Morphological evolution of prussian yellow Fe[Fe(CN)6] colloidal nanospheres
A simple hydrothermal system was developed for controllable morphologies of the Prussian yellow Fe[Fe(CN)6] nanostructures in the presence of organic additives. Hollow and solid nanospheres of the Prussian yellow materials were successfully synthesized with suitable experimental conditions. It is fo...
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Veröffentlicht in: | Journal of solid state chemistry 2016-07, Vol.239, p.64-68 |
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creator | Gu, Jianmin Fu, Shaoyan Jin, Cuihong Liu, Xin Gao, Yahui Wu, Jingxiao Bian, Zhenpan Tian, Hua Wang, Lin Gao, Faming |
description | A simple hydrothermal system was developed for controllable morphologies of the Prussian yellow Fe[Fe(CN)6] nanostructures in the presence of organic additives. Hollow and solid nanospheres of the Prussian yellow materials were successfully synthesized with suitable experimental conditions. It is found that the amounts of organic additives CTAB could result in the formation of the spherical nanocrystals and the hydrolysis of phosphate in the solution could play a role in the final morphology of the products. A possible formation mechanism of the Prussian yellow nanostructures is proposed.
A hydrothermal process was developed for controllable fabrication of the Prussian yellow hollow and solid nanospheres with the employment of different phosphate. The hydrolysis of phosphate in the solution could play a role in the morphology of the Prussian yellow nanomaterials. The acid phosphate (NaH2PO4) could result in the formation of the solid nanoparticles. The alkalescent phosphate (Na2HPO4) could result in the formation of the hollow nanoparticles.
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doi_str_mv | 10.1016/j.jssc.2016.03.047 |
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A hydrothermal process was developed for controllable fabrication of the Prussian yellow hollow and solid nanospheres with the employment of different phosphate. The hydrolysis of phosphate in the solution could play a role in the morphology of the Prussian yellow nanomaterials. The acid phosphate (NaH2PO4) could result in the formation of the solid nanoparticles. The alkalescent phosphate (Na2HPO4) could result in the formation of the hollow nanoparticles.
[Display omitted]</description><identifier>ISSN: 0022-4596</identifier><identifier>EISSN: 1095-726X</identifier><identifier>DOI: 10.1016/j.jssc.2016.03.047</identifier><language>eng</language><publisher>United States: Elsevier Inc</publisher><subject>Additive ; ADDITIVES ; Colloidal nanospheres ; CYANIDES ; Evolution ; Formations ; HYDROLYSIS ; Hydrothermal process ; HYDROTHERMAL SYSTEMS ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; Inorganic-salt-assisted ; Morphology ; Nanocrystals ; NANOMATERIALS ; NANOPARTICLES ; NANOSCIENCE AND NANOTECHNOLOGY ; Nanospheres ; Nanostructure ; NANOSTRUCTURES ; PHOSPHATES ; Prussian yellow ; SOLIDS ; SOLUTIONS</subject><ispartof>Journal of solid state chemistry, 2016-07, Vol.239, p.64-68</ispartof><rights>2016 Elsevier Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c427t-3c02973ec411c272214d30b2c96908d19f2112e4ffbff0a748a0a1fb5c98b6ad3</citedby><cites>FETCH-LOGICAL-c427t-3c02973ec411c272214d30b2c96908d19f2112e4ffbff0a748a0a1fb5c98b6ad3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jssc.2016.03.047$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/22584146$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Gu, Jianmin</creatorcontrib><creatorcontrib>Fu, Shaoyan</creatorcontrib><creatorcontrib>Jin, Cuihong</creatorcontrib><creatorcontrib>Liu, Xin</creatorcontrib><creatorcontrib>Gao, Yahui</creatorcontrib><creatorcontrib>Wu, Jingxiao</creatorcontrib><creatorcontrib>Bian, Zhenpan</creatorcontrib><creatorcontrib>Tian, Hua</creatorcontrib><creatorcontrib>Wang, Lin</creatorcontrib><creatorcontrib>Gao, Faming</creatorcontrib><title>Morphological evolution of prussian yellow Fe[Fe(CN)6] colloidal nanospheres</title><title>Journal of solid state chemistry</title><description>A simple hydrothermal system was developed for controllable morphologies of the Prussian yellow Fe[Fe(CN)6] nanostructures in the presence of organic additives. Hollow and solid nanospheres of the Prussian yellow materials were successfully synthesized with suitable experimental conditions. It is found that the amounts of organic additives CTAB could result in the formation of the spherical nanocrystals and the hydrolysis of phosphate in the solution could play a role in the final morphology of the products. A possible formation mechanism of the Prussian yellow nanostructures is proposed.
