Transformation of dense AgI into a silver-rich framework iodide using thiophenol as mineralizer

A new three-dimensional framework iodide, (DabcoH)2[(Dabco)2Ag14I16] (1), was solvothermal synthesized by transformation of dense AgI using p-methylthiophenol as mineralizer, and characterized by elemental analysis, single-crystal and powder X-ray diffraction, thermogravimetric analysis, differentia...

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Veröffentlicht in:	Journal of solid state chemistry 2014-12, Vol.220, p.185-190
Hauptverfasser:	Zhang, Ren-Chun, Zhang, You-Juan, Yuan, Bai-Qing, Miao, Jun-Peng, Pei, Bao-Hua, Liu, Pan-Pan, Wang, Jun-Jie, Zhang, Dao-Jun
Format:	Artikel
Sprache:	eng
Schlagworte:	CALORIMETRY Channels EXCITATION FLUORESCENCE FLUORESCENCE SPECTROSCOPY HYBRIDIZATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Iodides Mineralizer MONOCRYSTALS PHOTOLUMINESCENCE POWDERS Reflectance Reflectivity Semiconductivity SILVER SILVER IODIDES Solvothermal synthesis SPACE GROUPS Spectroscopy SYNTHESIS THERMAL GRAVIMETRIC ANALYSIS Three dimensional Transformations X-RAY DIFFRACTION
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