characterization of Dehydrochlorinated PVC

In this paper, we study the kinetics of polyvinyl chloride (PVC) decomposition using a combination of experimental and computational approaches. We develop a simplified kinetic model that contains only two steps: dehydrochlorination of PVC and further decomposition of the PVC residue. The model is c...

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Veröffentlicht in:	ACS sustainable chemistry & engineering 2024-05, Vol.12 (19), p.7402-7413
Hauptverfasser:	Wu, Jiayang, Papanikolaou, Konstantinos G., Cheng, Feng, Addison, Bennett, Cuthbertson, Amy A., Mavrikakis, Manos, Huber, George W.
Format:	Artikel
Sprache:	eng
Schlagworte:	benzene carbon chlorides crosslinking density functional theory DFT calculations Fourier transform infrared spectroscopy green chemistry homolytic cleavage hydrochloric acid INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY kinetic model kinetics nuclear magnetic resonance spectroscopy plastic pyrolysis poly(vinyl chloride) PVC dehydrochlorination pyrolysis thermogravimetry
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