Unique edge-sharing sulfate-transition metal coordination in Na{sub 2}M(SO{sub 4}){sub 2} (M=Ni and Co)

Two compounds, Na{sub 2}Ni(SO{sub 4}){sub 2} and Na{sub 2}Co(SO{sub 4}){sub 2}, were synthesized and their structure and properties were characterized. They adopt a structure that contains a bidentate coordination of sulfate to the transition metal center, which was determined via single crystal X-r...

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Veröffentlicht in:	Journal of solid state chemistry 2015-02, Vol.222
Hauptverfasser:	Fry, Allyson M., Institute for Quantum Matter and Department of Physics and Astronomy, The Johns Hopkins University, Baltimore, MD 21218, Department of Materials Science and Engineering, The Johns Hopkins University, Baltimore, MD 21218, Sweeney, Owen T., Adam Phelan, W., Drichko, Natalia, Siegler, Maxime A., McQueen, Tyrel M.
Format:	Artikel
Sprache:	eng
Schlagworte:	INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY INTERACTIONS MAGNETIZATION MONOCLINIC LATTICES MONOCRYSTALS NEUTRON DIFFRACTION NICKEL OXYGEN RAMAN SPECTROSCOPY SPACE GROUPS SULFATES TIME-OF-FLIGHT METHOD X RADIATION X-RAY DIFFRACTION
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