Morphological evolution of prussian yellow Fe[Fe(CN)6] colloidal nanospheres

A simple hydrothermal system was developed for controllable morphologies of the Prussian yellow Fe[Fe(CN)6] nanostructures in the presence of organic additives. Hollow and solid nanospheres of the Prussian yellow materials were successfully synthesized with suitable experimental conditions. It is fo...

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Veröffentlicht in:Journal of solid state chemistry 2016-07, Vol.239, p.64-68
Hauptverfasser: Gu, Jianmin, Fu, Shaoyan, Jin, Cuihong, Liu, Xin, Gao, Yahui, Wu, Jingxiao, Bian, Zhenpan, Tian, Hua, Wang, Lin, Gao, Faming
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container_title Journal of solid state chemistry
container_volume 239
creator Gu, Jianmin
Fu, Shaoyan
Jin, Cuihong
Liu, Xin
Gao, Yahui
Wu, Jingxiao
Bian, Zhenpan
Tian, Hua
Wang, Lin
Gao, Faming
description A simple hydrothermal system was developed for controllable morphologies of the Prussian yellow Fe[Fe(CN)6] nanostructures in the presence of organic additives. Hollow and solid nanospheres of the Prussian yellow materials were successfully synthesized with suitable experimental conditions. It is found that the amounts of organic additives CTAB could result in the formation of the spherical nanocrystals and the hydrolysis of phosphate in the solution could play a role in the final morphology of the products. A possible formation mechanism of the Prussian yellow nanostructures is proposed. A hydrothermal process was developed for controllable fabrication of the Prussian yellow hollow and solid nanospheres with the employment of different phosphate. The hydrolysis of phosphate in the solution could play a role in the morphology of the Prussian yellow nanomaterials. The acid phosphate (NaH2PO4) could result in the formation of the solid nanoparticles. The alkalescent phosphate (Na2HPO4) could result in the formation of the hollow nanoparticles. [Display omitted]
doi_str_mv 10.1016/j.jssc.2016.03.047
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Hollow and solid nanospheres of the Prussian yellow materials were successfully synthesized with suitable experimental conditions. It is found that the amounts of organic additives CTAB could result in the formation of the spherical nanocrystals and the hydrolysis of phosphate in the solution could play a role in the final morphology of the products. A possible formation mechanism of the Prussian yellow nanostructures is proposed. A hydrothermal process was developed for controllable fabrication of the Prussian yellow hollow and solid nanospheres with the employment of different phosphate. The hydrolysis of phosphate in the solution could play a role in the morphology of the Prussian yellow nanomaterials. The acid phosphate (NaH2PO4) could result in the formation of the solid nanoparticles. The alkalescent phosphate (Na2HPO4) could result in the formation of the hollow nanoparticles. 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Hollow and solid nanospheres of the Prussian yellow materials were successfully synthesized with suitable experimental conditions. It is found that the amounts of organic additives CTAB could result in the formation of the spherical nanocrystals and the hydrolysis of phosphate in the solution could play a role in the final morphology of the products. A possible formation mechanism of the Prussian yellow nanostructures is proposed. A hydrothermal process was developed for controllable fabrication of the Prussian yellow hollow and solid nanospheres with the employment of different phosphate. The hydrolysis of phosphate in the solution could play a role in the morphology of the Prussian yellow nanomaterials. The acid phosphate (NaH2PO4) could result in the formation of the solid nanoparticles. The alkalescent phosphate (Na2HPO4) could result in the formation of the hollow nanoparticles. 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subjects Additive
ADDITIVES
Colloidal nanospheres
CYANIDES
Evolution
Formations
HYDROLYSIS
Hydrothermal process
HYDROTHERMAL SYSTEMS
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
Inorganic-salt-assisted
Morphology
Nanocrystals
NANOMATERIALS
NANOPARTICLES
NANOSCIENCE AND NANOTECHNOLOGY
Nanospheres
Nanostructure
NANOSTRUCTURES
PHOSPHATES
Prussian yellow
SOLIDS
SOLUTIONS
title Morphological evolution of prussian yellow Fe[Fe(CN)6] colloidal nanospheres
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