A hydrothermal process was developed for controllable fabrication of the Prussian yellow hollow and solid nanospheres with the employment of different phosphate. The hydrolysis of phosphate in the solution could play a role in the morphology of the Prussian yellow nanomaterials. The acid phosphate (NaH2PO4) could result in the formation of the solid nanoparticles. The alkalescent phosphate (Na2HPO4) could result in the formation of the hollow nanoparticles.
[Display omitted]</description><subject>Additive</subject><subject>ADDITIVES</subject><subject>Colloidal nanospheres</subject><subject>CYANIDES</subject><subject>Evolution</subject><subject>Formations</subject><subject>HYDROLYSIS</subject><subject>Hydrothermal process</subject><subject>HYDROTHERMAL SYSTEMS</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>Inorganic-salt-assisted</subject><subject>Morphology</subject><subject>Nanocrystals</subject><subject>NANOMATERIALS</subject><subject>NANOPARTICLES</subject><subject>NANOSCIENCE AND NANOTECHNOLOGY</subject><subject>Nanospheres</subject><subject>Nanostructure</subject><subject>NANOSTRUCTURES</subject><subject>PHOSPHATES</subject><subject>Prussian yellow</subject><subject>SOLIDS</subject><subject>SOLUTIONS</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kE9LxDAQxYMouK5-AU8FL3poTdL0H3iRxVVh1YuCIBLSdOJm6SY1aVf225tSz55mGH5veO8hdE5wQjDJrzfJxnuZ0LAnOE0wKw7QjOAqiwuavx-iGcaUxiyr8mN04v0GY0Kyks3Q6sm6bm1b-6WlaCPY2XbotTWRVVHnBu-1MNEe2tb-REv4WMLl4vkq_4ykDSfdBIkRxvpuDQ78KTpSovVw9jfn6G1597p4iFcv94-L21UsGS36OJWYVkUKkhEiaUEpYU2KayqrvMJlQypFCaHAlKqVwqJgpcCCqDqTVVnnoknn6GL6a32vuZe6B7mW1hiQPac0BCMsD9TlRHXOfg_ge77VXoYowoAdPCclzViRViwLKJ1Q6az3DhTvnN4Kt-cE87FgvuFjwXwsmOOUh4KD6GYSQYi60-BGJ2AkNNqNRhqr_5P_Auggg78</recordid><startdate>20160701</startdate><enddate>20160701</enddate><creator>Gu, Jianmin</creator><creator>Fu, Shaoyan</creator><creator>Jin, Cuihong</creator><creator>Liu, Xin</creator><creator>Gao, Yahui</creator><creator>Wu, Jingxiao</creator><creator>Bian, Zhenpan</creator><creator>Tian, Hua</creator><creator>Wang, Lin</creator><creator>Gao, Faming</creator><general>Elsevier Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>OTOTI</scope></search><sort><creationdate>20160701</creationdate><title>Morphological evolution of prussian yellow Fe[Fe(CN)6] colloidal nanospheres</title><author>Gu, Jianmin ; Fu, Shaoyan ; Jin, Cuihong ; Liu, Xin ; Gao, Yahui ; Wu, Jingxiao ; Bian, Zhenpan ; Tian, Hua ; Wang, Lin ; Gao, Faming</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c427t-3c02973ec411c272214d30b2c96908d19f2112e4ffbff0a748a0a1fb5c98b6ad3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Additive</topic><topic>ADDITIVES</topic><topic>Colloidal nanospheres</topic><topic>CYANIDES</topic><topic>Evolution</topic><topic>Formations</topic><topic>HYDROLYSIS</topic><topic>Hydrothermal process</topic><topic>HYDROTHERMAL SYSTEMS</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>Inorganic-salt-assisted</topic><topic>Morphology</topic><topic>Nanocrystals</topic><topic>NANOMATERIALS</topic><topic>NANOPARTICLES</topic><topic>NANOSCIENCE AND