Molecular Switch Cobalt Redox Shuttle with a Tunable Hexadentate Ligand

Strong-field hexadentate ligands were synthesized and coordinated to cobalt metal centers to result in three new low-spin to low-spin Co­(III/II) redox couples. The ligand backbone has been modified with dimethyl amine groups to result in redox potential tuning of the Co­(III/II) redox couples from...

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Veröffentlicht in:	Journal of the American Chemical Society 2023-01, Vol.145 (2), p.1367-1377
Hauptverfasser:	Raithel, Austin L., Meador, William E., Kim, Tea-Yon, Staples, Richard J., Delcamp, Jared H., Hamann, Thomas W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Cobalt Coloring Agents INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Ligands Oxidation-Reduction Sunlight
Online-Zugang:	Volltext
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