Invariant exchange perturbation theory for multicenter systems: Time-dependent perturbations

A formalism of exchange perturbation theory (EPT) is developed for the case of interactions that explicitly depend on time. Corrections to the wave function obtained in any order of perturbation theory and represented in an invariant form include exchange contributions due to intercenter electron pe...

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Veröffentlicht in:Journal of experimental and theoretical physics 2015-02, Vol.120 (2), p.296-311
Hauptverfasser: Orlenko, E. V., Evstafev, A. V., Orlenko, F. E.
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Evstafev, A. V.
Orlenko, F. E.
description A formalism of exchange perturbation theory (EPT) is developed for the case of interactions that explicitly depend on time. Corrections to the wave function obtained in any order of perturbation theory and represented in an invariant form include exchange contributions due to intercenter electron permutations in complex multicenter systems. For collisions of atomic systems with an arbitrary type of interaction, general expressions are obtained for the transfer ( T ) and scattering ( S ) matrices in which intercenter electron permutations between overlapping nonorthogonal states belonging to different centers (atoms) are consistently taken into account. The problem of collision of alpha particles with lithium atoms accompanied by the redistribution of electrons between centers is considered. The differential and total charge-exchange cross sections of lithium are calculated.
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subjects ALPHA PARTICLES
Analysis
ATOMIC AND MOLECULAR PHYSICS
ATOMS
CHARGE EXCHANGE
Classical and Quantum Gravitation
CORRECTIONS
CROSS SECTIONS
Disorder
ELECTRONS
Elementary Particles
ION-ATOM COLLISIONS
LITHIUM
Order
Particle and Nuclear Physics
PERTURBATION THEORY
Phase Transition in Condensed System
Physics
Physics and Astronomy
Quantum Field Theory
Relativity Theory
S MATRIX
SCATTERING
Solid State Physics
TIME DEPENDENCE
WAVE FUNCTIONS
title Invariant exchange perturbation theory for multicenter systems: Time-dependent perturbations
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