NANOTECHNOLOGY</topic><topic>Nanospheres</topic><topic>Nanostructure</topic><topic>NANOSTRUCTURES</topic><topic>PHOSPHATES</topic><topic>Prussian yellow</topic><topic>SOLIDS</topic><topic>SOLUTIONS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gu, Jianmin</creatorcontrib><creatorcontrib>Fu, Shaoyan</creatorcontrib><creatorcontrib>Jin, Cuihong</creatorcontrib><creatorcontrib>Liu, Xin</creatorcontrib><creatorcontrib>Gao, Yahui</creatorcontrib><creatorcontrib>Wu, Jingxiao</creatorcontrib><creatorcontrib>Bian, Zhenpan</creatorcontrib><creatorcontrib>Tian, Hua</creatorcontrib><creatorcontrib>Wang, Lin</creatorcontrib><creatorcontrib>Gao, Faming</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>OSTI.GOV</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gu, Jianmin</au><au>Fu, Shaoyan</au><au>Jin, Cuihong</au><au>Liu, Xin</au><au>Gao, Yahui</au><au>Wu, Jingxiao</au><au>Bian, Zhenpan</au><au>Tian, Hua</au><au>Wang, Lin</au><au>Gao, Faming</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Morphological evolution of prussian yellow Fe[Fe(CN)6] colloidal nanospheres</atitle><jtitle>Journal of solid state chemistry</jtitle><date>2016-07-01</date><risdate>2016</risdate><volume>239</volume><spage>64</spage><epage>68</epage><pages>64-68</pages><issn>0022-4596</issn><eissn>1095-726X</eissn><abstract>A simple hydrothermal system was developed for controllable morphologies of the Prussian yellow Fe[Fe(CN)6] nanostructures in the presence of organic additives. Hollow and solid nanospheres of the Prussian yellow materials were successfully synthesized with suitable experimental conditions. It is found that the amounts of organic additives CTAB could result in the formation of the spherical nanocrystals and the hydrolysis of phosphate in the solution could play a role in the final morphology of the products. A possible formation mechanism of the Prussian yellow nanostructures is proposed.
A hydrothermal process was developed for controllable fabrication of the Prussian yellow hollow and solid nanospheres with the employment of different phosphate. The hydrolysis of phosphate in the solution could play a role in the morphology of the Prussian yellow nanomaterials. The acid phosphate (NaH2PO4) could result in the formation of the solid nanoparticles. The alkalescent phosphate (Na2HPO4) could result in the formation of the hollow nanoparticles.
[Display omitted]</abstract><cop>United States</cop><pub>Elsevier Inc</pub><doi>10.1016/j.jssc.2016.03.047</doi><tpages>5</tpages></addata></record> |
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subjects | Additive ADDITIVES Colloidal nanospheres CYANIDES Evolution Formations HYDROLYSIS Hydrothermal process HYDROTHERMAL SYSTEMS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Inorganic-salt-assisted Morphology Nanocrystals NANOMATERIALS NANOPARTICLES NANOSCIENCE AND NANOTECHNOLOGY Nanospheres Nanostructure NANOSTRUCTURES PHOSPHATES Prussian yellow SOLIDS SOLUTIONS |
title | Morphological evolution of prussian yellow Fe[Fe(CN)6] colloidal nanospheres |
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