Ternary and coupled binary zinc tin oxide nanopowders: Synthesis, characterization, and potential application in photocatalytic processes

[Display omitted] •Mechanochemically synthesized nanocrystalline zinc tin oxide (ZTO) powders.•Photocatalytic degradation of alprazolam in the presence of ZTO water suspensions.•Coupled binary ZTO exhibits enhanced photocatalytic activity compared to ternary ZTO. In this paper, ternary and coupled b...

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Veröffentlicht in:Materials research bulletin 2015-02, Vol.62, p.114-121
Hauptverfasser: Ivetić, T.B., Finčur, N.L., Đačanin, Lj. R., Abramović, B.F., Lukić-Petrović, S.R.
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container_start_page 114
container_title Materials research bulletin
container_volume 62
creator Ivetić, T.B.
Finčur, N.L.
Đačanin, Lj. R.
Abramović, B.F.
Lukić-Petrović, S.R.
description [Display omitted] •Mechanochemically synthesized nanocrystalline zinc tin oxide (ZTO) powders.•Photocatalytic degradation of alprazolam in the presence of ZTO water suspensions.•Coupled binary ZTO exhibits enhanced photocatalytic activity compared to ternary ZTO. In this paper, ternary and coupled binary zinc tin oxide nanocrystalline powders were prepared via simple solid-state mechanochemical method. X-ray diffraction, scanning electron microscopy, Raman and reflectance spectroscopy were used to study the structure and optical properties of the obtained powder samples. The thermal behavior of zinc tin oxide system was examined through simultaneous thermogravimetric-differential scanning calorimetric analysis. The efficiencies of ternary (Zn2SnO4 and ZnSnO3) and coupled binary (ZnO/SnO2) zinc tin oxide water suspensions in the photocatalytic degradation of alprazolam, short-acting anxiolytic of the benzodiazepine class of psychoactive drugs, under UV irradiation were determined and compared with the efficiency of pure ZnO and SnO2.
doi_str_mv 10.1016/j.materresbull.2014.11.001
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The efficiencies of ternary (Zn2SnO4 and ZnSnO3) and coupled binary (ZnO/SnO2) zinc tin oxide water suspensions in the photocatalytic degradation of alprazolam, short-acting anxiolytic of the benzodiazepine class of psychoactive drugs, under UV irradiation were determined and compared with the efficiency of pure ZnO and SnO2.</description><identifier>ISSN: 0025-5408</identifier><identifier>EISSN: 1873-4227</identifier><identifier>DOI: 10.1016/j.materresbull.2014.11.001</identifier><language>eng</language><publisher>United States: Elsevier Ltd</publisher><subject>A. Oxides ; B. Microstructure ; B. Optical properties ; C. Raman spectroscopy ; CALORIMETRY ; COMPARATIVE EVALUATIONS ; CRYSTALS ; D. 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The thermal behavior of zinc tin oxide system was examined through simultaneous thermogravimetric-differential scanning calorimetric analysis. The efficiencies of ternary (Zn2SnO4 and ZnSnO3) and coupled binary (ZnO/SnO2) zinc tin oxide water suspensions in the photocatalytic degradation of alprazolam, short-acting anxiolytic of the benzodiazepine class of psychoactive drugs, under UV irradiation were determined and compared with the efficiency of pure ZnO and SnO2.</description><subject>A. Oxides</subject><subject>B. Microstructure</subject><subject>B. Optical properties</subject><subject>C. Raman spectroscopy</subject><subject>CALORIMETRY</subject><subject>COMPARATIVE EVALUATIONS</subject><subject>CRYSTALS</subject><subject>D. 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X-ray diffraction, scanning electron microscopy, Raman and reflectance spectroscopy were used to study the structure and optical properties of the obtained powder samples. The thermal behavior of zinc tin oxide system was examined through simultaneous thermogravimetric-differential scanning calorimetric analysis. The efficiencies of ternary (Zn2SnO4 and ZnSnO3) and coupled binary (ZnO/SnO2) zinc tin oxide water suspensions in the photocatalytic degradation of alprazolam, short-acting anxiolytic of the benzodiazepine class of psychoactive drugs, under UV irradiation were determined and compared with the efficiency of pure ZnO and SnO2.</abstract><cop>United States</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.materresbull.2014.11.001</doi><tpages>8</tpages></addata></record>
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subjects A. Oxides
B. Microstructure
B. Optical properties
C. Raman spectroscopy
CALORIMETRY
COMPARATIVE EVALUATIONS
CRYSTALS
D. Catalytic properties
IRRADIATION
MATERIALS SCIENCE
MICROSTRUCTURE
NANOSTRUCTURES
OPTICAL PROPERTIES
PHOTOCATALYSIS
POWDERS
RAMAN SPECTROSCOPY
SCANNING ELECTRON MICROSCOPY
SOLIDS
SUSPENSIONS
SYNTHESIS
THERMAL GRAVIMETRIC ANALYSIS
TIN OXIDES
X-RAY DIFFRACTION
ZINC OXIDES
title Ternary and coupled binary zinc tin oxide nanopowders: Synthesis, characterization, and potential application in photocatalytic processes
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