Ternary and coupled binary zinc tin oxide nanopowders: Synthesis, characterization, and potential application in photocatalytic processes
[Display omitted] •Mechanochemically synthesized nanocrystalline zinc tin oxide (ZTO) powders.•Photocatalytic degradation of alprazolam in the presence of ZTO water suspensions.•Coupled binary ZTO exhibits enhanced photocatalytic activity compared to ternary ZTO. In this paper, ternary and coupled b...
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Veröffentlicht in: | Materials research bulletin 2015-02, Vol.62, p.114-121 |
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creator | Ivetić, T.B. Finčur, N.L. Đačanin, Lj. R. Abramović, B.F. Lukić-Petrović, S.R. |
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•Mechanochemically synthesized nanocrystalline zinc tin oxide (ZTO) powders.•Photocatalytic degradation of alprazolam in the presence of ZTO water suspensions.•Coupled binary ZTO exhibits enhanced photocatalytic activity compared to ternary ZTO.
In this paper, ternary and coupled binary zinc tin oxide nanocrystalline powders were prepared via simple solid-state mechanochemical method. X-ray diffraction, scanning electron microscopy, Raman and reflectance spectroscopy were used to study the structure and optical properties of the obtained powder samples. The thermal behavior of zinc tin oxide system was examined through simultaneous thermogravimetric-differential scanning calorimetric analysis. The efficiencies of ternary (Zn2SnO4 and ZnSnO3) and coupled binary (ZnO/SnO2) zinc tin oxide water suspensions in the photocatalytic degradation of alprazolam, short-acting anxiolytic of the benzodiazepine class of psychoactive drugs, under UV irradiation were determined and compared with the efficiency of pure ZnO and SnO2. |
doi_str_mv | 10.1016/j.materresbull.2014.11.001 |
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•Mechanochemically synthesized nanocrystalline zinc tin oxide (ZTO) powders.•Photocatalytic degradation of alprazolam in the presence of ZTO water suspensions.•Coupled binary ZTO exhibits enhanced photocatalytic activity compared to ternary ZTO.
In this paper, ternary and coupled binary zinc tin oxide nanocrystalline powders were prepared via simple solid-state mechanochemical method. X-ray diffraction, scanning electron microscopy, Raman and reflectance spectroscopy were used to study the structure and optical properties of the obtained powder samples. The thermal behavior of zinc tin oxide system was examined through simultaneous thermogravimetric-differential scanning calorimetric analysis. The efficiencies of ternary (Zn2SnO4 and ZnSnO3) and coupled binary (ZnO/SnO2) zinc tin oxide water suspensions in the photocatalytic degradation of alprazolam, short-acting anxiolytic of the benzodiazepine class of psychoactive drugs, under UV irradiation were determined and compared with the efficiency of pure ZnO and SnO2.</description><identifier>ISSN: 0025-5408</identifier><identifier>EISSN: 1873-4227</identifier><identifier>DOI: 10.1016/j.materresbull.2014.11.001</identifier><language>eng</language><publisher>United States: Elsevier Ltd</publisher><subject>A. Oxides ; B. Microstructure ; B. Optical properties ; C. Raman spectroscopy ; CALORIMETRY ; COMPARATIVE EVALUATIONS ; CRYSTALS ; D. Catalytic properties ; IRRADIATION ; MATERIALS SCIENCE ; MICROSTRUCTURE ; NANOSTRUCTURES ; OPTICAL PROPERTIES ; PHOTOCATALYSIS ; POWDERS ; RAMAN SPECTROSCOPY ; SCANNING ELECTRON MICROSCOPY ; SOLIDS ; SUSPENSIONS ; SYNTHESIS ; THERMAL GRAVIMETRIC ANALYSIS ; TIN