The First Seven-Coordinated Triiodo Complex of Rhenium(III)
The reaction of cis -[ReO 2 I(P Ph 3 ) 2 ] with tert -butyl isocyanide in benzene led to the isolation of the complex [ReI 3 (CN- t -Bu) 3 (P Ph 3 )] ( 1 ). The complex is unusual since it contains bulky ligands with large cone angles, i.e. three iodides, three isocyanides with tert -butyl groups an...
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| Veröffentlicht in: | Crystallography reports 2017-12, Vol.62 (7), p.1135-1137 |
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| creator | Schoultz, X. Gerber, T. I. A. Betz, R. Hosten, E. C. |
| description | The reaction of
cis
-[ReO
2
I(P
Ph
3
)
2
] with
tert
-butyl isocyanide in benzene led to the isolation of the complex [ReI
3
(CN-
t
-Bu)
3
(P
Ph
3
)] (
1
). The complex is unusual since it contains bulky ligands with large cone angles, i.e. three iodides, three isocyanides with
tert
-butyl groups and a triphenylphosphine as ligands in a seven-coordinate geometry around the rhenium(III) metal ion. |
| doi_str_mv | 10.1134/S1063774517070239 |
| format | Article |
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cis
-[ReO
2
I(P
Ph
3
)
2
] with
tert
-butyl isocyanide in benzene led to the isolation of the complex [ReI
3
(CN-
t
-Bu)
3
(P
Ph
3
)] (
1
). The complex is unusual since it contains bulky ligands with large cone angles, i.e. three iodides, three isocyanides with
tert
-butyl groups and a triphenylphosphine as ligands in a seven-coordinate geometry around the rhenium(III) metal ion.</description><identifier>ISSN: 1063-7745</identifier><identifier>EISSN: 1562-689X</identifier><identifier>DOI: 10.1134/S1063774517070239</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Angles (geometry) ; BENZENE ; CARBON NITRIDES ; Crystallography and Scattering Methods ; GEOMETRY ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; IODIDES ; LIGANDS ; Physics ; Physics and Astronomy ; Rhenium ; RHENIUM COMPLEXES ; RHENIUM IONS ; Structure of Organic Compounds ; TRIPHENYLPHOSPHINE</subject><ispartof>Crystallography reports, 2017-12, Vol.62 (7), p.1135-1137</ispartof><rights>Pleiades Publishing, Inc. 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c333t-83e109305d974cdf633298ea330e56dcd4eeb4861787e4f0a3de8ac4733e374e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1063774517070239$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1063774517070239$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,776,780,881,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/22758293$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Schoultz, X.</creatorcontrib><creatorcontrib>Gerber, T. I. A.</creatorcontrib><creatorcontrib>Betz, R.</creatorcontrib><creatorcontrib>Hosten, E. C.</creatorcontrib><title>The First Seven-Coordinated Triiodo Complex of Rhenium(III)</title><title>Crystallography reports</title><addtitle>Crystallogr. Rep</addtitle><description>The reaction of
cis
-[ReO
2
I(P
Ph
3
)
2
] with
tert
-butyl isocyanide in benzene led to the isolation of the complex [ReI
3
(CN-
t
-Bu)
3
(P
Ph
3
)] (
1
). The complex is unusual since it contains bulky ligands with large cone angles, i.e. three iodides, three isocyanides with
tert
-butyl groups and a triphenylphosphine as ligands in a seven-coordinate geometry around the rhenium(III) metal ion.</description><subject>Angles (geometry)</subject><subject>BENZENE</subject><subject>CARBON NITRIDES</subject><subject>Crystallography and Scattering Methods</subject><subject>GEOMETRY</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>IODIDES</subject><subject>LIGANDS</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Rhenium</subject><subject>RHENIUM COMPLEXES</subject><subject>RHENIUM IONS</subject><subject>Structure of Organic Compounds</subject><subject>TRIPHENYLPHOSPHINE</subject><issn>1063-7745</issn><issn>1562-689X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kEFLAzEQhYMoWKs_wNuCFz2sJpnsJosnWawuFARbwVtYk1mb0m5qsiv6791SoQfxNAPve4-ZR8g5o9eMgbiZMZqDlCJjkkrKoTggI5blPM1V8Xo47IOcbvVjchLjklKqFBMjcjtfYDJxIXbJDD-xTUvvg3Vt3aFN5sE5b31S-vVmhV-Jb5LnBbauX19WVXV1So6aehXx7HeOycvkfl4-ptOnh6q8m6YGALpUATJaAM1sIYWxTQ7AC4U1AMUst8YKxDehciaVRNHQGiyq2ggJgCAFwphc7HJ97JyOxnVoFsa3LZpOcy4zxQvYU5vgP3qMnV76PrTDYZoP3wrIsgEbE7ajTPAxBmz0Jrh1Hb41o3rbpP7T5ODhO08c2PYdwz75f9MPcIlyDQ</recordid><startdate>20171201</startdate><enddate>20171201</enddate><creator>Schoultz, X.</creator><creator>Gerber, T. I. A.</creator><creator>Betz, R.</creator><creator>Hosten, E. C.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>20171201</creationdate><title>The First Seven-Coordinated Triiodo Complex of Rhenium(III)</title><author>Schoultz, X. ; Gerber, T. I. A. ; Betz, R. ; Hosten, E. C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c333t-83e109305d974cdf633298ea330e56dcd4eeb4861787e4f0a3de8ac4733e374e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Angles (geometry)</topic><topic>BENZENE</topic><topic>CARBON NITRIDES</topic><topic>Crystallography and Scattering Methods</topic><topic>GEOMETRY</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>IODIDES</topic><topic>LIGANDS</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Rhenium</topic><topic>RHENIUM COMPLEXES</topic><topic>RHENIUM IONS</topic><topic>Structure of Organic Compounds</topic><topic>TRIPHENYLPHOSPHINE</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schoultz, X.</creatorcontrib><creatorcontrib>Gerber, T. I. A.</creatorcontrib><creatorcontrib>Betz, R.</creatorcontrib><creatorcontrib>Hosten, E. C.</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Crystallography reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schoultz, X.</au><au>Gerber, T. I. A.</au><au>Betz, R.</au><au>Hosten, E. C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The First Seven-Coordinated Triiodo Complex of Rhenium(III)</atitle><jtitle>Crystallography reports</jtitle><stitle>Crystallogr. Rep</stitle><date>2017-12-01</date><risdate>2017</risdate><volume>62</volume><issue>7</issue><spage>1135</spage><epage>1137</epage><pages>1135-1137</pages><issn>1063-7745</issn><eissn>1562-689X</eissn><abstract>The reaction of
cis
-[ReO
2
I(P
Ph
3
)
2
] with
tert
-butyl isocyanide in benzene led to the isolation of the complex [ReI
3
(CN-
t
-Bu)
3
(P
Ph
3
)] (
1
). The complex is unusual since it contains bulky ligands with large cone angles, i.e. three iodides, three isocyanides with
tert
-butyl groups and a triphenylphosphine as ligands in a seven-coordinate geometry around the rhenium(III) metal ion.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1063774517070239</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Crystallography reports, 2017-12, Vol.62 (7), p.1135-1137 |
| issn | 1063-7745 1562-689X |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Angles (geometry) BENZENE CARBON NITRIDES Crystallography and Scattering Methods GEOMETRY INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IODIDES LIGANDS Physics Physics and Astronomy Rhenium RHENIUM COMPLEXES RHENIUM IONS Structure of Organic Compounds TRIPHENYLPHOSPHINE |
| title | The First Seven-Coordinated Triiodo Complex of Rhenium(III) |
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