Ionothermal synthesis, structures, properties of cobalt-1,4-benzenedicarboxylate metal–organic frameworks
Eight kinds of 1-methyl-3-alkylimidazolium halide [RMI]X (R=ethyl (E), propyl (P), butyl (B) and amyl (A); MI = imidazolium; X= Cl−, I−) ionic liquids (ILs) were used as reaction media and obtained a series of 2D [RMI]2[Co3(BDC)3X2] frameworks through the ionothermal reactions of 1,4-benzenedicarbox...
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| Veröffentlicht in: | Journal of solid state chemistry 2016-06, Vol.238, p.217-222 |
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| creator | Zhang, Zong-Hui Xu, Ling Jiao, Huan |
| description | Eight kinds of 1-methyl-3-alkylimidazolium halide [RMI]X (R=ethyl (E), propyl (P), butyl (B) and amyl (A); MI = imidazolium; X= Cl−, I−) ionic liquids (ILs) were used as reaction media and obtained a series of 2D [RMI]2[Co3(BDC)3X2] frameworks through the ionothermal reactions of 1,4-benzenedicarboxylic acid (H2BDC) with Co(NO3)2·6H2O. The 2D [RMI]2[Co3(BDC)3X2] frameworks exhibit a same (3,6) topology network with [RMI]+ cations locating in the interlayer space. [RMI]+ cations play a template role in the structure constructions, whose influence combining with the effect of X− anions pass to the TG behaviors. The decomposition temperatures of the [RMI]2[Co3(BDC)3X2] frameworks decrease with the alkyl chains in [RMI]+ cations, and the compounds containing Cl− show higher thermal stabilities than those with I−. However, compounds 1–8 exhibit two similar broad emissions at ca. 380 and 390nm, assigned to ILCT. The RMI+ templates and the X− anions do not exert their influence on the fluorescence.
Eight 2D [RMI]2[Co3(BDC)3X2] compounds were synthesized through ionothermal reactions. [RMI]+ cations play a template role in the structure constructions, and tune the TG behaviors combining with the effect of X− anions.
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| doi_str_mv | 10.1016/j.jssc.2016.03.028 |
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Eight 2D [RMI]2[Co3(BDC)3X2] compounds were synthesized through ionothermal reactions. [RMI]+ cations play a template role in the structure constructions, and tune the TG behaviors combining with the effect of X− anions.
[Display omitted]</description><identifier>ISSN: 0022-4596</identifier><identifier>EISSN: 1095-726X</identifier><identifier>DOI: 10.1016/j.jssc.2016.03.028</identifier><language>eng</language><publisher>United States: Elsevier Inc</publisher><subject>1,4-Benzenedicarboxylic acid ; AMINO ACIDS ; ANIONS ; CARBONATES ; CATIONS ; COBALT ; COBALT NITRATES ; CRYSTAL STRUCTURE ; CRYSTALS ; DECOMPOSITION ; FLUORESCENCE ; HALIDES ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; Interlayers ; Ionic liquids ; Ionothermal synthesis ; Metal-organic framework ; Metal-organic frameworks ; MOLTEN SALTS ; ORGANOMETALLIC COMPOUNDS ; SYNTHESIS ; Two dimensional</subject><ispartof>Journal of solid state chemistry, 2016-06, Vol.238, p.217-222</ispartof><rights>2016 Elsevier Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c361t-be40b04ed101b89652ef71b1ab92f1ad70f0b5af0d7b4a3d892a101dd92a65f13</citedby><cites>FETCH-LOGICAL-c361t-be40b04ed101b89652ef71b1ab92f1ad70f0b5af0d7b4a3d892a101dd92a65f13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jssc.2016.03.028$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/22584122$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Zong-Hui</creatorcontrib><creatorcontrib>Xu, Ling</creatorcontrib><creatorcontrib>Jiao, Huan</creatorcontrib><title>Ionothermal synthesis, structures, properties of cobalt-1,4-benzenedicarboxylate metal–organic frameworks</title><title>Journal of solid state chemistry</title><description>Eight kinds of 1-methyl-3-alkylimidazolium halide [RMI]X (R=ethyl (E), propyl (P), butyl (B) and amyl (A); MI = imidazolium; X= Cl−, I−) ionic liquids (ILs) were used as reaction media and obtained a series of 2D [RMI]2[Co3(BDC)3X2] frameworks through the ionothermal reactions of 1,4-benzenedicarboxylic acid (H2BDC) with Co(NO3)2·6H2O. The 2D [RMI]2[Co3(BDC)3X2] frameworks exhibit a same (3,6) topology network with [RMI]+ cations locating in the interlayer space. [RMI]+ cations play a template role in the structure constructions, whose influence combining with the effect of X− anions pass to the TG behaviors. The decomposition temperatures of the [RMI]2[Co3(BDC)3X2] frameworks decrease with the alkyl chains in [RMI]+ cations, and the compounds containing Cl− show higher thermal stabilities than those with I−. However, compounds 1–8 exhibit two similar broad emissions at ca. 380 and 390nm, assigned to ILCT. The RMI+ templates and the X− anions do not exert their influence on the fluorescence.
Eight 2D [RMI]2[Co3(BDC)3X2] compounds were synthesized through ionothermal reactions. [RMI]+ cations play a template role in the structure constructions, and tune the TG behaviors combining with the effect of X− anions.