OXIDES ; X-RAY DIFFRACTION ; ZINC OXIDES</subject><ispartof>Materials research bulletin, 2015-02, Vol.62, p.114-121</ispartof><rights>2014 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c389t-1bb12d415caab9abeb6cdc2aac76c007f922672414fe2dd270d1b3550af38d333</citedby><cites>FETCH-LOGICAL-c389t-1bb12d415caab9abeb6cdc2aac76c007f922672414fe2dd270d1b3550af38d333</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.materresbull.2014.11.001$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,315,782,786,887,3554,27933,27934,46004</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/22420807$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Ivetić, T.B.</creatorcontrib><creatorcontrib>Finčur, N.L.</creatorcontrib><creatorcontrib>Đačanin, Lj. R.</creatorcontrib><creatorcontrib>Abramović, B.F.</creatorcontrib><creatorcontrib>Lukić-Petrović, S.R.</creatorcontrib><title>Ternary and coupled binary zinc tin oxide nanopowders: Synthesis, characterization, and potential application in photocatalytic processes</title><title>Materials research bulletin</title><description>[Display omitted]
•Mechanochemically synthesized nanocrystalline zinc tin oxide (ZTO) powders.•Photocatalytic degradation of alprazolam in the presence of ZTO water suspensions.•Coupled binary ZTO exhibits enhanced photocatalytic activity compared to ternary ZTO.
In this paper, ternary and coupled binary zinc tin oxide nanocrystalline powders were prepared via simple solid-state mechanochemical method. X-ray diffraction, scanning electron microscopy, Raman and reflectance spectroscopy were used to study the structure and optical properties of the obtained powder samples. The thermal behavior of zinc tin oxide system was examined through simultaneous thermogravimetric-differential scanning calorimetric analysis. The efficiencies of ternary (Zn2SnO4 and ZnSnO3) and coupled binary (ZnO/SnO2) zinc tin oxide water suspensions in the photocatalytic degradation of alprazolam, short-acting anxiolytic of the benzodiazepine class of psychoactive drugs, under UV irradiation were determined and compared with the efficiency of pure ZnO and SnO2.</description><subject>A. Oxides</subject><subject>B. Microstructure</subject><subject>B. Optical properties</subject><subject>C. Raman spectroscopy</subject><subject>CALORIMETRY</subject><subject>COMPARATIVE EVALUATIONS</subject><subject>CRYSTALS</subject><subject>D. Catalytic properties</subject><subject>IRRADIATION</subject><subject>MATERIALS SCIENCE</subject><subject>MICROSTRUCTURE</subject><subject>NANOSTRUCTURES</subject><subject>OPTICAL PROPERTIES</subject><subject>PHOTOCATALYSIS</subject><subject>POWDERS</subject><subject>RAMAN SPECTROSCOPY</subject><subject>SCANNING ELECTRON MICROSCOPY</subject><subject>SOLIDS</subject><subject>SUSPENSIONS</subject><subject>SYNTHESIS</subject><subject>THERMAL GRAVIMETRIC ANALYSIS</subject><subject>TIN OXIDES</subject><subject>X-RAY DIFFRACTION</subject><subject>ZINC OXIDES</subject><issn>0025-5408</issn><issn>1873-4227</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqNkM9u1DAQxi0EUpfSd7Dg2oSxk6yzvaFCS6VKHChnazKeaL1K7ch2ge0b8NZkdzlw7Gk0_75v5ifEewW1ArX-uKsfsXBKnIenaao1qLZWqgZQr8RK9aapWq3Na7EC0F3VtdCfibc57wCg7Y1ZiT8PnAKmvcTgJMWneWInB38sPftAsvgg42_vWAYMcY6_HKd8Jb_vQ9ly9vlS0hYT0nKFf8biY7g8as2xcCgeJ4nzPHk6tuQiNm9jiUuK0754knOKxDlzfifejDhlvvgXz8WPmy8P11-r-2-3d9ef7itq-k2p1DAo7VrVEeKwwYGHNTnSiGTWBGDGjdZro1vVjqyd0wacGpquAxyb3jVNcy4-nHRjLt5m8oVpSzEEpmK1bjX0YJapq9MUpZhz4tHOyT8uVKwCe0Bvd_Z_9PaA3iplF_TL8ufTMi9__PScDjYciJ1PBxcX_Utk_gJMDJi7</recordid><startdate>20150201</startdate><enddate>20150201</enddate><creator>Ivetić, T.B.