Morphology, UV–visible and ellipsometric studies of sodium lithium orthovanadate

Sodium lithium orthovanadates were prepared by the classic ceramic method technique. Structure, phase purity, composition, and morphology were characterized by X-ray powder diffraction, infrared spectroscopy, energy dispersive spectroscopy, scanning-electron microscopy and atomic force microscopy. T...

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Veröffentlicht in:Optical and quantum electronics 2019-09, Vol.51 (9), p.1-19, Article 299
Hauptverfasser: Enneffati, Marwa, Rasheed, Mohammed, Louati, Bassem, Guidara, Kamel, Barillé, Régis
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Rasheed, Mohammed
Louati, Bassem
Guidara, Kamel
Barillé, Régis
description Sodium lithium orthovanadates were prepared by the classic ceramic method technique. Structure, phase purity, composition, and morphology were characterized by X-ray powder diffraction, infrared spectroscopy, energy dispersive spectroscopy, scanning-electron microscopy and atomic force microscopy. The optical properties of Na x Li 1−x CdVO 4 (x = 0.5, 1) compounds prepared were recorded at room temperature using ultra-visible and ellipsometric spectroscopies in the spectral range (200–800) nm. The average reflectance of the pellets showed high reflectivity (over 80%) in the visible spectrum. The UV–Vis absorption bands are assigned to the charge transfer from the oxygen ligands to the central vanadium atom inside the [VO 4 ] 3− groups in the orthovanadate compounds. The optical band gaps E g of both samples are evaluated using Kubelka–Munk function. The analysis of the data revealed the existence of optical allowed direct transition for Na x Li 1−x CdVO 4 (x = 0.5, 1). Spectroscopic ellipsometry measurements have been performed on Na x Li 1−x CdVO 4 (x = 0.5, 1) specimens and their optical properties were analyzed using the Cauchy model.
doi_str_mv 10.1007/s11082-019-2015-5
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subjects ABSORPTION
Absorption spectra
ABSORPTION SPECTROSCOPY
ATOMIC FORCE MICROSCOPY
ATOMS
Characterization and Evaluation of Materials
Charge transfer
Computer Communication Networks
Electrical Engineering
ELLIPSOMETERS
ELLIPSOMETRY
IMPURITIES
INFRARED SPECTRA
Lasers
LIGANDS
Lithium
Microscopy
MORPHOLOGY
NANOSCIENCE AND NANOTECHNOLOGY
Optical Devices
Optical properties
Optics
PELLETS
Photonics
Physics
Physics and Astronomy
Reflectance
REFLECTIVITY
SCANNING ELECTRON MICROSCOPY
Spectroellipsometry
Spectrum analysis
TEMPERATURE RANGE 0273-0400 K
VANADATES
VANADIUM
Visible spectrum
X RADIATION
X ray powder diffraction
X-RAY DIFFRACTION
title Morphology, UV–visible and ellipsometric studies of sodium lithium orthovanadate
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