[Display omitted]</description><subject>1,4-Benzenedicarboxylic acid</subject><subject>AMINO ACIDS</subject><subject>ANIONS</subject><subject>CARBONATES</subject><subject>CATIONS</subject><subject>COBALT</subject><subject>COBALT NITRATES</subject><subject>CRYSTAL STRUCTURE</subject><subject>CRYSTALS</subject><subject>DECOMPOSITION</subject><subject>FLUORESCENCE</subject><subject>HALIDES</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>Interlayers</subject><subject>Ionic liquids</subject><subject>Ionothermal synthesis</subject><subject>Metal-organic framework</subject><subject>Metal-organic frameworks</subject><subject>MOLTEN SALTS</subject><subject>ORGANOMETALLIC COMPOUNDS</subject><subject>SYNTHESIS</subject><subject>Two dimensional</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kL1u3DAQhInAAXJ28gKpBLhxYSlL6uckwI1h2IkBA2kSIB1BUkubZ4k8c3mJL1XeIW-YJwmFc-1qp5gZ7HyMfeRQceDdp021ITKVyLqCugLRv2ErDkNbrkX344itAIQom3bo3rFjog0A523frNjjbfAhPWCc1VTQ3mdJjs4LSnFn0i5i1tsYthiTQyqCLUzQakolP29Kjf43ehydUVGH5_2kEhYzJjX9-_M3xHvlnSlsVDP-CvGR3rO3Vk2EH17uCft-c_3t6kt59_Xz7dXlXWnqjqfc2oCGBse8TPdD1wq0a6650oOwXI1rsKBbZWFc60bVYz8Ila3jmG_XWl6fsNNDb6DkJBmX0DyY4D2aJIXIu7kQ2XV2cOV5TzukJGdHBqdJeQw7krznHUAm1mWrOFhNDEQRrdxGN6u4lxzkwl9u5MJfLvwl1DLzz6GLQwjz1J8O4_IJepNxxeWRMbjX4v8Bi7SR2A</recordid><startdate>20160601</startdate><enddate>20160601</enddate><creator>Zhang, Zong-Hui</creator><creator>Xu, Ling</creator><creator>Jiao, Huan</creator><general>Elsevier Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>OTOTI</scope></search><sort><creationdate>20160601</creationdate><title>Ionothermal synthesis, structures, properties of cobalt-1,4-benzenedicarboxylate metal–organic frameworks</title><author>Zhang, Zong-Hui ; Xu, Ling ; Jiao, Huan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c361t-be40b04ed101b89652ef71b1ab92f1ad70f0b5af0d7b4a3d892a101dd92a65f13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>1,4-Benzenedicarboxylic acid</topic><topic>AMINO ACIDS</topic><topic>ANIONS</topic><topic>CARBONATES</topic><topic>CATIONS</topic><topic>COBALT</topic><topic>COBALT NITRATES</topic><topic>CRYSTAL STRUCTURE</topic><topic>CRYSTALS</topic><topic>DECOMPOSITION</topic><topic>FLUORESCENCE</topic><topic>HALIDES</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>Interlayers</topic><topic>Ionic liquids</topic><topic>Ionothermal synthesis</topic><topic>Metal-organic framework</topic><topic>Metal-organic frameworks</topic><topic>MOLTEN SALTS</topic><topic>ORGANOMETALLIC COMPOUNDS</topic><topic>SYNTHESIS</topic><topic>Two dimensional</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Zong-Hui</creatorcontrib><creatorcontrib>Xu, Ling</creatorcontrib><creatorcontrib>Jiao, Huan</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>OSTI.GOV</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Zong-Hui</au><au>Xu, Ling</au><au>Jiao, Huan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ionothermal synthesis, structures, properties of cobalt-1,4-benzenedicarboxylate metal–organic frameworks</atitle><jtitle>Journal of solid state chemistry</jtitle><date>2016-06-01</date><risdate>2016</risdate><volume>238</volume><spage>217</spage><epage>222</epage><pages>217-222</pages><issn>0022-4596</issn><eissn>1095-726X</eissn><abstract>Eight kinds of 1-methyl-3-alkylimidazolium halide [RMI]X (R=ethyl (E), propyl (P), butyl (B) and amyl (A); MI = imidazolium; X= Cl−, I−) ionic liquids (ILs) were used as reaction media and obtained a series of 2D [RMI]2[Co3(BDC)3X2] frameworks through the ionothermal reactions of 1,4-benzenedicarboxylic acid (H2BDC) with Co(NO3)2·6H2O. The 2D [RMI]2[Co3(BDC)3X2] frameworks exhibit a same (3,6) topology network with [RMI]+ cations locating in the interlayer space. [RMI]+ cations play a template role in the structure constructions, whose influence combining with the effect of X− anions pass to the TG behaviors. The decomposition temperatures of the [RMI]2[Co3(BDC)3X2] frameworks decrease with the alkyl chains in [RMI]+ cations, and the compounds containing Cl− show higher thermal stabilities than those with I−. However, compounds 1–8 exhibit two similar broad emissions at ca. 380 and 390nm, assigned to ILCT. The RMI+ templates and the X− anions do not exert their influence on the fluorescence.
Eight 2D [RMI]2[Co3(BDC)3X2] compounds were synthesized through ionothermal reactions. [RMI]+ cations play a template role in the structure constructions, and tune the TG behaviors combining with the effect of X− anions.
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| subjects | 1,4-Benzenedicarboxylic acid AMINO ACIDS ANIONS CARBONATES CATIONS COBALT COBALT NITRATES CRYSTAL STRUCTURE CRYSTALS DECOMPOSITION FLUORESCENCE HALIDES INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Interlayers Ionic liquids Ionothermal synthesis Metal-organic framework Metal-organic frameworks MOLTEN SALTS ORGANOMETALLIC COMPOUNDS SYNTHESIS Two dimensional |
| title | Ionothermal synthesis, structures, properties of cobalt-1,4-benzenedicarboxylate metal–organic frameworks |
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