Transformation of dense AgI into a silver-rich framework iodide using thiophenol as mineralizer
A new three-dimensional framework iodide, (DabcoH)2[(Dabco)2Ag14I16] (1), was solvothermal synthesized by transformation of dense AgI using p-methylthiophenol as mineralizer, and characterized by elemental analysis, single-crystal and powder X-ray diffraction, thermogravimetric analysis, differentia...
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| Veröffentlicht in: | Journal of solid state chemistry 2014-12, Vol.220, p.185-190 |
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| creator | Zhang, Ren-Chun Zhang, You-Juan Yuan, Bai-Qing Miao, Jun-Peng Pei, Bao-Hua Liu, Pan-Pan Wang, Jun-Jie Zhang, Dao-Jun |
| description | A new three-dimensional framework iodide, (DabcoH)2[(Dabco)2Ag14I16] (1), was solvothermal synthesized by transformation of dense AgI using p-methylthiophenol as mineralizer, and characterized by elemental analysis, single-crystal and powder X-ray diffraction, thermogravimetric analysis, differential scanning calorimetry analysis, UV–vis diffuse reflectance spectroscopy and fluorescence spectroscopy. Compound 1 crystallizes in the trigonal space group R-3c, a=13.4452(2)Å, c=63.725(2)Å, V=9976.5(4)Å3, Z=6. It features a 3D silver-rich [(Dabco)2Ag14I16]2− anionic framework built up from corner-sharing of hybrid [(Dabco)2Ag14I19]5− clusters, with protonated DabcoH+ as counterions residing in the channels. UV–vis reflectance spectroscopy reveals the band gap of 1 is 3.3eV. Compound 1 exhibits a strong photoluminescent emission band at 567nm upon excitation at 489nm.
A new 3-D iodoargentate was synthesized by transformation of dense AgI in I−-deficient system using thiophenol as mineralizer. [Display omitted]
•We have developed a new method to synthesize iodide using thiophenol as mineralizer.•A new 3D iodide, (DabcoH)2[(Dabco)2Ag14I16], was synthesized by transformation of dense AgI under solvothermal condition.•The compound features a 3D Ag–I framework with highest Ag/I ratio.•Compound 1 is a semiconductor with the band gap of 3.3eV.•Compound 1 exhibits a strong photoluminescent emission band at 567nm upon excitation at 489nm. |
| doi_str_mv | 10.1016/j.jssc.2014.08.036 |
| format | Article |
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A new 3-D iodoargentate was synthesized by transformation of dense AgI in I−-deficient system using thiophenol as mineralizer. [Display omitted]
•We have developed a new method to synthesize iodide using thiophenol as mineralizer.•A new 3D iodide, (DabcoH)2[(Dabco)2Ag14I16], was synthesized by transformation of dense AgI under solvothermal condition.•The compound features a 3D Ag–I framework with highest Ag/I ratio.•Compound 1 is a semiconductor with the band gap of 3.3eV.•Compound 1 exhibits a strong photoluminescent emission band at 567nm upon excitation at 489nm.</description><identifier>ISSN: 0022-4596</identifier><identifier>EISSN: 1095-726X</identifier><identifier>DOI: 10.1016/j.jssc.2014.08.036</identifier><language>eng</language><publisher>United States: Elsevier Inc</publisher><subject>CALORIMETRY ; Channels ; EXCITATION ; FLUORESCENCE ; FLUORESCENCE SPECTROSCOPY ; HYBRIDIZATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; Iodides ; Mineralizer ; MONOCRYSTALS ; PHOTOLUMINESCENCE ; POWDERS ; Reflectance ; Reflectivity ; Semiconductivity ; SILVER ; SILVER IODIDES ; Solvothermal synthesis ; SPACE GROUPS ; Spectroscopy ; SYNTHESIS ; THERMAL GRAVIMETRIC ANALYSIS ; Three dimensional ; Transformations ; X-RAY DIFFRACTION</subject><ispartof>Journal of solid state chemistry, 2014-12, Vol.220, p.185-190</ispartof><rights>2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c361t-d99647f9d8e142ed2becdd75930c87b372d4805b7f8402fcbdd37b9446f5b20c3</citedby><cites>FETCH-LOGICAL-c361t-d99647f9d8e142ed2becdd75930c87b372d4805b7f8402fcbdd37b9446f5b20c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jssc.2014.08.036$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3548,27922,27923,45993</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/22451129$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Ren-Chun</creatorcontrib><creatorcontrib>Zhang, You-Juan</creatorcontrib><creatorcontrib>Yuan, Bai-Qing</creatorcontrib><creatorcontrib>Miao, Jun-Peng</creatorcontrib><creatorcontrib>Pei, Bao-Hua</creatorcontrib><creatorcontrib>Liu, Pan-Pan</creatorcontrib><creatorcontrib>Wang, Jun-Jie</creatorcontrib><creatorcontrib>Zhang, Dao-Jun</creatorcontrib><title>Transformation of dense AgI into a silver-rich framework iodide using thiophenol as mineralizer</title><title>Journal of solid state chemistry</title><description>A new three-dimensional framework iodide, (DabcoH)2[(Dabco)2Ag14I16] (1), was solvothermal synthesized by transformation of dense AgI using p-methylthiophenol as mineralizer, and characterized by elemental analysis, single-crystal and powder X-ray diffraction, thermogravimetric analysis, differential scanning calorimetry analysis, UV–vis diffuse reflectance spectroscopy and fluorescence spectroscopy. Compound 1 crystallizes in the trigonal space group R-3c, a=13.4452(2)Å, c=63.725(2)Å, V=9976.5(4)Å3, Z=6. It features a 3D silver-rich [(Dabco)2Ag14I16]2− anionic framework built up from corner-sharing of hybrid [(Dabco)2Ag14I19]5− clusters, with protonated DabcoH+ as counterions residing in the channels. UV–vis reflectance spectroscopy reveals the band gap of 1 is 3.3eV. Compound 1 exhibits a strong photoluminescent emission band at 567nm upon excitation at 489nm.
