Six-coordinate nitrosyl complex of Co-meso-tetra-p-tolylporphyrin with a trans-1-methylimidazole ligand

Electron absorption and Fourier-transform IR spectroscopy was used to determine that the reaction of 1-methylimidazole (1-MeIm) with a nitrosyl complex of meso -tetra- p -tolylporphyrinate cobalt (Co(TTP)(NO)) at 210—240 K led to the formation of the six-coordinate complex (1-MeIm)Co(TTP)(NO), which...

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