The First Seven-Coordinated Triiodo Complex of Rhenium(III)

The reaction of cis -[ReO 2 I(P Ph 3 ) 2 ] with tert -butyl isocyanide in benzene led to the isolation of the complex [ReI 3 (CN- t -Bu) 3 (P Ph 3 )] ( 1 ). The complex is unusual since it contains bulky ligands with large cone angles, i.e. three iodides, three isocyanides with tert -butyl groups an...

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Veröffentlicht in:	Crystallography reports 2017-12, Vol.62 (7), p.1135-1137
Hauptverfasser:	Schoultz, X., Gerber, T. I. A., Betz, R., Hosten, E. C.
Format:	Artikel
Sprache:	eng
Schlagworte:	Angles (geometry) BENZENE CARBON NITRIDES Crystallography and Scattering Methods GEOMETRY INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IODIDES LIGANDS Physics Physics and Astronomy Rhenium RHENIUM COMPLEXES RHENIUM IONS Structure of Organic Compounds TRIPHENYLPHOSPHINE
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