A new 3-D iodoargentate was synthesized by transformation of dense AgI in I−-deficient system using thiophenol as mineralizer. [Display omitted]
•We have developed a new method to synthesize iodide using thiophenol as mineralizer.•A new 3D iodide, (DabcoH)2[(Dabco)2Ag14I16], was synthesized by transformation of dense AgI under solvothermal condition.•The compound features a 3D Ag–I framework with highest Ag/I ratio.•Compound 1 is a semiconductor with the band gap of 3.3eV.•Compound 1 exhibits a strong photoluminescent emission band at 567nm upon excitation at 489nm.</description><subject>CALORIMETRY</subject><subject>Channels</subject><subject>EXCITATION</subject><subject>FLUORESCENCE</subject><subject>FLUORESCENCE SPECTROSCOPY</subject><subject>HYBRIDIZATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>Iodides</subject><subject>Mineralizer</subject><subject>MONOCRYSTALS</subject><subject>PHOTOLUMINESCENCE</subject><subject>POWDERS</subject><subject>Reflectance</subject><subject>Reflectivity</subject><subject>Semiconductivity</subject><subject>SILVER</subject><subject>SILVER IODIDES</subject><subject>Solvothermal synthesis</subject><subject>SPACE GROUPS</subject><subject>Spectroscopy</subject><subject>SYNTHESIS</subject><subject>THERMAL GRAVIMETRIC ANALYSIS</subject><subject>Three dimensional</subject><subject>Transformations</subject><subject>X-RAY DIFFRACTION</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kMtuFDEQRS1EJIbAD7CyxIZNN-VHvyQ2UUQgUiQ2QcrOctvlTA3d9mD3BCVfT7eGNavanHt16zD2QUAtQLSfD_WhFFdLELqGvgbVvmI7AUNTdbJ9eM12AFJWuhnaN-xtKQcAIZpe75i5zzaWkPJsF0qRp8A9xoL86vGWU1wSt7zQ9IS5yuT2PGQ745-Uf3FKnjzyU6H4yJc9peMeY5q4LXymiNlO9IL5HbsIdir4_t-9ZD9vvt5ff6_ufny7vb66q5xqxVL5YWh1Fwbfo9ASvRzRed81gwLXd6PqpNc9NGMXeg0yuNF71Y2D1m1oRglOXbKP595UFjLF0YJu71KM6BYjpW6EkMNKfTpTx5x-n7AsZqbicJpsxHQqRrSN0EoBqBWVZ9TlVErGYI6ZZpufjQCzOTcHszk3m3MDvVmdr6Ev5xCurz4R5m0JRoee8jbEJ_pf_C8_U4tc</recordid><startdate>20141201</startdate><enddate>20141201</enddate><creator>Zhang, Ren-Chun</creator><creator>Zhang, You-Juan</creator><creator>Yuan, Bai-Qing</creator><creator>Miao, Jun-Peng</creator><creator>Pei, Bao-Hua</creator><creator>Liu, Pan-Pan</creator><creator>Wang, Jun-Jie</creator><creator>Zhang, Dao-Jun</creator><general>Elsevier Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>OTOTI</scope></search><sort><creationdate>20141201</creationdate><title>Transformation of dense AgI into a silver-rich framework iodide using thiophenol as mineralizer</title><author>Zhang, Ren-Chun ; Zhang, You-Juan ; Yuan, Bai-Qing ; Miao, Jun-Peng ; Pei, Bao-Hua ; Liu, Pan-Pan ; Wang, Jun-Jie ; Zhang, Dao-Jun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c361t-d99647f9d8e142ed2becdd75930c87b372d4805b7f8402fcbdd37b9446f5b20c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>CALORIMETRY</topic><topic>Channels</topic><topic>EXCITATION</topic><topic>FLUORESCENCE</topic><topic>FLUORESCENCE SPECTROSCOPY</topic><topic>HYBRIDIZATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>Iodides</topic><topic>Mineralizer</topic><topic>MONOCRYSTALS</topic><topic>PHOTOLUMINESCENCE</topic><topic>POWDERS</topic><topic>Reflectance</topic><topic>Reflectivity</topic><topic>Semiconductivity</topic><topic>SILVER</topic><topic>SILVER IODIDES</topic><topic>Solvothermal synthesis</topic><topic>SPACE GROUPS</topic><topic>Spectroscopy</topic><topic>SYNTHESIS</topic><topic>THERMAL GRAVIMETRIC ANALYSIS</topic><topic>Three