Berlinite substitution in the cement clinker
Incorporation of P2O5 in clinker minerals in laboratory samples of clinker with graded content of P2O5 were studied by means of electron microscopy. The most important outcome is that P2O5 enters partially the structure of clinker silicates together with Al2O3 via berlinite substitution (Al3++P5+↔2...
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| Veröffentlicht in: | Cement and concrete research 2017-02, Vol.92, p.21-28 |
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| container_title | Cement and concrete research |
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| creator | Stanek, Theodor Sulovský, Petr Boháč, Martin |
| description | Incorporation of P2O5 in clinker minerals in laboratory samples of clinker with graded content of P2O5 were studied by means of electron microscopy. The most important outcome is that P2O5 enters partially the structure of clinker silicates together with Al2O3 via berlinite substitution (Al3++P5+↔2 Si4+). Therefore, experiments were also carried out with the pure components and the influence of P2O5 on clinker phase composition in the absence of one of the main clinker oxide (Fe2O3 and Al2O3) was examined. It was found out that raw mix without Fe2O3 eliminates to a certain level negative influence of P2O5 on alite formation. The work was completed with preparation of white cement with high content of P2O5 in clinker, which exhibited good technological properties. |
| doi_str_mv | 10.1016/j.cemconres.2016.11.007 |
| format | Article |
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The most important outcome is that P2O5 enters partially the structure of clinker silicates together with Al2O3 via berlinite substitution (Al3++P5+↔2 Si4+). Therefore, experiments were also carried out with the pure components and the influence of P2O5 on clinker phase composition in the absence of one of the main clinker oxide (Fe2O3 and Al2O3) was examined. It was found out that raw mix without Fe2O3 eliminates to a certain level negative influence of P2O5 on alite formation. 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The most important outcome is that P2O5 enters partially the structure of clinker silicates together with Al2O3 via berlinite substitution (Al3++P5+↔2 Si4+). Therefore, experiments were also carried out with the pure components and the influence of P2O5 on clinker phase composition in the absence of one of the main clinker oxide (Fe2O3 and Al2O3) was examined. It was found out that raw mix without Fe2O3 eliminates to a certain level negative influence of P2O5 on alite formation. The work was completed with preparation of white cement with high content of P2O5 in clinker, which exhibited good technological properties.</description><subject>ALUMINIUM OXIDES</subject><subject>Aluminum oxide</subject><subject>Berlinite</subject><subject>Ca3SiO5 (D)</subject><subject>Cement (D)</subject><subject>CEMENTS</subject><subject>Clinker</subject><subject>EDX (B)</subject><subject>ELECTRON MICROSCOPY</subject><subject>FERRITES</subject><subject>IRON OXIDES</subject><subject>MATERIALS SCIENCE</subject><subject>Microstructure (B)</subject><subject>Minerals</subject><subject>OXIDATION</subject><subject>P2O5</subject><subject>Phase composition</subject><subject>PHOSPHATE MINERALS</subject><subject>PHOSPHATES</subject><subject>PHOSPHORUS OXIDES</subject><subject>SILICATES</subject><subject>Tricalcium silicate</subject><issn>0008-8846</issn><issn>1873-3948</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLxDAUhYMoOD5-gwW3tiZNJk2W4-ALBtzoOkxub5nUmXRMUsF_b8qILuUuwg3nHL57CLlitGKUydu-AtzB4APGqs4fFWMVpc0RmTHV8JJroY7JjFKqSqWEPCVnMfZ5lTVXM3Jzh2HrvEtYxNHG5NKY3OAL54u0wSJHo08FZMk7hgty0q23ES9_3nPy9nD_unwqVy-Pz8vFqgTesFRCa3nNteadFEpakJ2CORWN6CzMbWspba3SVinbAdYtA40oFe2yZS1ELfg5uT7kDhnIRMh0sMkneoRk6lrqhur5n2ofho8RYzL9MAafwQzTTPI8QmZVc1BBGGIM2Jl9cLt1-DKMmqlA05vfAs1UoGHM5AKzc3FwYj7102GYSNADti5MIO3g_s34BgnCfN8</recordid><startdate>20170201</startdate><enddate>20170201</enddate><creator>Stanek, Theodor</creator><creator>Sulovský, Petr</creator><creator>Boháč, Martin</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>OTOTI</scope></search><sort><creationdate>20170201</creationdate><title>Berlinite substitution in the cement clinker</title><author>Stanek, Theodor ; Sulovský, Petr ; Boháč, Martin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c371t-cdb323993f6486bc6f8c50474fbc5bdb00db89b88bfce2d1c9ee680f399a44243</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>ALUMINIUM OXIDES</topic><topic>Aluminum oxide</topic><topic>Berlinite</topic><topic>Ca3SiO5 (D)</topic><topic>Cement (D)</topic><topic>CEMENTS</topic><topic>Clinker</topic><topic>EDX (B)</topic><topic>ELECTRON MICROSCOPY</topic><topic>FERRITES</topic><topic>IRON OXIDES</topic><topic>MATERIALS SCIENCE</topic><topic>Microstructure (B)</topic><topic>Minerals</topic><topic>OXIDATION</topic><topic>P2O5</topic><topic>Phase composition</topic><topic>PHOSPHATE MINERALS</topic><topic>PHOSPHATES</topic><topic>PHOSPHORUS OXIDES</topic><topic>SILICATES</topic><topic>Tricalcium silicate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stanek, Theodor</creatorcontrib><creatorcontrib>Sulovský, Petr</creatorcontrib><creatorcontrib>Boháč, Martin</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>OSTI.GOV</collection><jtitle>Cement and concrete research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stanek, Theodor</au><au>Sulovský, Petr</au><au>Boháč, Martin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Berlinite substitution in the cement clinker</atitle><jtitle>Cement and concrete research</jtitle><date>2017-02-01</date><risdate>2017</risdate><volume>92</volume><spage>21</spage><epage>28</epage><pages>21-28</pages><issn>0008-8846</issn><eissn>1873-3948</eissn><abstract>Incorporation of P2O5 in clinker minerals in laboratory samples of clinker with graded content of P2O5 were studied by means of electron microscopy. The most important outcome is that P2O5 enters partially the structure of clinker silicates together with Al2O3 via berlinite substitution (Al3++P5+↔2 Si4+). Therefore, experiments were also carried out with the pure components and the influence of P2O5 on clinker phase composition in the absence of one of the main clinker oxide (Fe2O3 and Al2O3) was examined. It was found out that raw mix without Fe2O3 eliminates to a certain level negative influence of P2O5 on alite formation. The work was completed with preparation of white cement with high content of P2O5 in clinker, which exhibited good technological properties.</abstract><cop>Elmsford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.cemconres.2016.11.007</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Cement and concrete research, 2017-02, Vol.92, p.21-28 |
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| language | eng |
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| source | Access via ScienceDirect (Elsevier) |
| subjects | ALUMINIUM OXIDES Aluminum oxide Berlinite Ca3SiO5 (D) Cement (D) CEMENTS Clinker EDX (B) ELECTRON MICROSCOPY FERRITES IRON OXIDES MATERIALS SCIENCE Microstructure (B) Minerals OXIDATION P2O5 Phase composition PHOSPHATE MINERALS PHOSPHATES PHOSPHORUS OXIDES SILICATES Tricalcium silicate |
| title | Berlinite substitution in the cement clinker |
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