Crystal structure of a new amine nitrate: 4-dimethylaminopyridinium nitrate (C{sub 7}H{sub 11}N{sub 2})NO{sub 3}

The title compound (C{sub 7}H{sub 11}N{sub 2})NO{sub 3} (I) was obtained by the slow evaporation method at room temperature. Its crystal structure consists of organic cations (C{sub 7}H{sub 11}N{sub 2}){sup +} and nitrate anions (NO{sub 3}){sup –} linked by two types of hydrogen bonds. Each monoprot...

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Veröffentlicht in:	Crystallography reports 2015-12, Vol.60 (7)
Hauptverfasser:	Benhassan, D., Rekik, W., Naïli, H., Ślepokura, Katarzyna
Format:	Artikel
Sprache:	eng
Schlagworte:	AMINES ANIONS CATIONS CHEMICAL BONDS CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY CRYSTAL STRUCTURE EVAPORATION HYDROGEN LAYERS NITRATES NITROGEN NITROGEN OXIDES OXYGEN PHASE STABILITY TEMPERATURE RANGE 0273-0400 K
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description	The title compound (C{sub 7}H{sub 11}N{sub 2})NO{sub 3} (I) was obtained by the slow evaporation method at room temperature. Its crystal structure consists of organic cations (C{sub 7}H{sub 11}N{sub 2}){sup +} and nitrate anions (NO{sub 3}){sup –} linked by two types of hydrogen bonds. Each monoprotonated nitrogen atom, called bifurcated, is engaged in two N–H···O hydrogen bonds with two symmetric oxygen atoms. In addition, the crystal structure stability is established by C–H···O hydrogen bonds that ensure the formation of infinite layers, parallel to (001) plane. These layers are related together through π···π interactions established between aromatic amines.
doi_str_mv	10.1134/S1063774515070044
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Its crystal structure consists of organic cations (C{sub 7}H{sub 11}N{sub 2}){sup +} and nitrate anions (NO{sub 3}){sup –} linked by two types of hydrogen bonds. Each monoprotonated nitrogen atom, called bifurcated, is engaged in two N–H···O hydrogen bonds with two symmetric oxygen atoms. In addition, the crystal structure stability is established by C–H···O hydrogen bonds that ensure the formation of infinite layers, parallel to (001) plane. These layers are related together through π···π interactions established between aromatic amines.</abstract><cop>United States</cop><doi>10.1134/S1063774515070044</doi></addata></record>
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subjects	AMINES ANIONS CATIONS CHEMICAL BONDS CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY CRYSTAL STRUCTURE EVAPORATION HYDROGEN LAYERS NITRATES NITROGEN NITROGEN OXIDES OXYGEN PHASE STABILITY TEMPERATURE RANGE 0273-0400 K
title	Crystal structure of a new amine nitrate: 4-dimethylaminopyridinium nitrate (C{sub 7}H{sub 11}N{sub 2})NO{sub 3}
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