</creator><creator>Finčur, N.L.</creator><creator>Đačanin, Lj. R.</creator><creator>Abramović, B.F.</creator><creator>Lukić-Petrović, S.R.</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>20150201</creationdate><title>Ternary and coupled binary zinc tin oxide nanopowders: Synthesis, characterization, and potential application in photocatalytic processes</title><author>Ivetić, T.B. ; Finčur, N.L. ; Đačanin, Lj. R. ; Abramović, B.F. ; Lukić-Petrović, S.R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c389t-1bb12d415caab9abeb6cdc2aac76c007f922672414fe2dd270d1b3550af38d333</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>A. Oxides</topic><topic>B. Microstructure</topic><topic>B. Optical properties</topic><topic>C. Raman spectroscopy</topic><topic>CALORIMETRY</topic><topic>COMPARATIVE EVALUATIONS</topic><topic>CRYSTALS</topic><topic>D. 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R.</creatorcontrib><creatorcontrib>Abramović, B.F.</creatorcontrib><creatorcontrib>Lukić-Petrović, S.R.</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Materials research bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ivetić, T.B.</au><au>Finčur, N.L.</au><au>Đačanin, Lj. R.</au><au>Abramović, B.F.</au><au>Lukić-Petrović, S.R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ternary and coupled binary zinc tin oxide nanopowders: Synthesis, characterization, and potential application in photocatalytic processes</atitle><jtitle>Materials research bulletin</jtitle><date>2015-02-01</date><risdate>2015</risdate><volume>62</volume><spage>114</spage><epage>121</epage><pages>114-121</pages><issn>0025-5408</issn><eissn>1873-4227</eissn><abstract>[Display omitted]
•Mechanochemically synthesized nanocrystalline zinc tin oxide (ZTO) powders.•Photocatalytic degradation of alprazolam in the presence of ZTO water suspensions.•Coupled binary ZTO exhibits enhanced photocatalytic activity compared to ternary ZTO.
In this paper, ternary and coupled binary zinc tin oxide nanocrystalline powders were prepared via simple solid-state mechanochemical method. X-ray diffraction, scanning electron microscopy, Raman and reflectance spectroscopy were used to study the structure and optical properties of the obtained powder samples. The thermal behavior of zinc tin oxide system was examined through simultaneous thermogravimetric-differential scanning calorimetric analysis. The efficiencies of ternary (Zn2SnO4 and ZnSnO3) and coupled binary (ZnO/SnO2) zinc tin oxide water suspensions in the photocatalytic degradation of alprazolam, short-acting anxiolytic of the benzodiazepine class of psychoactive drugs, under UV irradiation were determined and compared with the efficiency of pure ZnO and SnO2.</abstract><cop>United States</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.materresbull.2014.11.001</doi><tpages>8</tpages></addata></record> |
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subjects | A. Oxides B. Microstructure B. Optical properties C. Raman spectroscopy CALORIMETRY COMPARATIVE EVALUATIONS CRYSTALS D. Catalytic properties IRRADIATION MATERIALS SCIENCE MICROSTRUCTURE NANOSTRUCTURES OPTICAL PROPERTIES PHOTOCATALYSIS POWDERS RAMAN SPECTROSCOPY SCANNING ELECTRON MICROSCOPY SOLIDS SUSPENSIONS SYNTHESIS THERMAL GRAVIMETRIC ANALYSIS TIN OXIDES X-RAY DIFFRACTION ZINC OXIDES |
title | Ternary and coupled binary zinc tin oxide nanopowders: Synthesis, characterization, and potential application in photocatalytic processes |
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