dimensional</topic><topic>Transformations</topic><topic>X-RAY DIFFRACTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Ren-Chun</creatorcontrib><creatorcontrib>Zhang, You-Juan</creatorcontrib><creatorcontrib>Yuan, Bai-Qing</creatorcontrib><creatorcontrib>Miao, Jun-Peng</creatorcontrib><creatorcontrib>Pei, Bao-Hua</creatorcontrib><creatorcontrib>Liu, Pan-Pan</creatorcontrib><creatorcontrib>Wang, Jun-Jie</creatorcontrib><creatorcontrib>Zhang, Dao-Jun</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>OSTI.GOV</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Ren-Chun</au><au>Zhang, You-Juan</au><au>Yuan, Bai-Qing</au><au>Miao, Jun-Peng</au><au>Pei, Bao-Hua</au><au>Liu, Pan-Pan</au><au>Wang, Jun-Jie</au><au>Zhang, Dao-Jun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transformation of dense AgI into a silver-rich framework iodide using thiophenol as mineralizer</atitle><jtitle>Journal of solid state chemistry</jtitle><date>2014-12-01</date><risdate>2014</risdate><volume>220</volume><spage>185</spage><epage>190</epage><pages>185-190</pages><issn>0022-4596</issn><eissn>1095-726X</eissn><abstract>A new three-dimensional framework iodide, (DabcoH)2[(Dabco)2Ag14I16] (1), was solvothermal synthesized by transformation of dense AgI using p-methylthiophenol as mineralizer, and characterized by elemental analysis, single-crystal and powder X-ray diffraction, thermogravimetric analysis, differential scanning calorimetry analysis, UV–vis diffuse reflectance spectroscopy and fluorescence spectroscopy. Compound 1 crystallizes in the trigonal space group R-3c, a=13.4452(2)Å, c=63.725(2)Å, V=9976.5(4)Å3, Z=6. It features a 3D silver-rich [(Dabco)2Ag14I16]2− anionic framework built up from corner-sharing of hybrid [(Dabco)2Ag14I19]5− clusters, with protonated DabcoH+ as counterions residing in the channels. UV–vis reflectance spectroscopy reveals the band gap of 1 is 3.3eV. Compound 1 exhibits a strong photoluminescent emission band at 567nm upon excitation at 489nm.
A new 3-D iodoargentate was synthesized by transformation of dense AgI in I−-deficient system using thiophenol as mineralizer. [Display omitted]
•We have developed a new method to synthesize iodide using thiophenol as mineralizer.•A new 3D iodide, (DabcoH)2[(Dabco)2Ag14I16], was synthesized by transformation of dense AgI under solvothermal condition.•The compound features a 3D Ag–I framework with highest Ag/I ratio.•Compound 1 is a semiconductor with the band gap of 3.3eV.•Compound 1 exhibits a strong photoluminescent emission band at 567nm upon excitation at 489nm.</abstract><cop>United States</cop><pub>Elsevier Inc</pub><doi>10.1016/j.jssc.2014.08.036</doi><tpages>6</tpages></addata></record> |
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| ispartof | Journal of solid state chemistry, 2014-12, Vol.220, p.185-190 |
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| subjects | CALORIMETRY Channels EXCITATION FLUORESCENCE FLUORESCENCE SPECTROSCOPY HYBRIDIZATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Iodides Mineralizer MONOCRYSTALS PHOTOLUMINESCENCE POWDERS Reflectance Reflectivity Semiconductivity SILVER SILVER IODIDES Solvothermal synthesis SPACE GROUPS Spectroscopy SYNTHESIS THERMAL GRAVIMETRIC ANALYSIS Three dimensional Transformations X-RAY DIFFRACTION |
| title | Transformation of dense AgI into a silver-rich framework iodide using thiophenol as mineralizer |
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