Silica Supported Organometallic IrI Complexes Enable Efficient Catalytic Methane Borylation

Catalytic C–H borylation is an attractive method for the conversion of the most abundant hydrocarbon, methane (CH4), to a mild nucleophilic building block. However, existing CH4 borylation catalysts often suffer from low turnover numbers and conversions, which is hypothesized to result from inactive...

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Veröffentlicht in:	Journal of the American Chemical Society 2023-04, Vol.145 (14), p.7992-8000
Hauptverfasser:	Staples, Orion, Ferrandon, Magali S., Laurent, Guillaume P., Kanbur, Uddhav, Kropf, A. Jeremy, Gau, Michael R., Carroll, Patrick J., McCullough, Katherine, Sorsche, Dieter, Perras, Frédéric A., Delferro, Massimiliano, Kaphan, David M., Mindiola, Daniel J.
Format:	Artikel
Sprache:	eng
Schlagworte:	anions borylation catalysts INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ligands transition metals
Online-Zugang:	Volltext
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